Fixation of Nitrogen by Systems Based on Compounds of the Transition Metals and Inorganic Reducing Agents.. Catalytic Nitrogen Fixation in the Presence of Transition Metal Compounds... F
Trang 1Head of the laboratory: Prof Shur Vladimir Borisovich
Selected Publications
Molecular Nitrogen Fixation in Solutions
1) M.E Vol'pin, V.B Shur Nitrogen Fixation on Complex Catalysts Dokl Akad Nauk SSSR, 156
(1964) 1102-1104
2) M.E Vol'pin, V.B Shur, M.A Ilatovskaya Fixation of Nitrogen by Systems Based on
Dicyclo-pentadienyltitanium Dichloride Izv Akad Nauk SSSR, Ser.Khim., (1964) 1728-1729 [Bull Acad.
Sci USSR., Div Chem Sci., 13 (1964) 1644 (Engl Transl.)].
3) M.E Vol'pin, V.B Shur, L.P Bichin Study of the Fixation of Nitrogen on Complex Catalysts Using 15N Izv Akad Nauk SSSR, Ser.Khim., (1965) 720-721 [Bull Acad Sci USSR, Div Chem
Sci., 14 (1965) 698-699 (Engl Transl.)]
4) M.E Vol'pin, V.B Shur Problems of Chemical Fixation of Molecular Nitrogen Vestnik Akad.
Nauk SSSR, № 1 (1965) 51-58.
5) M.E Vol'pin, A.A Belyi, V.B Shur Fixation of Nitrogen by Systems Based on Compounds of
the Transition Metals and Inorganic Reducing Agents Izv Akad Nauk SSSR, Ser.Khim., (1965) 2225-2226 [Bull Acad Sci USSR, Div Chem Sci., 14 (1965) 2196 (Engl Transl.)].
6) M.E Vol'pin, V.B Shur Nitrogen Fixation by Transition Metal Complexes Nature, 209 (1966)
1236
7) M.E Vol'pin, V.B Shur Preparation of Amines in the Reactions of Molecular Nitrogen Izv.
Akad Nauk SSSR, Ser.Khim., (1966) 1873-1874 [Bull Acad Sci USSR., Div Chem Sci., 15
(1966) 1819 (Engl Transl.)]
8) M.E Vol'pin, V.B Shur, V.N Latyaeva, L.I Vyshinskaya, L.A Shul’gaitser Reaction of
Nitrogen with Bis-Cyclopentadienyl Derivatives of Titanium Izv Akad Nauk SSSR, Ser.Khim., (1966) 385 [Bull Acad Sci USSR., Div Chem Sci., 15 (1966) 364 (Engl Transl.)].
9) M.E Vol'pin, V.B Shur Complexation As a Way of the Activation of Molecular Nitrogen
Zh Vses Khim Obshchestva im D.I Mendeleeva, 12 (1967) 31-41.
10) M.E Vol'pin, V.B Shur, R.V Kudryavtsev, L.A Prodayko Amine Formation in Molecular
Nitrogen Fixation: Nitrogen Insertion into Transition Metal–Carbon Bonds Chem Commun.,
№ 17 (1968) 1038-1040
11) M.E Vol'pin, M.A Ilatovskaya, L.V Kosyakova, V.B Shur Catalytic Nitrogen Fixation in the
Presence of Transition Metal Compounds Dokl Akad Nauk SSSR, 180 (1968) 103-105.
Trang 212) M.E Vol'pin, M.A Ilatovskaya, L.V Kosyakova, V.B Shur Catalytic Fixation of Nitrogen.
Chem Commun., № 18 (1968) 1074-1075.
13) M.E Vol'pin, V.B Shur Chemical Fixation of Molecular Nitrogen Priroda, № 11 (1969) 29-34.
14) M.E Vol'pin, A.A Belyi, N.A Katkov, R.V Kudryavtsev, V.B Shur Formation of Amines from Aromatic Hydrocarbons and Molecular Nitrogen During the Reducing Fixation of N2
Izv Akad Nauk SSSR, Ser.Khim., (1969) 2858-2859 [Bull Acad Sci USSR, Div Chem Sci., 18
(1969) 2697 (Engl Transl.)]
15) M.E Vol'pin, M.A Ilatovskaya, V.B Shur Catalytic Nitrogen Fixation Kinetika i Kataliz, 11
(1970) 333-341
16) M.E Vol'pin, V.B Shur Chemical Fixation of Molecular Nitrogen In: "Organometallic
Reactions" (Eds E Becker and M Tsutsui), Vol 1, J Wiley, N.Y., 1970, p 55-117.
17) M.E Vol'pin, A.A Belyi, V.B Shur, Yu.I Lyakhovetskyi, R.V Kudryavtsev, N.N Bubnov Study
of Nitrogen Fixing Systems Investigation of the Mechanism of the Reduction of Titanocene
Dichloride by Metallic Magnesium Dokl Akad Nauk SSSR, 194 (1970) 577-579.
18) M.E Vol'pin, A.A Belyi, V.B Shur, N.A Katkov, I.M Nekaeva, R.V Kudryavtsev Formation
of Amines from Aromatic Hydrocarbons in Molecular Nitrogen Fixation Reactions Chem.
Commun., № 6 (1971) 246.
19) V.B Shur, E.G Berkovich, M.E Vol'pin Formation of Aniline During the Thermal
Decomposition of Diphenyltitanocene in the Presence of Nitrogen Izv Akad Nauk SSSR,
Ser.Khim., (1971) 2358 [Bull Acad Sci USSR., Div Chem Sci., 20 (1971) 2248 (Engl Transl.)].
20) V.B Shur, E.G Berkovitch, L.B Vasiljeva, R.V Kudryavtsev, M.E Vol'pin Amine Formation in
the Thermodecomposition of Diaryltitanocenes in the Presence of Dinitrogen J Organomet.
Chem., 78 (1974) 127-132.
21) V.B Shur, E.G Berkovich, S.M Yunusov, Sh.M Mamedov, I.L Nizker, M.E Vol'pin New
Systems Capable of Binding Molecular Nitrogen with the Formation of Amines Izv Akad Nauk
SSSR, Ser.Khim., (1977) 2841 [Bull Acad Sci USSR., Div Chem Sci., 26 (1977) 2630 (Engl.
Transl.)]
22) E.G Berkovich, V.B Shur, M.E Vol'pin, B Lorenz, S Rummel, M Wahren Die Reaktion von
Stickstoff mit Dehydrobenzol in der Koordinationssphäre von Titan Chem Ber., 113 (1980)
70-78
23) M.E Vol'pin, V.B Shur Fixation of Molecular Nitrogen in Aprotic Media In: "New Trends in
the Chemistry of Nitrogen Fixation" (Eds J.Chatt, L.M da Câmara Pina and R.L Richards),
Acad Press, London, 1980, p 67-100
24) M.E Vol'pin, V.B Shur Nitrogen Fixation by Transition Metal Compounds: Results and
Prospects J Organomet Chem., 200 (1980) 319-334.
Trang 325) M.N Bochkarev, A.A Trifonov, G.A Razuvaev, M.A Ilatovskaya, V.B Shur Fixation of
Molecular Nitrogen by Rare-Earth Metal Compounds Izv Akad Nauk SSSR, Ser.Khim., (1986) 1898-1900 [Bull Acad Sci USSR, Div Chem Sci., 35 (1986) 1726-1728 (Engl Transl.)].
26) M.N Bochkarev, A.A Trifonov, G.A Razuvaev, M.A Ilatovskaya, V.B Shur, M.E Vol’pin
Activation of Molecular Nitrogen by Compounds of the Lanthanides Dokl Akad Nauk SSSR,
295 (1987) 1381-1384 [Dokl Chem., 295 (1987) 378-380 (Engl Transl.)].
27) M.E Vol’pin, V.B Shur, E.G Berkovich Transformations of Molecular Nitrogen into Aromatic
Amines under the Action of Titanium Compounds Inorg Chim Acta, 280 (1998) 264-274.
Development of Catalysts for the Low-Temperature Ammonia Synthesis
from Dinitrogen and Dihydrogen
1) M.E Vol'pin, M.A Ilatovskaya, E.I Larikov, M.L Khidekel’, Yu.A Shvetsov, V.B Shur
Nitrogen Fixation by Transition Metal Complexes Activating Molecular Hydrogen Dokl Akad.
Nauk SSSR, 164 (1965) 331-333.
2) M.E Vol'pin, M.A Ilatovskaya, V.B Shur Catalytic Nitrogen Fixation Kinetika i Kataliz, 11
(1970) 333-341
3) M.E Vol'pin, V.B Shur Chemical Fixation of Molecular Nitrogen In: "Organometallic
Reactions" (Eds E Becker and M Tsutsui), Vol 1, J Wiley, N.Y., 1970, p 55-117.
4) V.A Postnikov, L.M Dmitrienko, R.F Ivanova, N.L Dobrolyubova, M.A Golubeva, T.I Gapeeva, Yu.N Novikov, V.B Shur, M.E Vol’pin Investigation of the Catalytic Activity of
Lamellar Graphite-Transition Metal Compounds in the Synthesis of Ammonia Izv Akad Nauk
SSSR, Ser.Khim., (1975) 2642-2646 [Bull Acad Sci USSR., Div Chem Sci., 24 (1975)
2529-2532 (Engl Transl.)]
5) A.V Nefed’ev, R.A Stukan, V.A Postnikov, V.B Shur, Yu.N Novikov, M.E Vol’pin Study of Catalysts for the Synthesis of Ammonia Based on Lamellar Compounds of Graphite with Ferric
Chloride and Potassium by Gamma-Resonance Spectroscopy Method Izv Akad Nauk SSSR,
Ser Khim., (1976) 2376-2378 [Bull Acad Sci USSR., Div Chem Sci., 25 (1976) 2219-2221
(Engl Transl.)]
6) M.E Vol'pin, Yu.N Novikov, V.A Postnikov, V.B Shur, B Bayerl, L Kaden, M Wahren, L.M Dmitrienko, R.A Stukan, A.V Nefed'ev Untersuchungen zur Katalyse der Ammoniak-synthese und des Stickstoffisotopenaustausches dürch Schichtverbindungen von Graphit mit
Eisen, Ruthenium und Osmium Z anorg allg Chem., 428 (1977) 231-236.
7) V.B Shur, S.M Yunusov, M.E Vol'pin Ammonia Synthesis from Nitrogen and Hydrogen Using
Catalysts Based on Potassium Salts of Iron Carbonyl Hydrides and Metallic Potassium Dokl.
Akad Nauk SSSR, 277 (1984) 884-888 [Dokl Chem., 277 (1984) 246-250 (Engl Transl.)].
Trang 48) V.B Shur, S.M Yunusov, S Rummel, M Wahren, M.E Vol'pin Stepwise Synthesis of Ammonia from Nitrogen and Hydrogen by the Action of Catalysts Based on Potassium Salts of
Transition Metal Carbonyl Hydrides and Potassium Metal Dokl Akad Nauk SSSR, 292 (1987) 1409-1413 [Dokl Chem., 292 (1987) 100-103 (Engl Transl.)].
9) I.L Arkhipov, R.A Stukan, S.M Yunusov, B.V Lokshin, M.G Ezernitskaya, V.B Shur, M.E Vol'pin Mössbauer and Infrared Spectroscopic Study of the Reactions of K2[Fe2(CO)8]
under the Influence of Activated Charcoal Metalloorg Khim., 1 (1988) 314-320 [Organomet.
Chem USSR, 1 (1988) 174-177 (Engl Transl.)].
10) K.S Rama Rao, P Kanta Rao, S.K Masthan, E Kaluschnaya, V.B Shur New Type of Carbon Coated Alumina Supports for the Preparation of Highly Active Ruthenium Catalysts for
Ammonia Synthesis Appl Cat., 62 (1990) L19-L22.
11) V.B Shur, S.M Yunusov, E.S Kalyuzhnaya, M.E Vol'pin Ammonia Synthesis Catalysts Derived from Potassium Salts of Ruthenium and Osmium Carbonyl Hydrides Supported on
Activated Charcoal and Metallic Potassium Dokl Akad Nauk SSSR, 320 (1991) 353-356 [Dokl.
Chem., 320 (1991) 254-257 (Engl Transl.)].
12) V.B Shur, S.M Yunusov, M.A Ilatovskaya, S Rummel, M.E Vol'pin Interaction of Ammonia-Synthesis Catalyst, K2[Fe2(CO)8] + K on SKT Carbon, with Dinitrogen in the Absence and
Presence of Dihydrogen Dokl Akad Nauk SSSR, 336 (1994) 631-635 [Dokl Chem., 336 (1994)
116-119 (Engl Transl.)]
13) V.B Shur, S.M Yunusov, M.A Ilatovskaya, S Rummel, M.E Vol'pin Nitrogen Isotope Exchange under Effect of Ammonia Synthesis Catalyst, K2[Fe2(CO)8] + K on SKT Carbon
Dokl Akad Nauk SSSR, 336 (1994) 789-794 [Dokl Chem., 336 (1994) 126-130 (Engl Transl.)].
14) S.M Yunusov, V.A Likholobov, V.B Shur Supported Ammonia Synthesis Catalysts Based on Anionic Ruthenium Cluster K2[Ru4(CO)13] The Promoting Effect of Cesium Nitrate Appl Cat.
A: General, 158 (1997) L35-L39.
15) S.M Yunusov, B.L Moroz, A.S Ivanova, V.A Likholobov, V.B Shur Anionic Ruthenium Cluster K2[Ru4(CO)13] as Precursor of Catalytically Active Ruthenium Particles and Potassium Promoter New Efficient Ammonia Synthesis Catalysts Based on Supported K2[Ru4(CO)13]
J Molec Cat A: Chem., 132 (1998) 263-265.
16) V.B Shur, S.M Yunusov On the Path to Catalysts for the Low-Temperature Ammonia
Synthesis Izv Akad Nauk, Ser Khim., (1998) 796-806 [Russ Chem Bull., 47 (1994) 765-775
(Engl Transl.)]
17) S.M Yunusov, E.S Kalyuzhnaya, H Mahapatra, V.K Puri, V.A Likholobov, V.B Shur Supported Ammonia Synthesis Catalysts Based on Potassium Derivatives of Anionic Ruthenium, Osmium and Iron Carbonyl Clusters The First Catalysts on Carbon Support Exhibiting Activity
Trang 5in Ammonia Synthesis in the Absence of a Specially Added Electron Promoter J Molec Cat A:
Chem., 139 (1999) 219-225.
18) S.M Yunusov, E.S Kalyuzhnaya, B.L Moroz, S.N Agafonova, V.A Likholobov, V.B Shur The Effect of Co and Ir on the Activity of the K2[Fe2(CO8)]- and K2[Ru4(CO)13]-based Systems in Ammonia Synthesis The Synergistic Acceleration of the Ammonia Synthesis over the
K2[Fe2(CO8)] + K Catalysts by Iridium J Molec Cat A: Chem., 165 (2001) 143-149.
19) S.M Yunusov, E.S Kalyuzhnaya, B.L Moroz, S.N Agafonova, V.A Likholobov, V.B Shur The Synergistic Acceleration of the Ammonia Synthesis over the K2[Fe2(CO8)] + K Catalysts on
Carbon “Sibunit” by Rhodium Appl Cat A: General, 218 (2001) 251-256.
20) S.M Yunusov, E.S Kalyuzhnaya, B.L Moroz, A.S Ivanova, T.V Reshetenko, L.B Avdeeva, V.A Likholobov, V.B Shur New Ammonia Synthesis Catalysts Based on Supported Carbonyl Ruthenates as Precursors of Catalytically Active Ruthenium Particles and Potassium Promoter
J Molec Cat A: Chem., 219 (2004) 149-153.
21) A.S Ivanova, E.S Kalyuzhnaya, G.S Litvak, E.M Moroz, S.M Yunusov, V.S Lenenko, B.L Moroz, V.B Shur, V.A Likholobov New Y(La)-M-O Binary Systems (M=Ca, Sr, Ba): Synthesis, Physicochemical Characterization, and Application as the Supports of Ruthenium
Catalysts for Ammonia Synthesis Kinetika i Kataliz, 45 (2004) 574-579 [Kinetics and Catalysis,
45 (2004) 541-546 (Engl Transl.)]
22) Yu.V Larichev, B.L Moroz, E.M Moroz, V.I Zaikovskii, S.M Yunusov, E.S Kalyuzhnaya, V.B Shur, V.I Bukhtiyarov Effect of the Support on the Nature of Metal-Promoter Interactions
in Ru-Cs+/MgO and Ru-Cs+/Al2O3 Catalysts for Ammonia Synthesis Kinetika i Kataliz, 46 (2005) 940-948 [Kinetics and Catalysis, 46 (2005) 891-899 (Engl Transl.)].
23) Yu.V Larichev, B.L Moroz, V.I Zaikovskii, S.M Yunusov, E.S Kalyuzhnaya, V.B Shur, V.I Bukhtiyarov XPS and TEM Studies on the Role of the Support and Alkali Promoter in Ru/MgO and Ru–Cs+/MgO Catalysts for Ammonia Synthesis J Phys Chem C, 111 (2007)
9427-9436
24) S.M Yunusov, E.S Kalyuzhnaya, B.L Moroz, A.S Ivanova, V.B Shur Ammonia Synthesis from Dinitrogen and Dihydrogen over the Catalysts Based on the Supported Mononuclear
Potassium Carbonylruthenate Promoting Effect of Lithium Alkyls Izv Akad Nauk, Ser Khim.,
2011, in press [Russ Chem Bull., Int.Ed., 60 (2011) in press].
Molecular Nitrogen Complexes
1) V.B Shur, I.A Tikhonova, E.F Isaeva, M.E Vol'pin Formation of Nitrogen Complexes by
the Reaction of a Ru(III) Derivative with Monoarylhydrazines Izv Akad Nauk SSSR, Ser Khim., (1971) 2357-2358 [Bull Acad Sci USSR., Div Chem Sci., 20 (1971) 2247 (Engl Transl.)].
Trang 62) V.I Nefedov, V.S Lenenko, V.B Shur, M.E Vol'pin, J.E Salyn, M.A Porai-Koshits Molecular Nitrogen as a Ligand A Study of Dinitrogen Complexes of Transition Metals,
Diazocompounds and Azides by X-Ray Photoelectron Spectroscopy Inorg Chim Acta, 7 (1973)
499-502
3) I.A Tikhonova, K Jähnisch, V.G Andrianov, S.F Byalotskii, Yu.T Struchkov, V.B Shur,
É Schmitz, M.E Vol'pin Reaction of 3,3-Pentamethylenediazirine with Nonacarbonyliron and Aquapentaammine Derivative of Divalent Ruthenium New Pathway to the [Ru(NH3)5H2О]2+
Complex Koord Khim., 2 (1976) 1653-1658 [Sov J Coord Chem., (1976) 1274-1278 (Engl.
Transl.)]
4) V.B Shur, I.A Tikhonova, M.E Vol'pin Formation of Dinitrogen Complexes in the Interaction of the [Ru(NH3)5H2О]2+ Ion with Diazoacetic Ester and Aromatic Diazonium Salts
Koord Khim., 4 (1978) 1248-1255 [Sov J Coord Chem., (1978) (Engl Transl.)].
5) A.L Blumenfel’d, V.S Lenenko, B Lorentz, I Mebius, M Wahren, V.B Shur, M.E Vol’pin Investigation of Diazo Compounds, Azides, and Nitrogen Complexes of Transition Metals by NMR 15N Spectroscopy Dokl Akad Nauk SSSR, 251 (1980) 611-615 [Dokl Chem.,
251 (1980) 143-148 (Engl Transl.)]
6) V.B Shur, I.A Tikhonova, G.G Aleksandrov, Yu.T Struchkov, M.E Vol'pin, E Schmitz,
K Jähnisch The Diazirine Complex [(NH3)5Ru(N2C6H10)]2+: Synthesis, Structure and Conver-sion into the Dinitrogen Complex [(NH3)5RuN2)]2+ Inorg Chim Acta, 44 (1980) L275-L277.
7) V.S Lenenko, A.G Knizhnik, E.I Mysov, V.B Shur, M.E Vol’pin Reduction of Aromatic
Diazo Compounds by Alcohols to Hydrocarbons Catalyzed by the Nitrogen Complex
trans-(Ph2PCH2CH2PPh2)2W(N2)2 Dokl Akad Nauk SSSR, 255 (1980) 1131-1135 [Dokl Chem., 255
(1980) 591-594 (Engl Transl.)]
8) V.S Lenenko, A.P Borisov, V.D Makhaev, E.I Mysov, V.B Shur, M.E Vol’pin New Catalysts for the Reduction of Aromatic Diazo Compounds by Alcohols to Hydrocarbons
Izv Akad Nauk SSSR, Ser Khim., (1983) 947-950 [Bull Acad Sci USSR, Div Chem Sci., 32
(1983) 858-860 (Engl Transl.)]
9) V.B Shur, I.A Tikhonova, M.E Vol'pin Catalytic Oxidation-Reduction Disproportionation
of Phenylhydrazine by the Action of [Ru(NH3)5Cl]Cl2 Izv Akad Nauk SSSR, Ser Khim., (1988) 943-944 [Bull Acad Sci USSR, Div Chem Sci., 37 (1988) 824 (Engl Transl.)].
10) V.S Lenenko, P Kränke, M Wahren, V.B Shur, M.E Vol’pin Acid-Catalyzed Attack of
the Dinitrogen Ligand in the cis-(Ме2PhP)4Mo(N2)2 and trans-(Ph2PCH2CH2PPh2)2W(N2)2
Complexes by Nitronium and Nitrosonium Cations with the Formation of Nitrogen Oxides
Izv Akad Nauk, Ser Khim., (1995) 1340-1346 [Russ Chem Bull., 44 (1995) 1293-1299 (Engl.
Transl.)]
Trang 711) E.G Berkovich, V.S Lenenko, L.I Vyshinskaya, G.A Vasil'eva, V.B Shur, M.E Vol'pin Formation of Aromatic Amines from Dinitrogen Complexes [Cp2TiAr]2N2 (Ar = C6H5,
m-CH3C6H4) J Organomet Chem., 535 (1997) 169-173.
Hexaazabenzene Molecule N 6 and Possible Ways of Its Stabilization
1) E.G Gal’pern, I.V Stankevich, A.L Chistyakov, V.B Shur, M.E Vol’pin Is It Possible to
Stabilize the Hexaazabenzene Cyclic System? Izv Akad Nauk SSSR, Ser Khim., (1987) 1675 [Bull Acad Sci USSR, Div Chem Sci., 36 (1987) 1552 (Engl Transl.)].
2) E.G Gal’pern, I.V Stankevich, A.L Chistyakov, V.B Shur, M.E Vol’pin Possibility of
Stabilizing the Cyclic Hexaazabenzene System Dokl Akad Nauk SSSR, 302 (1988) 1384-1388 [Dokl Chem., 302 (1988) 302-305 (Engl Transl.)].
3) I.V Stankevich, A.L Chistyakov, V.B Shur, M.E Vol’pin Possible Existence of a Cyclic Trimer
of Nitrous Oxide Dokl Akad Nauk SSSR, 313 (1990) 118-120 [Dokl Chem., 313 (1990)
194-195 (Engl Transl.)]
Activation of С–Н Bonds
1) V.N Latyaeva, L.I Vyshinskaya, V.B Shur, L.A Fedorov, M.E Vol'pin Reaction of
Dicyclo-pentadienyldiphenyltitanium with Phenyllithium J Organomet Chem., 16 (1969) 103-109.
2) M.E Vol'pin, A.A Belyi, V.B Shur, Yu.I Lyakhovetsky, R.V Kudryavtsev, N.N Bubnov Study
of Nitrogen Fixing Systems Investigation of the Mechanism of the Reduction of
Titanocenedichloride by Magnesium Dokl Akad Nauk SSSR, 194 (1970) 577-579.
3) M.E Vol'pin, A.A Belyi, V.B Shur, Yu.I Lyakhovetsky, R.V Kudryavtsev, N.N Bubnov
Cyclo-pentadienyl Ligands as a Hydrogen Source in the Formation of Titanium Hydride Complexes J.
Organomet Chem., 27 (1971) C5-C8.
4) V.B Shur, E.G Berkovich, E.I Mysov, M.E Vol’pin Catalytic Activity of Cyclopentadienyl Titanium Complexes in Isotopic Exchange Reactions of Aromatic Hydrocarbons with Molecular
Deuterium Izv Akad Nauk SSSR, Ser Khim., (1987) 2435-2439 [Bull Acad Sci USSR, Div.
Chem Sci., 36 (1987) 2259-2263 (Engl Transl.)].
5) M.A Ilatovskaya, S Rummel, Yu.V Isaev, S.M Yunusov, N.D Lenenko, M Herrmann,
M Wahren, Yu.N Novikov, V.B Shur Lamellar Graphite Compounds with Metallic Potassium
As Catalysts for Deuterium-Hydrogen Exchange in Hydrocarbons Izv Akad Nauk SSSR, Ser.
Khim., (1991) 1935-1936 [Bull Acad Sci USSR., Div Chem Sci., 40 (1991) 1722].
6) S.M Yunusov, S Rummel, M.A Ilatovskaya, M Herrmann, V.A Likholobov, V.B Shur, M.E Vol’pin Activation of Hydrocarbon С–Н Bonds by Catalysts Based on Potassium Salts of
Transition Metal Carbonyl Hydrides on a Carbon Support Metalloorg Khim., 5 (1992)
1395-1396 [Organomet Chem USSR, 5 (1992) 685 (Engl Transl.)].
Trang 87) S Rummel, M.A Ilatovskaya, E.I Mysov, V.S Lenenko, H Langguth, V.B Shur Catalytic Activation of C–H Bonds in Aromatic Hydrocarbons, Ethene, and Methane by the
Naphthalene/Sodium System in Tetrahydrofuran Angew Chem Int Ed Engl., 35 (1996)
2489-2491
8) S Rummel, S.M Yunusov, M.A Ilatovskaya, H Langguth, E.I Mysov, M Wahren, V.A Likholobov, V.B Shur Catalytic Activation of C–H Bonds of Alkanes, Ethene and
Aromatic Hydrocarbons by the Adducts of Active Carbons with Metallic Potassium J Molec.
Cat A: Chem., 132 (1998) 277-280.
9) S Rummel, M.A Ilatovskaya, S.M Yunusov, E.S Kalyuzhnaya, V.B Shur Activation of C–H Bonds of Hydrocarbons by the ArH–Alkali Metal Systems in THF (ArH – Naphthalene,
Biphenyl, Anthracene, Phenanthrene, trans-Stilbene, Pyrene) Alkylation of Naphthalene and Toluene with Ethene J Organomet Chem., 694 (2009) 1459-1466.
10) S Rummel, S.M Yunusov, E.S Kalyuzhnaya, V.B Shur Synergistic Effects of Alkali Metals in the Alkylation of Naphthalene and Toluene with Ethene in the ArH–Alkali Metal Systems in
THF (ArH – Naphthalene, Phenanthrene) J Organomet Chem., 694 (2009) 1467-1472.
Acetylene Complexes of Group IVB Metallocenes
1) V.B Shur, E.G Berkovich, M.E Vol'pin, B Lorenz, M Wahren Interaction of Titanocene Generated in the System Cp2TiCl2 + Mg in THF with Benzyne and Tolane A Novel Route to
Titanaindene and Titanacyclopentadiene Complexes J Organomet Chem., 228 (1982) C36-C38.
2) V.B Shur, S.Z Bernadyuk, V.V Burlakov, V.G Andrianov, A.I Yanovsky, Yu.T Struchkov, M.E Vol'pin Synthesis and X-Ray Structure Determination of an Organometallic Titanoxane [Cp2TiC(Ph)=CH(Ph)]2O Evidence for the Formation of a Titanocene Complex with Tolane
J Organomet Chem., 243 (1983) 157-163.
3) V.B Shur, V.V Burlakov, M.E Vol'pin Synthesis of Unsymmetrical Titanacyclopentadienes by
Reacting a Titanocene Tolan Complex with Acetylenes Izv Akad Nauk SSSR, Ser Khim., (1983) 1929-1930 [Bull Acad Sci USSR, Div Chem Sci., 32 (1983) 1753 (Engl Transl.)]
4) V.B Shur, V.V Burlakov, A.I Yanovsky, P.V Petrovsky, Yu.T Struchkov, M.E Vol'pin Reaction
of a Tolane Complex of Titanocene with Carbonyl Compounds Synthesis of Titanadihydrofuran
Metallacycles J Organomet Chem., 297 (1985) 51-59.
5) V.B Shur, V.V Burlakov, M.E Vol'pin Complex of Titanocene with Tolane Isolation, Spectral
Characteristics, Reactivity J Organomet Chem., 347 (1988) 77-83
6) V.V Burlakov, U Rosenthal, P.V Petrovskii, V.B Shur, M.E Vol'pin A Complex of Titanocene
with Bis(trimethylsilyl)acetylene Metalloorg Khim., 1 (1988) 953-954 [Organomet Chem.
USSR, 1 (1988) 526-527].
Trang 97) U Rosenthal, G Oehme, V.V Burlakov, P.V Petrovskii, V.B Shur, M.E Vol'pin 13C{1H}NMR
Studies of Selected Transition Metal Alkyne Complexes J Organomet Chem., 391 (1990)
119-122
8) V.B Shur, V.V Burlakov, M.E Vol’pin Catalytic Activity of the Titanocene Complex with
Tolane in Homogeneous Hydrogenation of Unsaturated Hydrocarbons J Organomet Chem., 439
(1992) 303-308
9) U Rosenthal, H Görls, V.V Burlakov, V.B Shur, M.E Vol’pin Alkinkomplexe des Titanocens
und Permethyltitanocens ohne zusätzliche Liganden – Erste Structurvergleiche J Organomet.
Chem., 426 (1992) C53-C57.
10) U Rosenthal, A Ohff, M Michalik, H Görls, V.V Burlakov, V.B Shur Transformation of the First Zirconocene Alkyne Complex without an Additional Phosphane Ligand into a Dinuclear σ-Alkenyl Complex by Hydrogen Transfer from η5-C5H5 to the Alkyne Ligand Angew Chem Int.
Ed Engl., 32 (1993) 1193-1195.
11) U Rosenthal, A Ohff, M Michalik, H Görls, V.V Burlakov, V.B Shur Interaction of the Zirconocene Alkyne Complex Cp2Zr(THF).(Me3SiC2SiMe3) and the Binuclear Zirconium -Alkenyl Complex {Cp[-(1:5-C5H4)]ZrC(SiMe3)=CH(SiMe3)}2 with Carbon Dioxide and
Water Organometallics, 12 (1993) 5016-5019.
12) V.V Burlakov, A.V Polyakov, A.I Yanovsky, Yu.T Struchkov, V.B Shur, M.E Vol’pin,
U Rosenthal, H Görls Novel Acetylene Complexes of Titanocene and Permethyltitanocene without Additional Ligands The Synthesis, Spectral Characteristics and X-Ray Diffraction Study
J Organomet Chem., 476 (1994) 197-206.
13) U Rosenthal, A Ohff, W Baumann, A Tillack, H Görls, V.V Burlakov, V.B Shur
Zirkona-dihydrofuran-Komplexe: Darstellung, Structur und Reactivitäts-Betrachtungen J Organomet.
Chem., 484 (1994) 203-207.
14) U Rosenthal, A Ohff, W Baumann, A Tillack, H Görls, V.V Burlakov, V.B Shur Structur, Eigenschaften und NMR-spectroscopische Charakterisierung von Cp2 Zr(Pyridin)-(Me3SiCCSiMe3) Z anorg allg Chem., 621 (1995) 77-83.
15) V.V Burlakov, F.M Dolgushin, A.I Yanovsky, Yu.T Struchkov, V.B Shur, U Rosenthal,
U Thewalt Interaction of Carbon Dioxide with the Bis(trimethylsilyl)acetylene Complex of Permethyltitanocene: Synthesis and Structure of the Binuclear Carbonate Complex of Permethyltitanocene (Cp*2Ti)2CO3 J Organomet Chem., 522 (1996) 241-247.
16) L.I Strunkina, M.Kh Minacheva, P.V Petrovskii, Z.S Klemenkova, B.V Lokshin, V.V Burlakov, V.B Shur Interactions of Hafnocene and Zirconocene Dihydrides with
Trang 10Acetylenes Synthesis of the First Acetylene Complex of Hafnium Izv Akad Nauk, Ser Khim., (1997) 853-856 [Russ Chem Bull., 46 (1997) 820-823 (Engl Transl.)].
17) V.V Burlakov, A.I Yanovsky, Yu.T Struchkov, U Rosenthal, A Spannenberg, R Kempe, O.G Ellert, V.B Shur Interaction of Carbon Dioxide with Acetylene Complexes of Titanocene
Cp2Ti(RC2R) (R=Ph, SiMe3) Synthesis and Structure of Binuclear -Alkenylcarboxylate Complexes of Titanium (III) Cp2TiC(R)=C(R)COOTiCp2 and Unexpected Transformation of These Complexes into Titanafuranone Metallacycles Under the Action of Air Oxygen
J Organomet Chem., 542 (1997) 105-112.
18) V.V Burlakov, A.V Usatov, K.A Lyssenko, M.Yu Antipin, Yu.N Novikov, V.B Shur Synthesis and Structure of the First Fullerene Complex of Titanium Cp2Ti(2-C60) Eur J Inorg.
Chem., (1999) 1855-1857.
19) L.I Strunkina, M.Kh Minacheva, K.A Lyssenko, Z.S Klemenkova, A.Yu Volkonsky, P.V Petrovskii, V.V Burlakov, V.B Shur Interaction of Bis(trimethylsilyl)acetylene Complex of
Titanocene with Mercury Trifluoroacetate Izv Akad Nauk, Ser Khim., (2003) 1299-1301 [Russ.
Chem Bull., Int Ed., 52 (2003) 1372-1375].
Zwitterionic Group IVB Metallocenes
1)V.V Burlakov, S.I Troyanov, A.V Letov, E.I Mysov, G.G Furin, V.B Shur Synthesis of a Zwitterionic Metallocene of a New Type by the Reaction of the Bis(trimethylsilyl)acetylene
Complex of Titanocene with Tris(pentafluorophenyl)borane Izv Akad Nauk, Ser Khim., (1999) 1022-1024 [Russ Chem Bull., 48 (1999) 1012-1013 (Engl Transl.)].
2)V.V Burlakov, S.I Troyanov, A.V Letov, L.I Strunkina, M.Kh Minacheva, G.G Furin,
U Rosenthal, V.B Shur Interaction of Bis(trimethylsilyl)acetylene Complex of Titanocene with Tris(pentafluorophenyl)borane Synthesis and Structure of a New Type of Zwitterionic Metallocene (5-C5H5){5-[C5H4B(C6F5)3]}Ti J Organomet Chem., 598 (2000) 243-247.
3)V.V Burlakov, P.-M Pellny, P Arndt, W Baumann, A Spannenberg, V.B Shur, U Rosenthal Reactions of Permethylmetallocene Alkyne Complexes of Titanium and Zirconium with
Tris(perfluorophenyl)borane J Chem Soc Chem Commun., (2000) 241-242.
4)V.V Burlakov, P Arndt, W Baumann, A Spannenberg, U Rosenthal, A.V Letov, K.A Lyssenko, A.A Korlyukov, L.I Strunkina, M.Kh Minacheva, V.B Shur Synthesis and X-Ray Crystal Structure Determination of New Zwitterionic Complexes of Titanocene
Organometallics, 20 (2001) 4072-4079.
5)A Spannenberg, V.V Burlakov, P Arndt, W Baumann, V.B Shur, U Rosenthal Crystal Structure
of [1,2-ethylene-1,1′-bis(η5-tetrahydroindenyl)][hydroxytris(pentafluorophenyl)borato]titanium (III), C38H24BF15OTi Z Kristallogr NCS, 217 (2002) 546-548.