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Tiêu đề Convulxin induces platelet shape change through myosin light chain kinase and Rho kinase
Tác giả Silvia Riondino, Pier P. Gazzaniga, Fabio M. Pulcinelli
Trường học Università La Sapienza
Chuyên ngành Experimental Medicine and Pathology
Thể loại Báo cáo
Năm xuất bản 2002
Thành phố Rome
Định dạng
Số trang 7
Dung lượng 183,68 KB

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Convulxin induces platelet shape change through myosin light chain kinase and Rho kinase Silvia Riondino, Pier P.. Pulcinelli Department of Experimental Medicine and Pathology, Universit

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Convulxin induces platelet shape change through myosin light chain kinase and Rho kinase

Silvia Riondino, Pier P Gazzaniga and Fabio M Pulcinelli

Department of Experimental Medicine and Pathology, Universita´ La Sapienza, Rome, Italy

Once platelets are activated, the first event to occur is a rapid

change in shape, associated with Ca2+

/calmodulin-dependent myosin light chain (MLC) phosphorylation and

with Rho kinase activation The purpose of this study was to

investigate which is the biochemical pathway that leads to

platelet shape change in response to convulxin, a selective

GpVI activator, and to verify whether MLC

phosphoryla-tion is essential for this process The inhibiphosphoryla-tion of the Ca2+

-dependent pathway by means of the Ca2+chelator BAPTA,

the Ca2+/calmodulin inhibitor W-7 or the cAMP enhancing

drug iloprost reduced about 50% of platelet shape change in

response to convulxin The treatment with either the Rho

kinase inhibitors Y27632 or HA 1077 had no effect on

platelet shape change induced by convulxin When both

Ca2+/calmodulin-dependent and Rho kinase-dependent

pathways were concomitantly inhibited by the combined use

of Y27632 plus BAPTA, W-7 or iloprost, platelet shape change was completely abolished Our findings suggest that convulxin-induced platelet shape change occurs via both pathways, the Ca2+/calmodulin-dependent, which appears

to be more important, and the Rho kinase-dependent one The pattern of MLC phosphorylation was not modified by Rho kinase inhibitors Conversely, the inhibition of the

Ca2+-dependent pathway caused a strong reduction of MLC phosphorylation in BAPTA-treated platelets, and a total inhibition in W-7 or iloprost-treated platelets Our results demonstrate that following Rho kinase-dependent pathway platelet shape change can occur without the involvement of MLC phosphorylation

Keywords: convulxin; cyclic AMP; myosin light chain kin-ase; platelet shape change; Rho kinase

One of the first events to follow platelet functional response

to various stimuli is the rearrangement of cytoskeletal

proteins, such as actin and myosin, with the consequent

change from the discoid to the spheroid shape and the

production of pseudopodia [1] It has been demonstrated

that a crucial event in triggering shape change is myosin

light chain (MLC) phosphorylation [2] The signal

origin-ating from agonist-induced activation can lead to MLC

phosphorylation through two distinct pathways One is the

Ca2+/calmodulin-dependent pathway, subsequent to Ca2+

mobilization and mediated by MLC kinase [3], and the

other is Ca2+-independent, subsequent to the small

GTP-binding protein RhoA activation, and mediated by Rho

kinase [4–6] The Ca2+/calmodulin-dependent pathway

which leads to MLC phosphorylation depends upon the

stimulation of a Gq-coupled receptor and phospholipase C

(PLC) activation This datum has also been supported by

experiments on Gaq-deficient mice platelets [7] On the other

hand, the Ca2+-independent pathway follows the stimula-tion of a G12/G13coupled receptor [4]

The second messenger cAMP also exerts an efficacious action on cytoskeletal rearrangements, by inhibiting actin assembly and focal adhesion in many cell types [8,9] through the decreased phosphorylation of various proteins [10,11] including MLC [12]

In a previous study of our group, it was found that it was possible to by-pass the inhibitory effect of cAMP on the multistep cascade of biochemical and morphological events that result in platelet aggregation, provided a Gq-coupled receptor and a Gi-coupled receptor were activated [12] In the same study it was demonstrated that the activation of PLC was sufficient to elicit full aggregation, in spite of elevated intracellular concentrations of cAMP, in the presence of an activated Giprotein

The activation of a PLC isoform, PLC c2, might be achieved using the snake venom toxin convulxin Convulxin activates platelets through the collagen receptor complex glycoprotein VI (GpVI)/Fc receptor c-chain, leading to tyrosine phosphorylation and activation of syk and PLCc2 [13,14] Following activation of GpVI by convulxin, several adapter molecules are tyrosine phosphorylated and/or recruited into intracellular signalling complexes; many of the adapter proteins associate with the transmembrane adapter LAT [15]

Francischetti and his coworkers demonstrated that cAMP did not inhibit the early onset of convulxin-induced tyrosine-phosphorylation of PLCc2, which also occurs in the presence of the aIIb/b3 antagonist, peptide RGDS, or actin polymerization inhibitors, such as cytochalasin D [16] The purpose of the present study was to investigate the biochemical pathways followed by convulxin in inducing

Correspondence to P Gazzaniga, Department of Experimental

Medicine and Pathology, Universita´ La Sapienza, Viale Regina

Elena 324, 00161 Rome, Italy.

Fax: + 39 064452955, Tel.: + 39 064454820,

E-mail: pierpaolo.gazzaniga@uniroma1.it

Abbreviations: A3P5P, adenosine 3¢-phosphate 5¢-phosphate;

BAPTA, 1,2-bis(2-aminophenoxy)ethane-N,N,N,N-tetraacetic acid;

CP/CPK, creatine phosphate/creatine kinase; HA, 1077

(1-(5-isoquinolinesulfonyl)homopiperazine); MLC, myosin light

chain; MLCK, myosin light chain kinase; PLC, phospholipase C;

W-7, N-(6-aminohexyl)-5-chloro-1-naphtalenesulfonamide.

(Received 3 January 2002, revised 8 October 2002,

accepted 11 October 2002)

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platelet shape change In particular, the roles of Rho kinase

and of MLC kinase have been studied by means of specific

inhibitors in order to asses whether the Rho/Rho kinase

pathway is an additional route in mediating platelet shape

change in response to convulxin, independently of the

Ca2+-dependent pathway

M A T E R I A L S A N D M E T H O D S

Platelet preparation

Blood samples were obtained from informed healthy

volunteers who denied having taken any drugs in the two

weeks before blood sampling and collected in citric acid/

citrate/dextrose-containing tubes [17]

Platelet rich plasma was obtained after centrifugation

(180 g for 15 min) and further centrifuged (800 g for

20 min) to concentrate the platelets (6· 108plateletsÆmL)1)

The concentrated platelets were incubated for 15 min at

37C with 1 mMaspirin (Sigma Chemicals Co., St Louis,

MO, USA) then washed twice in Tyrode’s buffer (137 mM

NaCl, 2.68 mMKCl, 0.42 mMNaH2PO4, 1.7 mMMgCl2)

containing 10 mM Hepes (pH 6.5) and resuspended in

Tyrode’s buffer containing 0.2% (w/v) albumin (bovine

serum fraction V-BSA), 0.1% (w/v) glucose and 10 mM

Hepes (pH 7.35) (all from Sigma Chemicals)

To enhance cAMP levels, platelets were treated with

iloprost (3 lM for 2 min at 37C) (generous gift of

Italfarmaco S.p.a., Italy) This platelet preparation was

further incubated with the ADP scavenger system creatine

phosphate/creatine kinase (CP/CPK) (4 mM and

10 UÆmL)1, respectively, Sigma Chemicals) before the

addi-tion of the agonist Samples were treated with

N-(6-amino-hexyl)-5-chloro-1-naphtalenesulfonamide (W-7) (90 lM) to

inhibit the Ca2+/calmodulin pathway [18,19] (Sigma

Chem-icals) HA 1077(1-(5-isoquinolinesulfonyl)homopiperazine)

(10 lM) [20,21] (BioMol R es Laboratory, Inc., PA, USA)

and Y27632 (10–30 lM) (Calbiochem-Novabiochem San

Diego, CA, USA) were used as Rho-kinase inhibitors

Platelet stimulation was achieved by means of convulxin

(5 ngÆmL)1) (Latoxan, Rosans, France), purified according

to Polgar et al [13]

Platelet shape change

In vitro platelet shape change was evaluated in a four

sample PACKS-4 (Helena Laboratories, Beaumont, TX,

USA) aggregometer using siliconized glass cuvettes at 37C

under continuous stirring Once the full function of the

platelet preparation was tested in response to convulxin

(5 ngÆmL)1), in order to prevent platelet aggregation and

allow shape change to occur, platelets were pretreated with

RGDS (120 lgÆmL)1) which inhibits fibrinogen binding to

the integrin aIIbb3 The magnitude of the shape change was

detected by measuring the maximum decrease in light

transmission and the slope value The last parameter was

obtained from the tangent to the curve and was measured in

millimetres per minute

Changes in intracellular calcium mobilization

The fluorescent changes in intracellular calcium

mobiliza-tion were studied in Fura-2 (Molecular Probes, Eugene,

OR, USA) loaded platelets (3 lMat 37C for 30 min) and monitored in a Kontron SFM 25 spectrofluorimeter thermostatically regulated at 37C Excitation and emission wavelengths were 340 nM and 510 nM, respectively Intra-cellular free calcium concentration was calibrated according

to Grynkiewicz [22]

Preparation of BAPTA-loaded platelets The concentrated platelets were incubated for 30 min at

37C with 1 mM aspirin, 100 lM 1,2-bis(2-aminophen-oxy)ethane-N,N,N,N-tetraacetic acid acetoxymethyl ester (BAPTA-AM) (Molecular Probes), then washed by centri-fugation The platelet preparation was further treated with CP/CPK (4 mM and 10 UÆmL)1, respectively) before the addition of the agonist If the DnM of Ca2+obtained in response to agonist stimulation was higher than 10, the platelet suspension was not used

Myosin light chain phosphorylation MLC phosphorylation was analysed according to Daniel

et al [23] Briefly, aspirinated platelets were resuspended in Tyrode’s buffer at a concentration of 2· 109 cellsÆmL)1 Aliquots of 500 lL were stirred at 37C in an aggrego-meter After 30 s from convulxin stimulation (5 ngÆmL)1) the reaction was stopped by adding 6.6MHClO4; the resulting precipitate was kept for 45 min in ice The pellets were centrifuged at 10 000 g for 2 min and washed twice with ice-cold deionized water The proteins were further centrifuged

at 10 000 g for 2 min and the resulting pellets were dissolved

in 50 lL of sample buffer containing 8Murea, 20 mMTris, (pH 8.6), 122 mM glycine, 5 mM dithiothreitol to which 0.1% (w/v) bromophenol blue dye was added The suspen-ded pellet was sonicated in a PBI Briansonic 220 sonication bath for 30 min Gel electrophoresis was performed in a 10% (w/v) polyacrylamide-urea minigel apparatus (Hoefer Scientific Instruments, San Francisco, CA, UA) The running buffer used in the top chamber was composed of

20 mMTris and 122 mMglycine at pH 8.6 containing 4 mM urea The electrophoresis was stopped 1 h after the blue marker had migrated off the end of the gel Gels were stained in 0.25% (w/v) Coomassie Brilliant Blue (Sigma), destained and dried in an SE 1200 Easy Breeze Air Gel Dryer (Hoefer) apparatus The gels were then scanned using

a Gel Doc 2000 (Bio-Rad Laboratories, Hercules, CA, USA) scanner and the optical densities corresponding to the phosphorylated form of MLC were analysed using the programNIH IMAGE1.62 and reported as mean grey values The results were expressed as the percentage of maximal MLC phosphorylation induced by convulxin

To confirm the identity of the detected band, further sample proteins were transferred to Immobilion-P (Milli-pore) membranes and identified with anti-MLC mono-clonal Ig (Sigma Chemicals), followed by horseradish peroxidase-conjugated secondary antibody and visualized with ECL chemiluminescence reaction reagent (Amersham) and Kodak X-ray film (X-OMAT AR)

R E S U L T S

To investigate the correlation between the increase in intracellular Ca2+ concentration and shape change in

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convulxin-induced platelet activation, we studied platelet

shape change and MLC phosphorylation in experimental

conditions in which either Ca2+/calmodulin or Rho-kinase

pathways were inhibited

The increase in the cytosolic Ca2+concentration, which

occurs normally after convulxin (5 ngÆmL)1) stimulation

(743.6 ± 192.2 DnM), was strongly inhibited in platelets

treated with the cAMP-enhancing drug iloprost (3 lM)

(Fig 1)

Table 1 summarizes the variation in shape change

induced by 5 ngÆmL)1convulxin, indicating the magnitude

and slope of aspirinated platelets in the presence of Ca2+/

calmodulin or Rho-kinase inhibitors, that are also

repre-sentatively shown in Fig 2 The results shown in Fig 2A

demonstrate that when the two pathways were separately

inhibited by treating the platelets with either the calmodulin

inhibitor W-7 (90 lM) or with the Rho kinase inhibitors

HA 1077 (10 lM) or Y27632 (30 lM), we observed only a

slight reduction in the rate of shape change (more

pronounced when the Ca2+-dependent pathway was

inhib-ited) as compared to control, untreated,

convulxin-stimula-ted platelets Then, in order to minimize the cytosolic

concentration of calcium, we treated our platelet

prepar-ation with 5,5¢-dimethyl BAPTA (Fig 2B), and studied

both the magnitude and the slope of the shape change

Under these conditions we found that both were slightly

decreased, with a delay in the initiation of the process A

more pronounced reduction was observed in the presence of

high concentrations of iloprost (3 lM) (Fig 2C) A similar

degree of reduction was observed after the simultaneous

treatment with calmodulin inhibitors and iloprost,

suggest-ing that these agents were actsuggest-ing on a common pathway

However, when iloprost was added to 5,5¢-dimethyl

BAPTA-loaded platelets, both the extent and the rate of

shape change were significantly inhibited (Fig 2C)

A complete inhibition was obtained when both pathways,

Ca2+-dependent and Rho-dependent, were simultaneously

blocked by adding the calmodulin inhibitor W-7 or iloprost

or when the increase in cytosolic Ca2+concentration was

minimized by BAPTA, to HA 1077- or Y27632-treated

platelets

Interestingly, a complete inhibition of platelet shape change was achieved by notably lowering the concentrations

of HA 1077 or Y-27632 when used in combination with W-7 (Table 1)

To avoid any possible interference with platelet shape change caused by released ADP on its receptor P2Y1, we incubated our CP/CPK-treated platelet preparation with

Fig 1 Changes in intracellular calcium concentration in 5 ngÆmL)1 convulxin-stimulated aspirinated platelets Stimulation in the (a) absence and (b) presence of 3 l M iloprost The figure is representative

of three experiments performed.

Table 1 Effects of different inhibitory treatments on platelet shape change in response to 5 ngÆmL)1convulxin stimulation.

*P < 0.05; **P < 0.01.

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the selective P2Y1 inhibitor adenosine 3¢-phosphate

5¢-phosphate (A3P5P) (100 lM for 1 min at 37C) and

obtained the same results as those observed after CP/CPK

treatment alone

This result suggests that the ADP secreted is promptly

scavenged by CP/CPK and that the residual ADP is at too

low a concentration to activate the P2Y1-receptor coupled

pathway

Because MLC phosphorylation has been suggested to be

involved in early processes during platelet activation [24] we

measured the appearance of a 20-kDa band, indicating

MLC phosphorylation consequent to the activation of the

two pathways, Ca2+-dependent and Ca2+-independent,

and determined the action exerted by the different

inhibi-tors Rho kinase inhibition by HA 1077 or Y27632 did not

significantly modify the pattern of MLC phosphorylation

after convulxin stimulation (63.0 ± 10.9 for HA 1077 and

66.33 ± 12.6 for Y-27632 vs 78.6 ± 11.4 mean grey

value), equal to 19.8% and 15% reduction, respectively

(Fig 3A)

The identity of the 20 kDa band detected was confirmed

by immunoblot analysis by means of an anti-MLC

mono-clonal Ig (data not shown)

Inhibition of the increase in cytosolic Ca2+by BAPTA

(Fig 3B) reduced by about 40% the maximum level of

MLC phosphorylation (45.7 ± 9.6 mean grey value vs

78.6 ± 11.4) induced by convulxin It is worth noting that,

since BAPTA treatment might delay the time course of

MLC phosphorylation [5], we performed experiments at 60,

120, 150 and 180 s, but we did not observe any further MLC

phosphorylation (data not shown) Inhibition of calmodulin

by W-7 (90 lM) completely abolished MLC

phosphoryla-tion (Fig 3A), while a certain degree of platelet shape

change was still preserved although significantly reduced

(Table 1)

The increase in intracellular cAMP levels by iloprost completely inhibited MLC phosphorylation (4.2 ± 0.7 mean grey value) (Fig 3C)

When both the Ca2+-dependent and Ca2+-independent pathways were inhibited by the combined treatment with

HA 1077 or Y27632 and W-7 or BAPTA, we did not observe any phosphorylation of MLC

D I S C U S S I O N The initial functional response of platelets to stimuli is represented by shape change, during which phase platelets are subject to cytoskeletal reorganization consequent to the phosphorylation of several contractile proteins It has already been demonstrated that such a phenomenon can occur both in the presence and in the absence of an increase

of cytosolic Ca2+concentration in response to thrombin, ionomycin, the stable prostaglandin endoperoxide analogue U44069 and the thrombin receptor activating peptide [25–27] Other authors [4] observed that the thromboxane A2 synthetic analogue, U46619, was not able to induce a detectable elevation of intracellular Ca2+concentration in the absence of Gaqand that Rho kinase inhibitor Y-27632 and C3 exoenzyme inhibited the U46619-induced MLC phosphorylation in Gaq-deficient mouse platelets These observations led them to conclude that a Rho/Rho kinase pathway regulating MLC phosphorylation operated in platelets and that Rho kinase mediates the Ca2+ -independ-ent pathway The dichotomous regulation of MLC phos-phorylation and shape change by Rho kinase and calcium in human platelets was demonstrated by other studies carried out with several agonists, different from convulxin [5,6,28] Elevated cAMP and the consequent activation of protein kinase A affects cell morphology, inducing the loss of actin stress fibres and their detachment from the underlying

Fig 2 Platelet shape change in response to

5 ngÆmL)1convulxin (A) Shape change in the

presence of the calmodulin inhibitor W-7

(90 l M ) or Rho kinase inhibitors HA 1077

(10 l M ) and Y-27632 (30 l M ) in aspirinated,

RGDS-treated, control platelets The

response to convulxin stimulation in the

presence of the cited inhibitors of platelets

loaded with 100 l M BAPTA for 30 min at

37 C (B) or treated with 3 l M iloprost for

2 min at 37 C (C) The figure is

representative of four experiments

performed.

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substratum in many cell types [9,29] Protein kinase A, once

activated, phosphorylates myosin light chain kinase

(MLCK), thus inhibiting its activity and causing a decrease

in MLC phosphorylation [8]

As regards the inhibition exerted by cAMP on the

biochemical pathway leading to platelet shape change

following convulxin activation, the results shown in this

paper demonstrate that it is possible to evoke platelet shape

change even in the presence of elevated intracellular

concentrations of cAMP This observation leads us to

hypothesize that the inhibitory action of cAMP is not exerted at the level of Rho kinase pathway

The conclusion that shape change responses were not due

to ADP release arises from two observations First, the degranulation process was dramatically reduced in convul-xin-stimulated platelets treated with iloprost This showed a reduction of about 86% of the intracellular ATP as compared to convulxin-stimulated platelets untreated with iloprost, as already demonstrated in a previous study from our group [12] Second, in all preparations platelets were treated with the ADP scavenger system CP/CPK to ensure that even traces of ADP released could not interfere with the experiments

Furthermore, experiments employing the inhibitor of the ADP receptor P2Y1(the only receptor involved in platelet shape change induced by ADP [28,30]), A3P5P, demon-strated no additional inhibition as compared to CP/CPK alone (data not shown)

Iloprost treatment strongly affected convulxin-induced MLC phosphorylation, only partially acting on the Ca2+ -dependent pathway which, in fact, was inhibited as dem-onstrated by fluorimetric studies on intracellular Ca2+ mobilization This result also demonstrates that in response

to convulxin Ca2+ mobilization can be inhibited by elevating the levels of intracellular cAMP, as shown in studies using different agonists [31] However, the inhibition

of Ca2+ mobilization alone is not sufficient to cause a complete inhibition of MLC phosphorylation, as demon-strated by the experiments with BAPTA, which only diminished MLC phosphorylation by about 50% The enhanced capability of cAMP of inhibiting MLC phos-phorylation can be explained by the direct action of cAMP

on MLCK [8]

Antagonizing the Ca2+-dependent pathway at different stages by means of the Ca2+/calmodulin inhibitor, W-7, or with the cytosolic Ca2+chelator BAPTA, we observed a good degree of platelet shape change in response to convulxin This indicates that the inhibition exerted by these inhibitors on the Ca2+-dependent pathway did not affect the Rho kinase-dependent one

In fact, while the inhibition of Rho kinase by means of the inhibitors HA 1077 or Y-27632 was without any effect on platelet shape change and MLC phosphorylation induced

by convulxin, a complete inhibition of platelet shape change was achieved only when both pathways were concomitantly inhibited, combining HA 1077 or Y-27632 treatment with iloprost, W-7 or BAPTA treatment These results suggest that both pathways are involved in platelet shape change induced by convulxin and that, since Rho kinase inhibitors are less powerful in interfering with such a process, the

Ca2+-dependent one is more effective

The fact that BAPTA treatment reduced convulxin-induced MLC phosphorylation, while the rate of inhibition

of platelet shape change was similar to that observed after W-7 or iloprost treatment, might be explained by the demonstration that a weak activation of MLC phosphory-lation is not sufficient to elicit shape change [6]

Bauer and coworkers [5] suggested that the GpVI-specific agonist, collagen-related peptide, causes shape change by a mechanism that is entirely dependent on calcium, since it is not affected by the Rho kinase inhibitor Y-27632 Their conclusion delineated the exist-ence of two distinct pathways of myosin phosphorylation

Fig 3 Myosin light chain phosphorylation in response to

aspirin-trea-ted, convulxin stimulated (5 ng mL)1, for 30 s at 37 °C) platelets (A)

Phosphorylation in the presence of calmodulin inhibitor W-7 (90 l M )

or Rho kinase inhibitors HA 1077 (10 l M ) and Y-27632 (30 l M ) The

effects of the same inhibitors on (B) BAPTA-treated (100 l M for

30 min at 37 C) or (C) Iloprost-treated (3 l M for 2 min at 37 C)

platelets The quantitative comparison of the effects of the cited

inhibitors is reported Results are shown as mean ± SEM of four

experiments The level of MLC phosphorylation of resting platelets

was subtracted and the results expressed as percent of the maximal

MLC phosphorylation induced by convulxin alone (78.6 ± 11.4 mean

grey value) (A).

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and platelet shape change, one mediated by Rho kinase

and the other by the Ca2+-dependent activation of MLC

kinase These two pathways could be activated

independ-ently of each other, depending on the type and

concen-tration of the agonist used The Rho kinase-dependent

pathway was stimulated by the activation of thrombin

and thromboxane receptors as opposed to the Ca2+-/

MLC kinase-dependent pathway that was stimulated by

ADP and collagen receptor activation Like collagen,

convulxin has also been described as a GpVI agonist [13]

The different behaviour of this agonist that emerged in

our study might be explained by the fact that it is more

efficacious than collagen-related peptide [15]

Taken together our findings suggest that convulxin is able

to cause shape change by activating both pathways, the

Ca2+-dependent and Rho/Rho kinase-dependent The

former appears to be more important, while the latter

seems to represent an additional route in mediating platelet

shape change and becomes preferentially involved in

response to stimuli that do not produce any increase in

cytosolic Ca2+ concentration, or when the Ca2+

/calmo-dulin-dependent pathway is not operating (Fig 4)

More-over, our results demonstrate that following Rho A/Rho

kinase activation, convulxin-induced platelet shape change can occur without the involvement of MLC phosphoryla-tion

A C K N O W L E D G E M E N T S

This work was partially supported by Grant 60% Ateneo 2000.

We thank Prof Luisa Lenti for her precious help in convulxin purification.

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Fig 4 Hypothetical model depicting the biochemical pathways leading

to platelet shape change following convulxin activation The double bars

indicate the suggested sites of action of the inhibitors employed in our

study.

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