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Báo cáo khoa học: Stage specific expression of poly(malic acid)-affiliated genes in the life cycle of Physarum polycephalum Spherulin 3b and polymalatase potx

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Quantitative PCR then revealed low levels of mRNA in amoebae, high levels in plasmodia, and also low levels in spherules, in agreement with the expres-sion under transcriptional regulati

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genes in the life cycle of Physarum polycephalum

Spherulin 3b and polymalatase

Nadthanan Pinchai, Bong-Seop Lee and Eggehard Holler

Institut fu¨r Biophysik und Physikalische Biochemie der Universita¨t Regensburg, Germany

Physarum polycephalum is a versatile organism,

dis-playing several alternative cell types and developmental

transitions [1] Uninucleate amoebae and multinucleate

plasmodia constitute the two vegetative growth phases

in the life cycle These two cell types differ in cellular

organization, behaviour and gene expression In

adverse conditions, amoebae reversibly transform into

cysts Usually, when the conditions are favourable,

amoebae mate and develop into plasmodia Plasmodia

survive adverse conditions by transforming into

another kind of cysts, spherules When starved in the

light, sporangia are formed In favourable conditions,

spores hatch to release amoebae, thus completing the

cycle

Of the various cell types in the life cycle of

P polycephalum, only the plasmodium contains the

water soluble polymer, b-poly(l-malate) (PMLA) [2–4] The polymer is concentrated in the nuclei in

an amount comparable with that of DNA and hi-stones [5] Due to its structural similarity to the backbone of nucleic acids, PMLA has been proposed

to bind nuclear proteins and function in a molecular transporter system ([6] and references therein) Injec-tion of PMLA into plasmodia increased the growth rate and shortened cell cycle duration, indicating that

it could also be involved in the molecular events responsible for the synchronization of events in the plasmodium [7,8] PMLA is synthesized from

l-malate derived from d-glucose through the glyco-lytic pathway and the tricarboxylic acid cycle [9] The polymer is released from the nuclei into cyto-plasm and finally to the culture medium, where it is

Keywords

Physarum polycephalum; plasmodium;

polymalatase, polymalic acid; spherulin 3b

Correspondence

E Holler, Institut fu¨r Biophysik und

Physikalische Biochemie der Universita¨t

Regensburg, D-93040 Regensburg,

Germany

Fax: +49 941 943 2813

Tel: +49 941 943 3030

E-mail: Eggehard.Holler@biologie.

uni-regensburg.de

(Received 4 November 2005, revised 4

January 2006, accepted 9 January 2006)

doi:10.1111/j.1742-4658.2006.05131.x

Polymalic acid is receiving interest as a unique biopolymer of the plasmodia

of mycetozoa and recently as a biogenic matrix for the synthesis of devices for drug delivery The acellular slime mold Physarum polycephalum is charac-terized by two distinctive growth phases: uninucleated amoebae and multi-nucleated plasmodia In adverse conditions, plasmodia reversibly transform into spherules Only plasmodia synthesize poly(malic acid) (PMLA) and PMLA-hydrolase (polymalatase) We have performed suppression subtrac-tive hybridization (SSH) of cDNA from amoebae and plasmodia to identify plasmodium-specific genes involved in PMLA metabolism We found cDNA encoding a plasmodium-specific, spherulin 3a-like polypeptide, NKA48 (spherulin 3b), but no evidence for a PMLA-synthetase encoding transcript Inhibitory RNA (RNAi)-induced knockdown of NKA48-cDNA generated a severe reduction in the level of PMLA suggesting that spherulin 3b func-tioned in regulating the level of PMLA Unexpectedly, cDNA of poly-malatase was not SSH-selected, suggesting its presence also in amoebae Quantitative PCR then revealed low levels of mRNA in amoebae, high levels

in plasmodia, and also low levels in spherules, in agreement with the expres-sion under transcriptional regulation in these cells

Abbreviations

DSDM, diluted semidefined medium; PMLA, b-poly( L -malate); RNAi, inhibitory RNA; SDM, semidefined medium; Sph, spherulin; SSH, suppression subtractive hybridisation.

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degraded to l-malate by a plasmodium-specific

hy-drolase (polymalatase) [4,5,10,11]

PMLA is a highly interesting polymer: applications

in pharmacy and medicine are proposed ([6] and

refer-ences therein); nanoconjugates of PMLA can be used

as drug delivery vehicles [12], the crystal structure is

being investigated [13] However, little is known about

the regulation of the polymer at the genetic level of its

synthesis and degradation The gene for polymalatase

has been sequenced (accession number AJ543320 [14]),

and distinct features of its sequenced promotor remain

to be assigned to transcription control The mechanism

of PMLA synthesis has been studied in vivo, but

attempts to identify the PMLA synthesizing enzyme

system have been unsuccessful because of loss of

syn-thetic activity during rupture of plasmodia in the

pre-paration of extracts [15]

The PMLA synthetic capacity of plasmodia of the

yellow strains such as P polycephalum MC3VII is

approximately 1 mgÆh)1Æg plasmodia)1 [8,9] ([6] and

references therein), suggesting the presence of

detect-able amounts of PMLA synthetase-specific mRNA

The absence of PMLA and polymalatase in other cell

types could be the result of cell specific gene expression

for synthesis and degradation To gain deeper insight,

this investigation was aimed at identifying

plasmo-dium-specific genes, which are involved in the synthesis

of PMLA and⁄ or its regulation, and to clarify whether

the stage-specific expression of polymalatase [4,10] is

regulated at the transcriptional or the translational

level We report on the identification of

plasmodium-specific mRNAs on the basis of suppressive

substrac-tive hybridization (SSH) using cDNAs of plasmodial

extracts as tester and of amoebal extracts as driver A

large number of transcripts were found, most of them

false-positive and only three true-positive One had a

high degree of identity with spherulin 3a and appeared

to be involved in regulation of PMLA levels in vivo

None of the SSH-generated DNAs showed similarity

with a sequence listed in the databases that would be

indicative of a PMLA synthetase Quantitative PCR

revealed that polymalatase mRNA was expressed at

considerably lower levels in amoebae and spherules

than in plasmodia This paralleled contents of

poly-malatase protein [4,10] suggesting regulated expression

at the transcriptional level

Results

Isolation of differentially expressed cDNAs

After SSH, differentially expressed cDNAs were

ana-lysed after two rounds of PCR The amplified products

from the secondary nested PCR were ligated with pGEMT-vector and were transformed into DH10B competent cells About 70 white colonies were obtained in total, 52 of which were selected Plasmid DNAs were isolated and analysed after restriction enzyme digestion Each DNA sequence occurred only once in agreement with the fact that 5¢-ends of mRNAs had been isolated with the Capfinder oligo-nucleotides Restriction to 5¢-ends was thought to reduce the complexity of bands after SSH and enhance isolation of products Nineteen of the plasmid prepara-tions contained inserts of 150 bp and were sequenced PCR analysis indicated three true-positive subtracted transcripts and all others to be false positives The high ratio of false- to true-transcripts was attributed to the use of the different strains LU352 for amoebae and M3CVII for plasmodia Isolation of 5¢-ends of mRNA by SSH using Capfinder oligonucleotides responded in particular to variability in this region The three transcripts NKA8 (accession number DQ017262), NKA49 (accession number DQ017263), and NKA48 (accession number DQ017261) were plas-modium-specific, as they were not detected in amoe-bae Fragment NKA8 contained an ORF encoding

257 amino acids and showed a putative conserved domain in the NCBI data base termed DUF343 (or gnI|CDD|26165 in the conserved domain data base), found in various cellular organisms Fragment NKA49 encoded 37 amino acids, and no alignments were found These two fragments were not considered fur-ther Although the high PMLA producing activity of plasmodia had suggested the finding of an abundant cDNA for PMLA-synthetase, no such cDNA could be identified to date

Transcript of NKA48 showed the highest abundance and was further analysed Nucleotide and deduced amino acid sequences of NKA48 were compared with the GenBank database The results indicated a high degree of identity on the levels of nucleotides (84%) and amino acids (86%) with spherulin 3a (Figs 1 and 2), the most abundant encystment-specific protein [16], and identities with sequences of bc-crystallins (Fig 2) The total number of amino acids is 103, correlating with a calculated molecular mass of 11271.5 and a the-oretical isoelectric point of 4.88 Because of the high similarity, the polypeptide encoded by NKA48 was named spherulin 3b

Knockdown of mRNA to NKA48 (spherulin 3b) Macroplasmodia were injected with dsRNA to NKA48 (spherulin 3b) and harvested after 24 h Two negative controls were performed: macroplasmodia

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without microinjection and macroplasmodia injected

with unspecific dsRNA (generated using part of the

pGEM-5zf(+) vector as template [14]) The degree of

mRNA knockdown was analysed by real-time PCR

with actin mRNA as reference Figure 3 shows that

the ratio of mRNA to NKA48 over that of actin was

significantly reduced to 1% (P < 0.001) Control

microinjection with unspecific dsRNA showed no

effect on mRNA levels (P > 0.5), indicating that the

knockdown was specific The fact that this low residual

level was obtained after 24 h suggested that the

half-life of spherulin 3b mRNA was in the range of one to

a few hours and much less than the half-life of 24–

36 h for spherulin 3a mRNA [16] Inhibitory RNA

(RNAi) experiments were also carried out with dsRNA

to NKA8 but a reduction of only 25% of the mRNA

level was observed and this was considered

insignifi-cant (P > 0.1) For the relatively short NKA49, RNAi

inhibition was not attempted; this decision was based

on previous experience with short dsRNA

Decreased levels of PMLA after microinjection

of dsRNA

PMLA was measured in the extracts of the above

NKA48-dsRNA injected and control macroplasmodia

harvested 24 h after microinjection and referenced to

the amount of protein in the same cells Knockdown

of mRNA in Fig 3A was found to be paralleled by a severe reduction to 3.5 ± 0.5 lg PMLAÆmg)1 protein (12% with reference to uninjected macroplasmodia;

P < 0.002) (Fig 3B) The control that had received unspecific dsRNA amounted to 20 ± 4 lg PMLAÆmg)1 protein (P > 0.05), not significantly lower than the uninjected control, indicating that the reduction in PMLA content was specifically referred to knockdown

of NKA48 mRNA As suggested by the low level of suppression of specific mRNA, no effects were notified

in experiments with dsRNA to NKA8

Macroplasmodia were observed for several days after microinjection, however, significant morphologi-cal changes related to the depression of PMLA were not observed

Level of polymalatase mRNA at different stages

in the life cycle The amount of polymalatase transcript at different sta-ges in the life cycle was monitored by real-time PCR using specific primers Since the mRNA level of house-keeping genes, such as of actin, varies from one cell type to the other, a cloned fragment of the polymala-tase gene was used as an external standard and subjec-ted to the same treatment as the samples In Fig 3C,

Fig 1 Nucleotide sequence alignment of spherulin 3b (1) with spherulin 3a (2) Identical residues are highlighted in grey Start and stop codons are given in bold Forward and reverse primer for RNAi experiments are underlined Ac, Accession Number The alignment was car-ried out using CLUSTALW from http://www.expasy.org and BLAST from NCBI.

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the level of cDNA of polymalatase (corresponding to

the level of mRNA) was very low for amoebae and

spherules in comparison with plasmodia (P < 0.001)

The expression of the gene in amoebae and plasmodia

explained, why cDNA was absent after SSH screening

(see above) The presence of cDNA in the stages of the

life cycle indicated that the protein could have some

general function High levels specifically in plasmodia

are consistent with a functional affiliation to PMLA

and with a regulation of gene expression at the

tran-scription level

Discussion

Physarum polycephalum belongs to the mycetozoa, the

multicellular eukaryotes more closely related to

ani-mal–fungi than to green plants [17,18] Mycetozoa

dis-play a life cycle including the microscopic amoebae

and the gigantic multinucleate plasmodium [1] Of the

various cell types only the plasmodium contains the

water soluble polymer, PMLA [10] The polymer is

concentrated in the nuclei, the level being under

homeo-static control, and the excess released continuously

into the culture medium [5] Its presumed function is

to coordinate transport, delivery, and activity of cer-tain proteins (DNA polymerases, histones, etc.) to nuc-lei [3,7,10,19,20], and it has been suggested that it participates in the maintenance of the observed high degree of synchrony typical for plasmodia [8] Strain

M3CVII is one of the high PMLA producers [8] Sev-eral other strains contain less PMLA, but no strain has been found that was devoid of the polymer In contrast, PMLA contents of nuclei were similar in all strains Thus, although the treatment with RNAi to spherulin 3b reported here suppressed the overall level

of PMLA, the remaining low level was probably suffi-cient to support normal cell morphology

Under adverse conditions, such as starvation and desiccation in the dark, the plasmodium undergoes reversible differentiation into smaller dehydrated sphe-rules [21] Each of the sphesphe-rules contains several nuclei that overexpress particular stress proteins Four major spherulation-specific mRNAs have been identified that emerged 24 h after beginning of starvation-induced spherulation of plasmodia and that then comprise

 10% of the total mRNA [16] Among them,

spheru-Fig 2 Structural alignment of amino acid sequence by motifs, of spherulin 3b with spherulin 3a and other members of the bc-crystallin fam-ily: (1) spherulin 3b from P polycephalum; (2) spherulin 3a from P polycephalum; (3) hypothetical protein YPTB2846 from Yersinia pseudo-tuberculosis; (4) hypothetical protein YmolA_01000341 from Y mollaretii; (5) hypothetical protein Y1348 from Y pestis; (6) c-crystallin from Danio rerio; and (7) development-specific protein S homologue from Myxococcus xanthis The residues highlighted in black indicate glycines, serines, and aromatics that are conserved in a bc-crystallin fold The residues shown in grey indicate the side chains and backbone sites that are involved in calcium binding [24] The residues in the conserved tyrosine corners are in bold [24] ‘Greek key’ motifs are highlighted with underlines: single line, first motif; broken line, second motif; double line, third motif Motif searches were performed using PROSITE from http://www.expasy.org Similarity search and multiple alignment were carried out using CLUSTALW from http://www.expasy.org and BLAST from NCBI Ac, Accession Number.

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lin 3a is the most abundant mRNA During differenti-ation, synthesis of PMLA discontinues, and the remaining polymer is exported into the extracellular fluid and degraded It is assumed that the PMLA syn-thesizing enzyme is downregulated at the onset of spherulation

Despite considerable effort, knowledge of PMLA synthetase activity and its regulation is still fragment-ary [15] To discover stage-specifc genes affiliated with PMLA metabolism and ultimately to identify the syn-thetase gene, SSH was used with mRNA of the plas-modium as the tester and mRNA of amoebae as the driver The amoebae strain chosen was LU352, which was not identical with plasmodia of strain M3CVII It was chosen because it allowed preparations of contam-ination-free RNA that, for unknown reasons, had not been possible for M3CVII amoebae The choice of the different strain had the principle disadvantage of gen-erating a large portion of false-positive transcripts Assuming that mRNA would be abundant in the plasmodium it was hoped that PMLA synthetase cDNA could be identified by SSH using amoebae as driver, which do not produce PMLA While this cDNA could not be identified, an abundant species was revealed that encoded a 11.3-kDa polypeptide, NKA48 (named spherulin 3b), which is structurally highly related to spherulin 3a (85% identical amino acids) While NKA48 occurs in plasmodia, spherulin 3a is only found in spherules [16] Both proteins con-tain the ‘Greek key’ typical of the bc-crystallin family

of proteins While spheruline 3a like another two-domain protein, protein S [22], responds in terms of stress proteins [23] to extreme environmental condi-tions, NKA48 has no such function

bc-Crystallins are two-domain proteins found in vertebrate eye lenses and have distant relatives in microorganisms (e.g the proteins in Fig 2) The bc-crystallin domain of spherulin 3a from P poly-cephalum, considered by some as a primitive organ-ism, has been compared by X-ray crystallography with the modern lens crystalline domain fold in order

to address the evolutionary origin of the vertebrate bc-crystallins [24] Typically, two successive Greek key motives (underlined in Fig 2, each approximately

40 amino acid residues) pair to form a domain The domain fold contains a pair of calcium binding sites While the bc-crystallins of lens (not shown) and lower organisms in Fig 2 contain two domain folds, spheru-lin 3a and NKA48 contain only a single domain fold The stability of these two proteins is highly dependent

on calcium binding [25] The typical domain motives contain a ‘tyrosine corner’ in the domain centre as seen in proteins 3–6 of Fig 2 or slightly displaced as

A

B

C

Fig 3 Knockdown experiments and stage specific expression of

polymalatase mRNA (A) Knockdown of NKA48 mRNA by specific

dsRNA Levels of mRNA relative to that of actin are shown 24 h

after microinjection with dsRNA to NKA48 and with unspecific

con-trol dsRNA to pGEM-5zf(+) vector Standard deviations refer to

experiments in triplicates (B) PMLA content of plasmodia injected

with dsRNA to NKA48 in the RNAi experiment The data are

refer-enced to protein contents Standard deviations are shown for

measurements in triplicates (C) mRNA levels of polymalatase in

different cell types during the life cycle Levels were measured

in terms of cDNA by PCR referenced to a standard as described in

Experimental procedures One-hundred per cent mRNA (plasmodia)

refers to 8.91 pgÆlL)1 standard cDNA Standard deviations are

shown for measurements in triplicates.

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in Protein S (7) or spherulin 3a (2) NKA48 (1)

dif-fers from all of these proteins by not containing a

tyrosine in a corresponding position In contrast to

NKA48, spherulin 3a is stabilized by forming dimers

through disulfide bonds Dimerization is not possible

for NKA48, because it does not contain such

cyste-ines It is concluded that NKA48 is more distant

from two-domain bc-crystallins as is spherulin 3a,

and has evolved from this gene by gene duplication,

as indicated by the high degree of sequence similarity

(Fig 1) This resulted in a structure devoid of the

tyrosine corner and dimerization by disulfide

forma-tion It is also different in structure from spherulin 3a

by 14 amino acid substitutions, eight of them located

in the first two b-strands of the N-terminal half of

NKA48, upstream of the homodimer interface and

accessible for interactions with other macromolecules

It is to be shown how these mutations serve the

par-ticular function of NKA48 in the regulation of

PMLA synthesis

Knockdown analysis of plasmodia with dsRNA to

NKA48 revealed a dramatic decrease in NKA48

mRNA to a residual 1% and a decrease in PMLA to

a residual 12% compared to the contents in reference

plasmodia Because of the high sequence identity of

mRNA for spherulin 3a and spherulin 3b, knockdown

of spherulin 3a mRNA might have also occurred by

this dsRNA treatment However, because spherulin 3a

is not transcribed in the plasmodium [16], this

possibil-ity could not have effected the suppression of PMLA

synthesis

Among other possibilities, this effect on PMLA

synthesis could be the result of loss of induction at

the transcriptional level, of loss of activation of the

synthetase protein itself, or of derepression of

enzyme(s) catalysing PMLA degradation An

interest-ing interplay of NKA48 with spherulin 3a could be

imagined if both proteins bound competitively at the

same loci but only NKA48 was an inducer and⁄ or

activator In a physiologically meaningful mechanism,

spherulin 3a would displace NKA48 during the onset

of spherulation and suppress PMLA synthesizing

activity

Degradation of PMLA during the onset of

spherula-tion is catalysed by enzymatically active forms of

polymalatase in the extraplasmodial fluid [5,10,11]

During plasmodia growth, only catalytic amounts of

polymalatase are contained in the culture medium,

while large amounts of zymogen reside within the

plas-modium Correspondingly, zymogen and polymalatase

with different functions have been proposed, namely a

PMLA hydrolysing variant in the exterior and a

chap-eroning adapter variant in the interior of plasmodia

[7,10,11] Polymalatase activity depends on zymogen activation [10] at the outer surface of plasmodia (unpublished results) The enzymology has been inves-tigated in detail [5,10,11,26,27]

The hydrolytically inactive form or zymogen of polymalatase binds PMLA, chaperons it through the intracellular fluid, thus functioning as an adapter by connecting it with other proteins [7,10], and eventually manages its export into the extracellular fluid (unpub-lished data)

In agreement with these activities, the role of polymalatase and its zymogen is correlated with the synthesis of PMLA by the plasmodium Our results of real-time PCR measurements indicated high levels of mRNA in plasmodia and low levels in both amoebae and spherules The differences parallel the occurrence

of high amounts of polymalatase protein in plasmodia, very low levels in spherules, and the absence of polymalatase protein in amoebae [10] The correlation suggested regulation of synthesis at the transcriptional level

Experimental procedures

Culture conditions for the growth of plasmodia

Microplasmodia of P polycephalum strain M3CVII ATCC

204388 (American type Culture Collection, LGC Promo-chem, Wesel, Germany) were grown axenically in semi-defined medium (SDM) as described [28] Cells were harvested for SSH after 2 days Macroplasmodia were obtained by fusion of 400 lL of packed 2-day-old micro-plasmodia on agar in 13.5-cm Petri dishes according to a previously described method [29] and grown for 24 h in the dark prior to microinjections After injection, they were grown for further 24 h and then harvested for the analyses

of mRNA and PMLA content

Culture conditions for spherule preparation

Spherules were induced by the transfer of 2-day-old micro-plasmodia to a non-nutrient salt medium and were shaken

in the dark for 2 days at 24C as described [30] After replacement with fresh salt medium, spherules were incuba-ted at 24C for 1 day and were harvested for real-time PCR

Culture conditions for the growth of amoebae

DSPB plates (diluted SDM with phosphate buffer [28]) were inoculated with 3· 105

amoebal cysts of the apogamic strain LU352 [31], 100 lL formalin-killed bacteria, and

100 lL Millipore water The plates were incubated at 24C

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for 48 h to allow excystment and were then transferred to

30C After 4 days at 30 C the plates became confluent

and were harvested for SSH and real-time PCR

RNA isolation

To isolate total RNA, amoebae and macroplasmodia were

harvested from the agar plates and immediately frozen in

liquid nitrogen RNA isolation was carried out by using the

QIAGEN RNeasy Mini Kit (Qiagen, Hilden, Germany)

and a maximum of 100 mg frozen cells

PolyA+ RNA was isolated using 85 lL Dynabeads

(Invitrogen, Karlsruhe, Germany) oligo(dT)25 and 25 lg

total RNA and was eluted in 15 lL Tris⁄ HCl (10 mm,

pH 7.5) The eluted mRNA was immediately used for the

first-strand cDNA synthesis

cDNA synthesis

First-strand synthesis reactions were set up with each

con-taining 0.5 lg mRNA, 10 lm oligo(dT) primer and 10 lm

CapFinder oligonucleotide according to the protocol of

Clontech Laboratories 1996 (Mountain View, CA) Reverse

transcription was performed with Rnase H Minus

M-MuLV Reverse Transcriptase (MBI Fermentas, St

Leon-Rot, Germany) After 1 h at 42C, 0.4 lL 100 mm

MnCl2was added, and the sample was incubated for a

fur-ther 15 min The reaction was terminated by heating at

70C for 10 min, the first-strand product was purified

using QIAquick PCR purification Kit (QIAGEN)

Second-strand synthesis reactions were carried out using

AdvantageTM2 PCR Kit (BD Biosciences Clontech,

Moun-tain View, CA) and long-distance PCR (BD SMARTTM

PCR cDNA Synthesis Kit User Manual)

Suppression subtractive hybridization

Differentially expressed cDNAs in plasmodia and amoebae

were identified following the SSH technique described by

Diatchenko et al [32] Plasmodial extract mRNA was used

as tester and amoebal extract mRNA as driver Only

poly(A)+ RNA was used for first-strand cDNA synthesis

PCR reactions were optimized and performed in such a

way that syntheses remained in the exponential phase Care

was taken that at least 25% of total cDNA was ligated

with adaptors on both ends The success of SSH was tested

for an abundantly expressed housekeeping gene (actin

Ppa35 [33], accession number M21500), for a less

abun-dantly expressed gene lig1 [34], and for the known

stage-specific genes actin-fragmin kinase [35], fragmin A [36],

fragmin P [36], and polymalatase (accession no AJ543320)

using primers to the published cDNA sequences Also, the

efficiency of SSH was checked by comparing the number of

PCR cycles necessary to produce equal amounts of actin

cDNA in probes containing equal amounts of either sub-stracted or unsubsub-stracted DNA

Subtracted PCR products were then ligated with pGEM T-vectors (Promega, Mannheim, Germany) and were trans-formed into DH10B competent cells The plasmids were isolated using Nucleospin Plasmid Kit (Machery-Nagel, Du¨ren, Germany) and were sent for sequencing (MWG Biotech, Ebersberg, Germany) The blast program was used for Databases analysis

The stage specificity of the subtracted cDNA sequences was verified by conventional PCR including 20 ng of the above cloned cDNA from SSH, 1· PCR buffer, 25 mm MgCl2, 10 mN dNTP mix, Taq polymerase (2.5 U, MBI Fer-mentas) and 10 lm of each of the following primers For

NKA48: forward, 5¢-GATGCTAACTTCAGCGGAAAC

TC-3¢ For NKA49: forward, 5¢-CTTCCACGACGGAAAC GATGAC-3¢; reverse, 5¢-CTCTCCAACACATGCTGACG TAG-3¢ Cycling conditions were 94 C for 2 min, followed

by 35 cycles of 94C for 30 s, 54 C for 30 s, 72 C for

2 min, and 72C for 10 min The samples were then separ-ated by electrophoresis through 2% agarose gel Sequences and primers of the other SSH products can be obtained on request from the corresponding author

RNA interference

RNAi experiments were carried out with dsRNA to NKA48 by the method essentially as described by Haindl and Holler [14] Specific DNA template to NKA48 for dsRNA synthesis was generated from first-strand cDNA and the following primers (NKA48, accession number

GAAATGTCCGTCCAACAAGGAG-3¢ (forward) and 5¢-GCCTTCTAATACGACTCACTATAGGGACCACGATG ATGGATGAAATG-3¢ (reverse) Both primers contained T7-polymerase promoter at the 5¢ terminus and were cus-tom-synthesized by MWG-Biotech The resulting 294-bp DNA spanned the nucleotides 51–310 of the gene including the origin of transcription, and was used as template for

in vitrodsRNA synthesis as described by Donze and Picard [37] In the case of NKA8, the forward primer was 5¢-GAT GCATAATACGACTCACTATAGGGAGTGCCTTGCAA GGAGTATTG-3¢ and the reverse primer was 5¢-GCCTTC TAATACGACTCACTATAGGGAGCTCGTAATAGCTT TTGGAC-3¢, the resulting DNA spanning nucleotides 21–536 of the gene (accession number DQ017262) For con-trol injections, nonspecific dsRNA was generated by the same method using a PCR-derived fragment with 592 bp, nucleotides 142–734 from the vector pGEM(R)-5zf(+) (Technical Servics, Promega Corporation, Madison, WI, USA) Each knockdown experiment was carried out with

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10 lg dsRNA, microinjected into the veins of

macro-plasmodia After 24 h, the plasmodia were analysed by

real-time PCR

Real-time PCR

The amount of NKA48-specific mRNA in the RNA

inter-ference experiment was measured with reinter-ference to mRNA

expressed for actin Ppa35 gene using the Roche-LightCycler

(Roche, Mannheim, Germany) cDNA was synthesized

from 2 lg total RNA of each sample and reference, and

2 lL of the purified product was subjected to real-time

PCR, each containing 10 lL 2· SYBR Green Master Mix,

10 lm each primer and 6 lL RNase free water using the

following conditions: 15 min 95C activation of

HotS-tarTaq DNA Polymerase and 35 cycles (15 s 94C, 20 s

58C and 20 s 72 C) For actin, primer pairs were

5¢-CATGTGCAAGGCTGGATTTGCTG-3¢ (forward) and

5¢-ACCGACGTATGAGTCCTTTTG-3¢ (reverse) and for

(for-ward), 5¢-CACTTGAGTGTTCTGCTCCAG-3¢ (reverse)

To compare mRNA expression levels of PMLA

hydro-lase in the amoebae, plasmodia and spherules, a PCR

frag-ment derived from the target sequence (polymalatase,

accession number AJ543320) was generated as a standard

for absolute quantification To create the standard, 40 ng

of plasmodial cDNA was used in a conventional PCR

including 1· PCR buffer, 25 mm MgCl2, 10 mm dNTP

mix, Taq polymerase (MBI Fermentas) and 10 lm each

(for-ward) and 5¢-ACTGTGCCATCCGCCTTC-3¢ (reverse)

Cycling conditions were 94C for 2 min, followed by 35

cycles of 94C for 30 s, 55 C for 30 s and 72 C for

2 min The amplified product was purified by

electrophor-esis on 2% agarose gel and using QIAquick Gel

Extrac-tion Kit (QIAGEN) Fifty nanograms pGEM T-vector

was ligated with 16 ng purified PCR product and was

transformed into DH10B competent cells (Bethesda

Research Laboratories, Frederick, MD) Plasmid isolation

was carried out using the Nucleospin Plasmid Kit

(Machery-Nagel) For insert isolation, 12 lg plasmid DNA

was digested with NcoI and SpeI at 37C for 1.5 h and

was analysed on a 2% agarose gel The purified DNA

fragment was used as standard

Total RNA was isolated from cells of the different stages

in the life cycle, and first-strand cDNA synthesis was

per-formed in triplicate as above for mRNAs, but using 2 lg

total RNA Real-time PCR was carried out with 40 ng

cDNA of each sample in parallel with five different

amounts of the standard DNA, using the same primer pair

for polymalatase as above and cycling conditions 95C for

15 min, followed by 35 cycles of 95C for 15 s, 58 C for

20 s, and 72C for 20 s Default settings of the Lightcycler

Software Version 3.5.3 and conditions in the linear range of

the PCR-reaction were ensured

Quantitative analysis of PMLA

Macroplasmodia were harvested, weighed and transferred into a glass homogenizer Two vols lysis buffer (50 mm Tris⁄ HCl pH 7.5, 5 mm NaS2O5, 50 mm EGTA, 10 mm MgCl2, 300 mm NaCl, 0.5% Triton X-100), 1⁄ 25 volume

of protease inhibitor (calculated from the volume of the lysis buffer) and 1⁄ 1000 volume of mercaptoethanol were added The homogenate was transferred to a clean tube

and centrifuged at 20 000 g for 30 min One hundred

microlitres of the clarified lysate was removed and ali-quoted equally into two microcentrifuge tubes One of the two aliquots was hydrolysed with 50 lL 2 m sulfuric acid and incubated at 95C for 1.5 h Then the acid was neutralized with 50 lL of 4 m NaOH The other tube was kept on ice and was used to measure the amount of endogenous malate Polymalic acid was assessed on basis

of the malate dehydrogenase reaction as described [8] Protein was assayed according to the method of Bradford [38]

Acknowledgements

The technical assistance of Hermine Reisner and Sonja Fuchs is greately acknowledged

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