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Tiêu đề Organizational constraints on ste12 cis-elements for a pheromone response in saccharomyces cerevisiae
Tác giả Ting-Cheng Su, Elena Tamarkina, Ivan Sadowski
Trường học University of British Columbia
Chuyên ngành Biochemistry and Molecular Biology
Thể loại báo cáo khoa học
Năm xuất bản 2010
Thành phố Vancouver
Định dạng
Số trang 14
Dung lượng 694,57 KB

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We have systematically examined nucleotides of the consen-sus PRE for binding of wild-type Ste12 to DNA in vitro, as well as the organizational requirements of PREs to produce a pheromon

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pheromone response in Saccharomyces cerevisiae

Ting-Cheng Su1,2, Elena Tamarkina1and Ivan Sadowski1

1 Department of Biochemistry and Molecular Biology, Molecular Epigenetics, LSI, University of British Columbia, Vancouver, Canada

2 Graduate Program in Genetics, University of British Columbia, Vancouver, Canada

Introduction

Ste12 protein of the budding yeast Saccharomyces

cerevisiae has attracted considerable interest as a

model eukaryotic transcription factor because, much

like metazoan factors with a similar function, it

regu-lates multiple distinct classes of genes in response to

combinations of signal transduction pathways In

hap-loid yeast, Ste12 activates genes required for mating

between MATa and MATa cells to form diploids, in

response to peptide pheromones produced by the

opposite mating type [1] Ste12 also activates genes necessary for filamentous growth in response to nutri-ent limitation in a process known as invasive or pseudohyphal growth In both cases, Ste12 activity is regulated by two inhibitor proteins, Dig1 and Dig2 [2], whose functions are considered to be antagonized

by a prototypical mitogen-activated protein kinase (MAPK) signaling cascade [3–5] Genes induced by pheromones include those that encode many of the

Keywords

gene regulation; pheromone response; PRE,

Ste12; yeast

Correspondence

I Sadowski, Department of Biochemistry

and Molecular Biology, University of British

Columbia, 2350 Health Sciences Mall,

Vancouver, BC, V6T 1Z3, Canada

Fax: +1 604 822 9311

Tel: +1 604 822 4524

E-mail: sadowski@interchange.ubc.ca

(Received 1 April 2010, revised 30 May

2010, accepted 3 June 2010)

doi:10.1111/j.1742-4658.2010.07728.x

Ste12 of Saccharomyces cerevisiae binds to pheromone-response cis-elements (PREs) to regulate several classes of genes Genes induced by pheromones require multimerization of Ste12 for binding of at least two PREs on respon-sive promoters We have systematically examined nucleotides of the consen-sus PRE for binding of wild-type Ste12 to DNA in vitro, as well as the organizational requirements of PREs to produce a pheromone response

in vivo Ste12 binds as a monomer to a single PRE in vitro, and two PREs upstream of a minimal core promoter cause induction that is proportional to their relative affinity for Ste12 in vitro Although consensus PREs are arranged in a variety of configurations in the promoters of responsive genes,

we find that there are severe constraints with respect to how they can be posi-tioned in an artificial promoter to cause induction Two closely-spaced PREs can induce transcription in a directly-repeated or tail-to-tail orientation, although PREs separated by at least 40 nucleotides are capable of inducing transcription when oriented in a head-to-head or tail-to-tail configuration

We characterize several examples of promoters that bear multiple consensus PREs or a single PRE in combination with a PRE-like sequence that match these requirements A significant number of responsive genes appear to pos-sess only a single PRE, or PREs in configurations that would not be expected

to enable induction, and we suggest that, for many pheromone-responsive genes, Ste12 must activate transcription by binding to cryptic or sub-optimal sites on DNA, or may require interaction with additional uncharacterized DNA bound factors

Abbreviations

EMSA, electrophoretic mobility shift assay; FRE, filamentous response element; MAPK, mitogen-activated protein kinase; PRE, pheromone response element; RCS, relative competition strength; TCS, Tec1 binding site.

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mating pheromone response pathway components,

proteins that cause G1 cell cycle arrest along with the

morphological alterations necessary for mating, and

gene products that eventually contribute to

down-regulation of the pheromone response, allowing

re-entry into the cell cycle following mating [6,7]

Nutrient limitation induces filamentous growth

through up-regulation of genes that alter cell cycle

progression, budding pattern, formation of an

elon-gated cellular morphology, increased agar invasiveness

and enhanced cellular adhesion [8,9] The regulation

of this response involves Ste12 in combination with a

host of additional DNA bound factors, including

Tec1, Phd1, Flo8 and Sok2 [10], through signals

transmitted by the pheromone response MAPK,

Ras-cAMP-protein kinase A and Snf1⁄ AMP-activated

pro-tein kinase pathways [11,12]

The capacity of Ste12 to activate these multiple

dis-tinct classes of genes in response to pheromone and

nutrient signals is considered to involve the binding to

DNA at pheromone-response elements (PREs), with

the consensus 5¢-ATGAAACA-3¢ [13] in combination

with additional factors bound to adjacent sites [7,14–

16] For example, the function of Ste12 with respect to

the activation of genes involved in filamentous growth

requires interaction with another transcription factor,

Tec1 [17] Some filamentous response genes have a

PRE adjacent to a Tec1 binding site (TCS) element,

and this combination of cis-elements is designated a

fil-amentous response element (FRE) [15] Ste12 and

Tec1 bind cooperatively to FREs from the TEC1,

FLO11and TY1 promoters in vitro [15] Several

differ-ent classes of genes can also be distinguished amongst

the pheromone-responsive genes MATa and

MATa-specific pheromone-inducible genes, including those

encoding the peptide-mating pheromones and their

receptors, appear to be regulated by Ste12 bound to

DNA in combination with Mcm1 and a1 protein,

respectively [14,16] By contrast, pheromone-responsive

genes common to both MATa and MATa haploids are

considered to require multimerization of Ste12 for

binding to multiple adjacent PREs Additionally, genes

that become activated later during the

phero-mone response, such as KAR3 and PRM2 involved in

karyogamy, may be regulated by Ste12 in combination

with Kar4, whose expression is itself induced by a

pheromone [18]

Despite having served as an important model for

eukaryotic signal-responsive transcription factors for

several decades, there is presently little mechanistic or

structural information available regarding how Ste12

forms multimers and interacts with additional factors

for the regulation of these different classes of genes

Global localization of Ste12 indicates that there are more than 800 target genes in untreated cells [7,19,20], presumably representing those involved in both pheromone and filamentous responses It is gen-erally accepted that Ste12 activates genes for the fila-mentous response when bound cooperatively to DNA

at PREs closely positioned to a binding site for Tec1 [15,21] However, an examination of the arrangement

of Ste12 and Tec1 binding sites in promoters of this class reveals a variety of spacing and orientations between PREs and TCS elements, and the FRE-like orientation as characterized from the TY1 and TEC1 promoters is quite rare An implication of this obser-vation is that cooperative interaction between Ste12 and Tec1 must be accommodated by a variety of ori-entations between their sites Similarly, haploid-specific pheromone-responsive genes, common to both MATa and MATa haploid cells, are presumed to be solely activated by Ste12 multimers bound to adjacent PREs [2] Global expression analysis indicates that more than 200 genes become induced within 30 min of treatment with mating pheromone [6,7] Examination of the promoters of a group of the most strongly induced pheromone-responsive genes does not reveal a simple correlation between either the number or arrangement

of predicted consensus pheromone response elements (PREs) and the relative level of inducibility (Fig 1), and there are also a significant number of pheromone-induced genes that appear to completely lack PREs (not shown in Fig 1) [6,7] It might be concluded that there are few restrictions on the arrangement of multiple PREs to enable cooperative interaction for DNA bind-ing of Ste12 for activation of pheromone response Most analyses of Ste12- and pheromone-responsive transcription have been performed in the context of the FUS1 promoter, which contains four PREs within

a 100 nucleotide upstream sequence (Fig 1), and whose expression is strongly induced in both MATa and MATa haploid cells in response to a- and a-factor, respectively [13,22] Within the FUS1 promoter,

a single PRE was found to confer some responsiveness

to pheromone, although a minimum of two were shown

to be necessary for a significant response Deletion of all four PREs eliminated the response to pheromone, and the response could be restored by insertion

of oligonucleotides bearing the PRE consensus [13] The contribution of spatial and orientation differences between multiple PREs to produce pheromone response was not examined in this previous study and,

in any case, the experiments were performed using high copy reporter genes, making it difficult to com-pare requirements for the expression of chromosomal genes

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Given the apparently relaxed organizational

require-ments for PREs on pheromone-responsive genes, we

expected that it should be relatively trivial to produce

artificial pheromone-responsive promoters Instead, in

the present study, we find that there are rather

strin-gent constraints on how two consensus PREs can be

positioned within a minimal artificial promoter

to enable a response to pheromone Wild-type Ste12

binds to a single PRE as a monomer in vitro, and a

minimum of two PREs positioned in specific

orienta-tions are necessary to cause induction in vivo We find

that there is a direct linear relationship between the

response to pheromone and the combined strength of the two PREs positioned in an optimal orientation Many natural pheromone-responsive promoters do not possess PREs in optimal orientations [7] and, for these genes, we propose that Ste12 must activate transcrip-tion when bound to cryptic or sub-optimal sites, or in cooperation with additional uncharacterized transcrip-tion factors

Results

Recombinant wild-type Ste12 binds as a monomer to a single PRE in vitro Several previous studies have examined the binding of recombinant maltose-binding domain-Ste12 fusions or Ste12 DNA-binding domain fragments to an FRE [15], or the FUS1 promoter in vitro [23] We have expressed 6-His-Ste12 in insect cells using baculovirus, and found that the protein is capable of forming com-plexes in vitro with an oligonucleotide (S26D) contain-ing two directly-repeated PREs from the FUS1 promoter, previously shown to be capable of confer-ring pheromone-responsiveness in vivo (Fig 2A, lane 2) Antibodies recognizing various Ste12 regions inhi-bit the formation of the complex (Fig 2A, lanes 8–10) but not control antibodies (Fig 2A, lane 11) Addi-tionally, competition with unlabeled wild-type S26D oligo inhibits complex formation (Fig 2A, lane 3) but not competition with an oligonucleotide bearing a cis-element for an unrelated transcription factor (Fig 2A, lane 6), demonstrating that recombinant wild-type Ste12 protein produced in insect cells forms a sequence-specific interaction with a PRE-containing oligonucleotide in vitro The complex that we observed

in an electrophoretic mobility shift assay (EMSA) likely represents the binding of Ste12 to a single PRE

on the oligo because competition with an unlabeled competitor bearing a mutation of only one of the PREs does not prevent its formation (Fig 2A, lane 4), although a competitor bearing mutations of both PREs does not compete for binding of Ste12 (Fig 2A, lane 5) Furthermore, oligonucleotide probes contain-ing only a scontain-ingle PRE produce a complex with identi-cal mobility to that produced by oligos with two PREs (not shown; Figs 3 and 4) Recombinant full-length Ste12 appears to have an autoinhibitory effect because the addition of greater concentrations of pro-tein causes the loss of DNA binding activity altogether (not shown), rather than producing multiple com-plexes This effect appears to require the C-terminus because a truncated derivative lacking the C-terminal

73 amino acids is able to form multiple complexes on

Fig 1 Organization of a selection of strongly inducible

pheromone-responsive promoters Schematic representation of the organization

of consensus PREs within nine of the 35 most strongly induced

pheromone response genes (excluding pseudogenes and genes

without obvious PREs), as identified by global expression analysis

(30 min of a-factor treatment) [6,7] Numbers between any two

PREs indicate the spacing in nucleotides, whereas the number

furthest to the right indicates the distance to the translation start

site The promoters are arranged in the relative order of inducibility

(top to bottom) STE12 is within the top 100 pheromone-inducible

genes, and was included here because we have examined this

promoter in some detail.

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this same probe (not shown) By contrast, recombinant

Ste12 and Tec1, both produced in insect cells, are

capable of binding individually to an FRE-containing

oligonucleotide in vitro (Fig 2C, lanes 1 and 2), and

form a higher-order complex when added together in

binding reactions (Fig 2C, lane 3) This indicates that

recombinant Ste12, although capable of forming

terni-ary complexes with Tec1 in vitro, is excluded from

forming multimerized complexes with two

closely-spaced PREs in vitro, which indicates that the binding

of wild-type Ste12 to multiple PREs in vivo may

require additional factors or post-translational

modifi-cations We are currently investigating the significance

of this feature with respect to the pheromone response,

and we discuss the implications of these observations

below

To determine the stoichiometry of Ste12 bound to a

single PRE in vitro, we expressed a series of C-terminal

truncations for use in the analysis of hetero-complex

formation Wild-type Ste12 protein produced in insect

cells (Fig 3A, lane 1) or truncated versions of Ste12

containing residues 1–476 (Fig 3A, lane 2), 1–350

(Fig 3A, lane 3) or 1–215 (Fig 3A, lane 4), produced

by in vitro transcription and translation, each were capable of forming complexes with a single PRE-con-taining oligo in EMSA We then mixed the full-length protein together with the truncated forms in vitro prior

to adding the labeled oligonucleotide probe and per-forming EMSA In these experiments, none of the truncated species caused the production of an inter-mediate complex in combination with wild-type Ste12 (Fig 3A, lanes 5–7), which would be expected if there were multiple protein molecules bound to a single PRE Because it is possible that co-translation of Ste12 may be necessary for hetero-complex formation, as is the case with proteins such as GCN4 and GAL4 [24,25], we also performed this experiment using co-translation of the truncated Ste12 derivatives (Fig 3B)

We found that when the 1–476 and 1–350 or 1–350 and 1–215 derivatives are produced by co-translation (Fig 3B, lanes 4 and 8, respectively), we also do not observe intermediate-sized complexes that would indi-cate formation of hetero-multimers From these results, we argue that Ste12 protein likely binds to a single PRE as a monomer

Sequence requirement of the PRE for binding Ste12 in vitro

The sequence requirements for binding of Ste12 to DNA have largely been inferred from a comparative

Fig 3 Ste12 binds to a PRE as a monomer (A) EMSA reactions were performed with a labeled oligo containing a single PRE (IS1430 ⁄ 1431) and full-length Ste12 (lane 1), Ste12 1–476 (lane 2), Ste12 1–350 (lane 3) and Ste12 1–215 (lane 4) Full-length Ste12 was mixed with 1–476 (lane 5), 1–350 (lane 6) or 1–215 (lane 7) prior to adding the labeled oligo and performing the binding reac-tion (B) Reactions were performed with in vitro translated Ste12 1–476 (lanes 1, 3 and 4), 1–350 (lanes 2, 3, 4, 5, 7 and 8) or 1–215 (lanes 6–8) The Ste12 derivatives were synthesized separately

in vitro and then mixed prior to EMSA (lanes 3 and 7) or were co-translated (lanes 4 and 8).

B

Fig 2 Recombinant Ste12 produced in insect cells binds to a

sin-gle PRE in vitro (A) EMSA reactions were performed with extracts

of Sf21 insect cells producing recombinant Ste12 protein (lanes

2–11) or uninfected cells (lane 1) using an oligonucleotide probe

containing two directly-repeated PREs (sites II and III from the

FUS1 promoter, S26D) Unlabeled oligonucleotide competitor oligos

were added at ten-fold molar excess (lanes 3–5), as indicated in

(B) The binding reaction in lane 6 contained a ten-fold molar excess

of an RBEIII oligonucleotide [37] Antibodies against Ste12 (lanes

8–10) or preimmune serum (lane 11) were added to the binding

reactions (C) Full-length recombinant Ste12 and Tec1 form a

com-plex on an FRE in vitro EMSA reactions using a labeled FRE probe

(CN140 ⁄ 141) derived from the TY1 LTR were performed with

Ste12 (lane 1), Tec1-flag (lane 2) or both Ste12 and Tec-1 flag

(lanes 3 and 4) Anti-flag sera were added to the binding reaction in

lane 4.

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analysis of pheromone-responsive promoters and

geno-mic localization of Ste12 protein in vivo [7,10,19] To

characterize residues of the PRE that are necessary for

affinity of Ste12 in vitro, we performed a systematic

analysis using competitions with mutant

oligonucleo-tides in EMSA (Fig 4A) Within the eight nucleotide

consensus (ATGAAACA), we found that mutation of

each of the residues impairs the ability to compete for binding to the wild-type oligo (Fig 4A, PRE mutants)

In particular, mutations of residues A5 and A6 of the central AAA trinucleotide to G significantly impair competition (Fig 4A, lines 5 and 6), as does substitu-tion of G3 with a pyrimidine (C or T) (Fig 4A, line 2; Table 1) We also compared the relative affinities of the four PREs within the FUS1 promoter (Fig 4B, designated I, II, III and IV, 5¢–3¢, top) Amongst these, site II is identical to the eight nucleotide consensus, sites III and IV have substitutions of the outer 3¢ and 5¢ nucleotides, respectively, and site I has a substitu-tion of A5 within the AAA trinucleotide Using com-petition experiments, we were able to rank the relative strengths of PREs within the FUS1 promoter as sites

II, IV, III and I (Fig 4B, strongest to weakest; Table 1)

Because higher concentrations of recombinant Ste12 produce an autoinhibitory effect, we were unable to determine affinity constants using EMSA with this reagent However, for each mutant oligonucleotide, we calculated a relative competition strength (RCS) value, which represents the ratio of competitor oligonucleo-tide required to compete for 50% binding of total Ste12 relative to the consensus oligonucleotide within the same experiment (Fig S1 and Table 1) From the RCS values, we predict the relative contribution of each nucleotide within the consensus PRE for binding

of wild-type Ste12 in vitro, as shown in Fig 4C

Relative affinity of Ste12 for PREs in vitro correlates directly with the pheromone response

in vivo

To determine by how much the relative affinity of Ste12 for PREs in vitro contributes to the pheromone response in vivo, we inserted oligonucleotides bearing the consensus or mutant PREs into a reporter with a minimal GAL1 core promoter upstream of LacZ, which were integrated in single copy at a lys2 disrup-tion We found that none of the PREs inserted individ-ually upstream of the GAL1 core element were capable

of inducing a response to pheromone, even with the strongest of the PREs from the FUS1 promoter (not shown) By contrast, reporters with an insertion of two identical directly-repeated PREs, in either orientation relative to the transcriptional start site (not shown), and arranged in the same context as FUS1 PREs II and III (Fig 4B), all produced a response to phero-mone and, interestingly, the level of inducibility corre-lated with the RCS values for the PREs as determined

in vitro (Fig 5A) Accordingly, a duplicated PRE with

a substitution of residue A5 of the central AAA

A

B

C

Fig 4 Nucleotides required for binding of full-length Ste12 to the

consensus PRE in vitro (A) EMSA reactions were performed with

recombinant wild-type Ste12 and a labeled oligonucleotide bearing

a single consensus PRE (RS010⁄ 011) Binding reactions contained

no competitor (lane 1), or a 0.625- (lanes 2 and 7), 1.25- (lanes 3

and 8), 2.5- (lanes 4 and 9), 5- (lanes 5 and 10) or 10- (lanes 6 and

11) fold molar excess of unlabeled consensus oligo (lanes 2–6) or

the indicated mutant oligos (lanes 7–11) Mutant oligos (lines 1–7)

contained a single nucleotide substitution from the consensus PRE

(Table S1) (B) The sequence of the FUS1 promoter indicating the

position of four PREs (designated sites I, II, III and IV, 5¢–3¢) EMSA

reactions were performed as in (A) but using a labeled

oligonucleo-tide bearing PRE IV (IS1428 ⁄ 1429), and with the unlabeled

compet-itors as indicated (C) The RCS was calculated for each mutant

oligo (Table 1) The effect that mutation of each nucleotide of the

consensus PRE has on the binding of Ste12 in vitro is indicated

proportional to the font size for each residue.

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trinucleotide to G, which seriously inhibits binding of

Ste12 in vitro, produces a small but detectable level of

inducibility (Fig 5A, line 4), whereas the duplicated

consensus PRE causes a level of pheromone response

comparable to the full FUS1 promoter (Fig 5A, lines

1 and 5)

Because the inducibility of reporters bearing

two directly-repeated PREs appeared to be

approxi-mately proportional to the relative affinity for Ste12

in vitro, we were interested in determining the extent

that mutations of one PRE would have in combination

with a strong consensus element To address this, we

introduced mutations of the central AAA trinucleotide

into the 3¢ PRE of the artificial reporter constructs

Mutation of the central A5 residue of the trinucleotide,

causes an approximately three-fold reduction in

phero-mone inducibility in combination with a consensus

PRE (compare Fig 5B, line 1, with Fig 5A, line 1)

Mutation of two of the central A residues

compro-mises the response by approximately ten-fold (Fig 5B,

line 2), and a PRE bearing substitution of all three A

residues completely prevents the response to

phero-mone (lines 3–5) The latter mutation also completely

prevents binding of Ste12 in vitro (not shown) and, in

effect, the reporters indicated in lines 4 and 5 of

Fig 5B possess only a single functional PRE We also

examined the effect that mutations in both

directly-repeated PREs have on pheromone response, and

observed that inducibility was reduced significantly

when both elements have mutations that limit binding

of Ste12 in vitro For example, directly-repeated PREs

with substitutions of residues A1 and A8, respectively,

comprising mutations that have a relatively minor effect on binding Ste12 in vitro, cause an approxi-mately four-fold defect in inducibility relative to two consensus PREs (Fig 5C, line 5) Combinations of PREs that have more serious defects in binding Ste12 produce proportionally less response (Fig 5C, lines 6 and 7), although even two quite weak directly-repeated PREs retain a detectable level of inducibility (Fig 5C, line 8) These results demonstrate that a significant

Table 1 RCS of mutant PREs for binding of wild-type Ste12 to a

PRE consensus (ATGAAACA) in vitro.

a

PREs represented in the FUS1 promoter (Fig 4B).bRCS for each

oligo was calculated from the concentration of unlabeled

competi-tor oligonucleotide required to compete 50% of total Ste12 protein

bound to the consensus PRE, relative to competition in the same

experiment with a wild-type PRE (Fig S1).cConcentrations of oligo

required for 50% competition was calculated by extrapolation.

A

B

C

Fig 5 The pheromone response conferred by two directly-repeated PREs in vivo is proportional to their relative affinity for Ste12 in vitro (A) Strains bearing single-copy integrations of a mini-mal GAL1-LacZ reporter bearing two copies of the indicated PRE (lines 1–4) were left untreated (red bars) or treated with a-factor for

60 min (blue bars) prior to harvesting the cells and assaying b-galac-tosidase activity The shading of the boxes containing the PRE sequence indicates the relative competition strength for Ste12

in vitro, with the stronger PREs being shaded darker and the weaker PREs shaded lighter Line 5 shows results from a strain bearing the full FUS1-LacZ promoter (B) Reporter genes bearing a consensus PRE and PREs containing substitutions of the central AAA trinucleotide were assayed as in (A) (C) Combinations of consensus PREs and PREs bearing the indicated mutations were assayed in the same context as described above.

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response to pheromone can be conferred by a single

strong consensus PRE in combination with much

weaker adjacent PREs, with a level of inducibility

proportional to the relative strength of the second

PRE Additionally, duplicated PREs with substitutions

that inhibit Ste12 binding are capable of inducing a

response to pheromone, but at significantly lower

levels Interestingly, when we examined the effect of

the combined RCS of two directly-repeated PREs on

the response to pheromone, we observed a direct and

simple linear relationship between the product of the

RCS values and pheromone responsiveness (Fig 6)

This analysis indicates that, in the context of the

mini-mal GAL1 promoter, the limiting factor for

transcrip-tional activation in pheromone-treated cells appears to

be binding of Ste12 multimers to DNA

Organizational constraints on multiple PREs for a

pheromone response

When examining the promoters of some of the most

strongly induced pheromone response genes (Fig 1),

we noted that PREs are arranged in a variety of

con-figurations Most promoters have PREs in a

directly-repeated orientation, although there are many

instances of PREs arranged in a tail-to-tail

configura-tion (PRM6, FUS1, AGA1 and STE12) Also, there is

considerable variability in spacing between multiple

PREs (Fig 1) To examine the significance that these

differences in configuration have for pheromone

response, we compared the responses of a GAL1 mini-mal promoter bearing two consensus PREs positioned

at different orientations with respect to each other (Fig 7) In the FUS1 promoter, two PREs (sites II and III) are positioned in a directly-repeated orienta-tion separated by three nucleotides (Fig 7A, line 2) (i.e the same context as the experiments described above) We found that inverting one of the PREs such that they are positioned in a head-to-head orien-tation completely prevented the response to phero-mone (Fig 7A, line 3) By contrast, two consensus PREs from the STE12 promoter positioned in a tail-to-tail configuration, separated by a single nucleotide, caused considerably greater induction compared to the directly-repeated PREs from FUS1 (Fig 7A, line 1) This indicates that there are severe organizational con-straints for closely-positioned PREs that must limit

Fig 6 The combined relative strength of two directly-repeated

PREs produces a proportionally linear response to pheromone.

A combined relative PRE strength for each of the reporter genes

described in Fig 5 was calculated as log(RCSPRE1· RCS PRE2 ) and

plotted against the respective pheromone responsiveness for each

reporter (b-galactosidase activity (· 10)3).

A

B

Fig 7 Organizational constraints on closely-spaced PREs for pheromone response in vivo (A) Pheromone responsiveness of minimal promoters containing PREs II and III from the STE12 pro-moter in a tail-to-tail orientation (line 1), directly-repeated consensus PREs from the FUS1 promoter (PRE II, line 2) or with the second consensus PRE inverted into a head-to-head orientation (line 3) (B) The consensus PREs from the FUS1 promoter were moved apart

to produce an intervening spacing of ten (lines 7–9), 20 (lines 4–6)

or 40 (lines 1–3) nucleotides, with the orientation of the PREs as indicated.

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binding and activation by Ste12 We then examined

how the spacing between two directly-repeated

consen-sus PREs affects the observed response, and found

that they could not be moved apart without seriously

compromising induction (Fig 7B) Separation of PREs

by even one nucleotide completely prevented

induc-tion, as did separation by three, five, seven (not

shown), 10 or 20 nucleotides (Fig 7B, lines 4–9)

Curiously, however, two PREs spaced 40 nucleotides

apart in either a head-to-head or tail-to-tail orientation

produced a significant level of pheromone response

(Fig 7B, lines 2 and 3, respectively) Taken together,

these results indicate that there must be structural

con-straints on Ste12 that allow binding to closely-spaced

PREs in several different configurations Additionally,

the fact that head-to-head and tail-to-tail PREs

sepa-rated by 40 nucleotides allow induction implies that a

sufficient length of intervening DNA is required to

bend or twist into a conformation enabling an

inter-action between Ste12 proteins bound to these PREs

We discuss the possible implications of these results

further below

PREs from the STE12 promoter demonstrate

organizational constraints

To examine whether the organizational constraints that

we observe on artificially produced arrangements of

PREs are representative of pheromone-responsive

pro-moters in vivo, we examined the contribution of PREs

within the STE12 promoter, which contains four PREs:

three in the forward orientation and one in the reverse

orientation (Fig 1, bottom) We found that a

sub-frag-ment bearing only the three 5¢ elesub-frag-ments (sites I, II and

III) caused an elevated level of basal expression, which

is dependent upon STE12 (Fig 8, basal expression, compare lines 1 and 2) and, furthermore, that a sub-fragment bearing only the inverted PREs II and III could account for almost all pheromone inducibility of the STE12 promoter (Fig 8, pheromone induction, line

1, compare lines 1 and 4) Similarly, mutation of site I had only a small negative effect on the response (Fig 8, line 3), whereas mutation of either sites II or III completely prevented induction (Fig 8, lines 5 and 6) These observations indicate that, although PREs may be scattered throughout the promoters of phero-mone-responsive genes, in some cases, the majority of pheromone response may involve only two properly spaced and oriented binding sites for Ste12

Pheromone response of promoters with a single consensus PRE

Considering the results reported above, we questioned how it is possible that a number of genes amongst those that are strongly induced by pheromone have only a single consensus PRE (Fig 1) [7] CIK1, for example, is one of the most strongly induced genes in pheromone-treated cells, and apparently has only a single consensus PRE We examined the CIK1 pro-moter to determine whether there were potential weaker binding sites for Ste12 falling within the con-straints that we observed on the artificial promoters described above Accordingly, we noted that the CIK1 PRE is positioned only three nucleotides downstream

of a PRE-like sequence with substitution at residues T1 and A6 of the consensus (Figs 4C and 9A, top) A portion of the CIK1 promoter bearing these elements inserted upstream of a minimal promoter was found to

be strongly induced by pheromone, although deletion

Fig 8 Orientation and spacing of PREs contributing to response of the STE12 promoter The sequence of the STE12 promoter region containing the three most distal PREs (designated I, II, and III, 5¢–3¢) is indicated An oligonucleotide representing this sequence, or bearing mutations or deletions as indicated, was inserted upstream of the minimal GAL1 core promoter-LacZ reporter gene The expression of the reporter was measured in untreated cells (basal expression, left) or cells treated with a-factor for 60 min (pheromone induction).

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of the PRE-like sequence completely prevented the

response (Fig 9A), indicating that this element does

contribute to induction by Ste12 multimers in vivo

Similarly, on the PRM3 promoter, we observed the

PRE-like sequence 5¢-ATAAAACA-3¢ 36 nucleotides

upstream of the consensus PRE, positioned in a

head-to-head orientation (Fig 9B) In vitro, we found that

an oligonucleotide bearing this sequence competes for

binding to Ste12 only slightly less efficiently than does

a consensus PRE (Table 1) A region including these

elements inserted upstream of the GAL1 core

pro-moter was responsive to pheromone (Fig 9B, line 1),

although the response was reduced considerably when

the PRE-like sequence was deleted (Fig 9B, line 2)

These results indicate that this PRE-like sequence can

produce a pheromone response by Ste12 multimers ori-ented in a head-to-head conformation approximately

40 nucleotides away from a consensus PRE, and we had demonstrated this effect with the artificial promo-ters Taken together, these results indicate that, for some pheromone-responsive genes, Ste12 must activate transcription from sub-optimal binding sites, in combi-nation with a single consensus PRE whose arrange-ment falls within specific organizational constrains

A

B

Fig 9 A single consensus PRE can confer pheromone

responsive-ness in conjunction with PRE-like sequences (A) Sequence of the

CIK1 promoter region, indicting the consensus PRE and a PRE-like

sequence An oligonucleotide representing this sequence, or

bear-ing a deletion of the PRE-sequence, was inserted upstream of the

minimal GAL1 core promoter-LacZ reporter, and expression was

measured in untreated and pheromone-treated cells (B) Sequence

of the PRM3 promoter indicating the location of a consensus PRE

and PRE-like sequence The pheromone responsiveness of the

min-imal promoter bearing oligonucleotides representing the wild-type

or mutant promoter sequences was measured in untreated and

pheromone-treated cells.

A

B

C

D

Fig 10 Structural constraints on Ste12 for binding closely-posi-tioned PREs Schematic representation of a possible mechanism for the recognition of closely-spaced PREs in different conforma-tions by Ste12 multimers Interaction with directly-repeated PREs, positioned three nucleotides apart (A) or in a tail-to-tail orientation (B) may involve an interaction with C-terminal sequences separated from the N-terminal DNA binding domain by a flexible linker region Some closely-spaced configurations appear to be excluded from binding Ste12 multimers, as in a closely-spaced head-to-head orien-tation (C) Head-to-head and tail-to-tail orienorien-tations may be accom-modated providing that the sites are separated sufficiently to allow bending or twisting of the intervening DNA to enable binding of Ste12 multimers (D).

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We note, however, that we have only examined

sub-fragments for both of these promoters, and there are

likely to be additional factors that contribute to

response In this vein, it is important to note that both

were shown to be Kar4-dependent [18]

Discussion

The pheromone response pathway of Saccharomyces

has provided an important model for understanding

how genes are regulated in response to signals

trans-mitted through MAP kinase cascades However,

despite almost 20 years of intensive research, there

remain many unanswered questions regarding the

func-tion of Ste12, including the molecular mechanisms that

control its activity by upstream MAPKs, how it causes

transcriptional activation, and the nature of its

interac-tion with PREs on DNA To begin addressing the

lat-ter issue, we have performed a systematic analysis of

Ste12 binding to the PRE in vitro, and studied the

rela-tionship between binding affinity and spatial

orienta-tion between two PREs for pheromone responsiveness

in vivo Ste12 likely binds to a single PRE in vitro as a

monomer, and therefore the protein must require

mul-timerization in vivo to bind DNA and activate the

haploid-specific pheromone response because a

mini-mum of two PREs are required

Surprisingly, based on analysis of artificial

promot-ers containing two PREs, there appear to be serious

constraints with respect to how these can be positioned

relative to one another to enable pheromone response

of an artificial promoter Two directly-repeated PREs

cause activation only when located within three

nucle-otides of each other By contrast, PREs inverted in a

tail-to-tail conformation separated by a single

nucleo-tide produce a very strong response Additionally,

PREs oriented in head-to-head or tail-to-tail

configura-tions are only able to cause a pheromone response

when separated by approximately 40 nucleotides

Taken together, these observations indicate that Ste12

must have structural features that can accommodate

multimerization for binding of closely-spaced sites

oriented in several different conformations (Fig 10),

such that binding to closely-positioned PREs in either

a directly-repeated (Fig 10A) or tail-to-tail

conforma-tion (Fig 10B) may form multimers through

interac-tion between surfaces on the Ste12 protein that are

separated from the DNA-binding domain by a flexible

linker in order to accommodate different orientations

Because PREs oriented in a head-to-head manner do

not produce a response, the flexibility of Ste12 may

not be able to accommodate this particular

orienta-tion, or perhaps the N-terminal DNA binding domain

is sterically precluded from such an interaction (Fig 10C) PREs oriented in either a head-to-head or tail-to-tail conformation are capable of inducing a pheromone response if positioned 40 nucleotides apart (i.e approximately four helical turns of DNA), sug-gesting that Ste12 is capable of forming multimers that can bind these configurations, provided that the inter-vening DNA is able to bend or twist into a conforma-tion that can accommodate the interacconforma-tion (Fig 10D)

An additional possibility is that Ste12 multimerization

in vivo, enabling accommodation of various PRE arrangements, may require additional nuclear factors Accordingly, Ste12 was shown to associate on phero-mone response promoters in vivo with both inhibitor proteins Dig1 and Dig2 [2], and so it is possible these proteins facilitate the binding of Ste12 to PREs arranged in various configurations However, we con-sider this to be unlikely concon-sidering that the activation

of Ste12-dependent genes appears to be constitutive in dig1 dig2 null strain backgrounds [3–5], presumably including genes requiring a variety of PRE orientations for a pheromone response

Curiously, recombinant wild-type Ste12 produced in insect cells is incapable of forming multimers on oligos containing two PREs in vitro, despite the fact that the same arrangement of PREs confers a strong response

to pheromone in vivo Furthermore, full-length Ste12 appears to have an autoinhibitory function because high concentrations of protein completely prevent binding to DNA Because the deletion of the C-terminus prevents these effects (not shown), we suggest that multimerization of Ste12 in vivo must be regulated through a mechanism involving the C-terminus Ste12 produced in insect cells becomes phosphorylated on most of the same residues that we have observed in yeast [26,27], and we find that mild treatment with phosphatase in vitro produces slower migrating com-plexes with oligos containing two PREs (T.-C Su and

I Sadowski, unpublished results), suggesting that phosphorylation may regulate the ability to bind multi-ple adjacent PREs By contrast, recombinant wild-type Ste12 does produce terniary complexes with Tec1 on

an FRE-containing oligo in vitro (Fig 2C) These results suggest that activation of haploid-specific pher-omone-responsive genes, but not Ste12⁄ Tec1-respon-sive genes, may require additional regulation in vivo involving dephosphorylation The results obtained in the present study also raise the important question of why two PREs are required for pheromone response if wild-type Ste12 is able to bind to a single PRE in vitro This indicates that either the activation domain of Ste12 is incapable of activating transcription when bound to a single site, or that binding to a single site

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