H304 Swallowing and entering the respiratory tract can be fatal H316 Causes mild skin irritation H411 Toxic to aquatic life with long lasting effects Preventive action： P210 Keep away fr
Trang 1Product Name: Cleaning agent（Part No.：WTO-206）
Edited according to :GB/T 16483 GB/T 17519
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Part I Chemical Product & Company Identification
Chemical Product name：Cleaning agent（Part No.：WTO-206）
Company: Shenzhen Vital New Material Company Limited
Address ： Vital Industrial Zone, No.18, Shuitian Rd.1, Tongle Community, Baolong Street, Longgang District,
Shenzhen City
Tel/Fax for Emergency Contact：(86)755-61863001/ (86)755-84856654
E-mail：vital@vitalchemical.com Postal Code：518116
Product recommendation and limited use：Suitable for cleaning of reflow ovens, condensers, and fixtures It can
also be used to clean stencils and metal surfaces of equipment
Part II Hazards Indentification
Emergency Overview：
Liquids and vapors with high flammability have mild irritation to the skin Swallowing and
inhalation of the trachea may be fatal and may be toxic to aquatic organisms due to long-term effects.
GHS Classification
GHS Label Elements:
Symbols/ Pictograms：
Signal Word：Danger
H225 Highly flammable liquid and vapor
H304 Swallowing and entering the respiratory tract can be fatal
H316 Causes mild skin irritation
H411 Toxic to aquatic life with long lasting effects
Preventive action：
P210 Keep away from heat/sparks/open flames/hot surfaces - no smoking
P233 Keep container closed
P240 Grounding/equal connection of container and receiving equipment
P241 Use explosion-proof electrical / ventilation / lighting equipment
P242 Use only tools that do not generate sparks
P243 Taking electrostatic discharge measures
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
First-aid measures in case of emergency:
P301+P310 If swallowed, call a detoxification center/doctor immediately
P370+P378 Use a suitable medium to extinguish the fire in case of fire Water may increase danger
P303+P361+P353 If skin (or hair) is contaminated: remove/take off immediately, wash skin with water/shower P331 Do not induce vomiting
P332+P313 If skin irritation occurs, seek medical advice/medical care
P391 Collect spills
Safety storage：
P405 Storage must be locked
P403+P235 Store in a well-ventilated place and keep it cool
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Disposal Considerations：
P501 Dispose of inclusions/containers in accordance with local/regional/national/international regulations
Physical and chemical hazards: It is extremely flammable, and its vapor and air can form an explosive mixture It
is easy to burn and explode in case of fire and high heat It reacts strongly with the oxidant and even causes combustion In a fire, heated containers are in danger of explosion Vapor is heavier than air, spreads along the ground and tends to accumulate in low-lying areas, and will ignite in the event of fire
Health hazard: Mild irritation to the eyes and upper respiratory tract Continuous inhalation can cause dizziness,
nausea, drowsiness, and other anesthesia symptoms Liquid contaminated skin can cause itching
Environmental hazards: The substance may be hazardous to the environment and toxic to aquatic organisms.
Part Ⅲ Composition/information on ingredients
Substance Name CAS No Concentration (ingredients%) Concentration or Range of Classification and Pattern of the Substance
Cyclohexane 110-82-7 85.0-95.0 Liquid homogeneous
material Methylcyclohexane 108-87-2 ≤5.0
Part Ⅳ First Aid Measures
First-aid measures in case of emergency:
Skin contact: Remove contaminated clothing and wash skin thoroughly with soap and water Get medical attention
if you feel uncomfortable
Eye contact: Lift eyelids and rinse with running water or saline Get medical attention if you feel uncomfortable Inhalation: Remove quickly from the scene to fresh air Keep the airway open If breathing is difficult, give
oxygen Breathing, heartbeat stop, and immediate cardiopulmonary resuscitation Seek medical attention
Ingestion: Drinking water, no vomiting Get medical attention if you feel uncomfortable.
Part Ⅴ Fire Fighting Measures
Hazardous characteristics: It is extremely flammable, and its vapor and air can form an explosive mixture It is
easy to burn and explode in case of fire and high heat It reacts strongly with the oxidant and even causes
combustion In a fire, heated containers are in danger of explosion Vapor is heavier than air, spreads along the
ground and tends to accumulate in low-lying areas, and will ignite in the event of fire
Hazardous combustion products: carbon monoxide.
Extinguishing method: Extinguish with foam, carbon dioxide, dry powder and sand.
Fire-fighting precautions and measures: Firefighters must wear an air-breathing device, wear a full-body
fire-fighting anti-virus suit, and extinguish the fire in the upwind direction Spray the water to cool the container and, if possible, move the container from the fire to the open space If the container in the fire has changed color or
produces sound from a safety relief device, it must be evacuated immediately Fire extinguishing with water is not effective
Part Ⅵ Accidental Release Measures
Emergency action:
Eliminate all ignition sources
The warning zone is delineated according to the influence area of liquid flow and vapor diffusion, and the unrelated personnel are evacuated from the crosswind and the upwind to the safe zone
It is recommended that emergency personnel wear positive pressure self-contained breathing apparatus and wear anti-static clothing
All equipment used in the work should be grounded
Do not touch or cross spills
Cut off the source of the leak as much as possible Prevent spills from entering water bodies, sewers, basements, or confined spaces
Small spill: Absorb with sand or other combustible materials Collect absorbent material using a clean, non-sparking tool
A large number of leaks: building a dike or digging a pit Use a flying dust or lime powder to absorb a large amount
of liquid Cover with foam to reduce evaporation
Water spray reduces evaporation but does not reduce the flammability of spills in confined spaces
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Transfer to an tank truck or a dedicated collector with an explosion-proof pump
Part Ⅶ Handling & Storage
Handling:
Safety management precautions:
Closed operation, full ventilation
Operators must be specially trained to strictly follow the operating procedures
Operators are advised to wear self-priming filter respirators (half masks), safety glasses, anti-static overalls, and rubber-resistant gloves
Keep away from fire, heat, and smoking in the workplace
Use explosion-proof ventilation systems and equipment
Prevent vapors from leaking into the workplace air
Avoid contact with oxidants
The flow rate should be controlled during filling and grounded to prevent static buildup
Lightly load and unload during handling to prevent damage to packaging and containers
Equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment
Empty containers may be harmful residues
Storage:
Requirements for storage and containers:
Store in a cool, ventilated warehouse
Keep away from fire and heat
Storage temperature is 5 ℃ ~ 35 ℃， keep the container sealed
should be kept away from oxidizer, do not store together
Explosion-proof lighting and ventilation facilities are used
It is forbidden to use mechanical equipment and tools that are prone to sparks
The storage area should be equipped with leakage emergency treatment equipment and suitable containment
materials
Part Ⅷ Exposure Control & Personal Protection
Exposure limits: MAC(mg/m3)：- PC-TWA（mg/m3）：250
PC-STEL（mg/m3）：375* TLV-C(mg/m3 )：-TLV-TWA(mg/m3)：300ppm TLV-STEL(mg/m3)：
-Monitoring method:solvent desorption-gas chromatography; thermal desorption-gas chromatography; direct
injection-gas chromatography
Engineering control method: The production process is closed, ventilation is enhanced, and safe bathing and
eyewash equipment are provided
Personal protection equipment:
General requirements
Respiratory protection: Generally no special protection is required, and a filter-type gas mask (half mask) can be
worn when exposed to high concentrations
Eye protection: Wear safety glasses when the concentration in the air exceeds the standard.
Body protection: Wear anti-static overalls.
Hand protection: Wear rubber and oil resistant gloves.
Other protection: Smoking is strictly prohibited on the job site Avoid long-term repeated contact.
Part Ⅸ Physical & Chemical Properties
Specific gravity (g / cm 3 @ 20 ℃):0.783±0.010 Boiling range (℃):79.0-83.0
Auto-ignition temperature (°C): 254（ASTM D-2155） Flash point (℃):-18 (closed cup)
Solubility: Do not dissolve in water, soluble in most organic solvents such as ethanol, ether, benzene, acetone.
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Part Ⅹ Stability & Reactivity
Safety: Stable（5℃～35℃）.
Substances to be avoided: strong oxidizing agents, strong acids, strong bases, halogens.
Possible hazardous reactions under special conditions: Reacts with oxidizing agents may cause a fire and
explosion hazard
Conditions to avoid: open flames, high heat.
Hazardous decomposition products: carbon monoxide, carbon dioxide.
Part ⅩⅠ Toxicological Information
Acute toxicity:
LD50: Rat oral LD50 (mg/kg): 12705;
Mice oral LD50 (mg/kg): 813
LC50/2h: Rats inhaled LC50 (mg/m3, 2H): 70000
Irritant: Rabbit percutaneous: 1548mg / 2 days (intermittent), skin irritation
Subacute and chronic toxicity:
Rabbits were inhaled 65g/m3, 6 hours/day, 2 weeks; 44g/m3, 6 hours/day, 2 weeks; 32g/m3, 6 hours/day, 5 weeks, respectively, 3/4, 1/4, 3/4 died Table shows the symptoms of rhythm, rhythm, anesthesia, temporary convulsions, salivation, and conjunctival irritation
Mutagenicity: DNA adduct: Escherichia coli 10 μmol/L.
Part ⅩⅡ Ecological Information
Ecotoxicity:
LC50 :93-117mg/l/96h (fish)
Biodegradability: biodegradable in the environment
Soil half-life - high (hours): 4320; soil half-life - low (hours): 672
Air half-life - high (hours): 87; air half-life - low (hours): 8.7
Surface water half-life - high (hours): 4320; surface water half-life - low (hours): 672
Groundwater half-life - high (hours): 8640; groundwater half-life - low (hours): 1344
Aqueous biodegradation - aerobic - high (hours): 4032; aqueous phase biodegradation - aerobic - low (hours): 672
Aqueous biodegradation - anaerobic - high (hours): 16128; aqueous phase biodegradation - anaerobic - low (hours): 2688
Non-biodegradable:
Photooxidation half-life in water - high (hours): 6.90E+10; photooxidation half-life in water - low (hours):
1.40E+09
Photooxidation half-life in air - high (hours): 87; photooxidation half-life in air - low (hours): 8.7 Other harmful effects: The substance may be harmful to the environment, and special attention should be paid to
seaweed
Part ⅩⅢ Disposal Considerations
Disposal methods: Refer to national and local regulations before disposal It is recommended to use incineration Residual waste: It is recommended to use incineration.
Contaminated containers and packaging: It is recommended to use incineration.
Disposal considerations: Refer to national and local regulations before disposal.
Part ⅩⅣ Transport Information
Dangerous Goods Code: /
UN NO.:1145
Packing category: Class II packaging
Packing mark: 7
Packing category: 052
Marine pollutants (yes, no): No
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Packing method: small open steel drum; ordinary wooden box outside the ampoule; threaded glass bottle, iron
cover glass bottle, plastic bottle or metal barrel (can) outside the ordinary wooden box
Transportation precautions: Transportation vehicles should be equipped with the corresponding variety and
quantity of fire-fighting equipment and leakage emergency treatment equipment It is best to transport in the
summer and evening The tank (tank) used in transportation should have a grounding chain, and a hole partition can
be arranged in the tank to reduce the static electricity generated by the shock It is strictly forbidden to mix and
transport with oxidants, food chemicals, etc During transportation, it should be protected from exposure, rain and high temperature Keep away from fire, heat and high temperature areas during stopovers The vehicle exhaust pipe carrying the item must be equipped with a fire-stop device, and it is forbidden to use the mechanical equipment and tools that are prone to sparks When transporting by road, follow the prescribed route and do not stay in residential areas and densely populated areas It is forbidden to slip when transporting by rail It is strictly forbidden to
transport in bulk by wooden or cement vessels
Part ⅩⅤ Regulatory Information
Regulatory information: The following laws, regulations, rules and standards provide for the safe production, use,
storage, transportation, handling, classification and marking, packaging, occupational hazards, etc of chemicals:
《Safety Production Law of the People's Republic of China》 (promulgated by Order No 13 of the President
of the People's Republic of China on August 31, 2014, effective as of December 1, 2014)
《Law of the People's Republic of China on the Prevention and Control of Occupational Diseases 》 (promulgated by Order No 52 of the President of the People's Republic of
《Environmental Protection Law of the People's Republic of China》 (adopted at the eleventh meeting of the Standing Committee of the Seventh National People's Congress on December 26, 1989; the eighth meeting of the Standing Committee of the 12th National People's Congress of the People's Republic of China in 2014 4 Revised
on February 24)
《Regulations on the Safety Management of Dangerous Chemicals 》(revised by the 144th executive meeting
of the State Council on February 16, 2011, effective as of December 1, 2011)
《Safe Production License Regulations》 (Promulgated by Order No 397 of the State Council of the People's Republic of China on January 13, 2004) According to the 《Decision of the State Council on the Abolition and Amendment of Some Administrative Regulations》 of July 18, 2013);
《Regulations on the Safe Use of Chemicals in the Workplace》 ([1996] Ministry of Labor issued No 423)
《Measures for the Administration of Registration of Dangerous Chemicals 》 (Order No 53 of the State Administration of Work Safety)
《Chemical Safety Data Sheet Contents and Project Sequence》 (GB/T 16483-2008)
《Guidelines for the Preparation of Chemical Safety Data Sheets》 (GB/T17519-2013)
《General Technical Conditions for the Transport of Dangerous Goods》 (GB 12463-2009)
《Dangerous Goods Packaging Mark 》(GB 190-2009)
《Dangerous Goods Transportation Packaging Category Division Method》 (GB/T 15098-2008)
《Dangerous Goods Classification and Product Name Number》 (GB 6944-2012)
《Dangerous Goods Name List》 (GB 12268-2012)
《Chemical Harmful Factors of Occupational Exposure Limits of Harmful Factors in the Workplace》 (GBZ 2.1-2007)
《General Rules for the Classification of Chemicals and Hazards》 (GB 13690-2009)
《Chemical Classification and Labeling Regulations》 (GB 30000.2~ 30000.29)
《Hazardous Chemicals 》Catalogue (2015 Edition)
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Part XVI Other information
Writing and Revising Information: Compared to theA0 version, this revised SDS has revised the content of the
subordinates:
Part 2 - Overview of hazards, adding GHS risk classification and labeling elements;
Prepared in accordance with the 《Guidelines for the Preparation of Chemical Safety Data Sheets》
GB/T17519-2013 and the 《Contents and Project Sequence of Chemical Safety Data Sheets》 GB/T16483-2008
References: 《Hazardous Chemicals Safety Technology Book》 (Second Edition, Volume I)
《Chemical Harmful Factors of Occupational Exposure Limits of Harmful Factors in the Workplace》 (GBZ 2.1-2007)
《Hazardous Chemicals Catalogue》 (2015 Edition)
《Chemical Safety Data Sheet Contents and Project Sequence》 (GB/T 16483-2008)
《Guidelines for the Preparation of Chemical Safety Data Sheets》 (GB/T17519-2013)
Abbreviation description:
PC-TWA: Average allowable contact concentration for 8h working days and 40h working weeks specified by
time
PC-STEL: A concentration that allows short-term (15 min) contact under the premise of PC-TWA.
LD50: Toxic items describe the median lethal dose of oral, inhalation and skin absorption of experimental
animals
LC50: Toxic items describe the median lethal concentration of oral, inhalation and skin absorption of
experimental animals
IARC: International Agency for Research on Cancer, International Agency for Oncology.
ACGIH: US Conference of Governmental Industrial Hygienists
RTECS: Chemical substance toxicity registration online database
HSDB: National Library of Medicine's Dangerous Substance Database
Remarks: The symbol “*” in the above information means that there is no relevant information at present;
the symbol “/” means that this column is not suitable for the substance
Disclaimer: The format of this Safety Data Sheet conforms to the requirements of GB/T16483 and
GB/T17519 in China The data comes from the international authoritative database and the data submitted by the enterprise The other information is based on the current knowledge of the company We try our best to ensure all the information Accuracy, but due to the diversity of information sources and the limitations of the company's
knowledge, this article is for user's reference only, the user of the SDS should judge the rationality of the relevant information according to the purpose of use No liability is assumed for any damages in the operation, storage, use
or disposal of the product