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Tiêu đề Fermentative lifestyle in yeasts belonging to the Saccharomyces complex
Tác giả Annamaria Merico, Pavol Sulo, Jure Piskur, Concetta Compagno
Trường học University of Milan (Università degli Studi di Milano)
Chuyên ngành Biochemistry / Molecular Biology
Thể loại Research article
Năm xuất bản 2007
Thành phố Milan
Định dạng
Số trang 14
Dung lượng 1,24 MB

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Compagno, Dipartimento di Scienze Biomolecolari e Biotecnologie, Universita` degli Studi di Milano, via Celoria, 26 20133 Milan, Italy Fax: +39 02503 14912 E-mail: concetta.compagno@unim

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Saccharomyces complex

Annamaria Merico1, Pavol Sulo2, Jure Pisˇkur3and Concetta Compagno1

1 Dipartimento di Scienze Biomolecolari e Biotecnologie, Universita` degli Studi di Milano, Milan, Italy

2 Department of Biochemistry, Faculty of Natural Sciences, Comenius University, Bratislava, Slovakia

3 Department of Cell and Organism Biology, Lund University, Sweden

The concentration of oxygen in the environment is

one of the most important factors that regulate

energy conversion in living cells Organisms have

developed multiple processes to optimize the

utiliza-tion of oxygen when its availability is reduced

Accord-ing to the role of oxygen in their metabolism, yeasts

can be classified as: (a) obligate aerobes, displaying

an exclusively respiratory metabolism; (b) facultative

fermentatives, displaying both respiratory and

fermenta-tive metabolism; and (c) obligate fermentafermenta-tives The

ability of yeasts to grow in very oxygen-limited condi-tions is strictly dependent on the ability to perform alcoholic fermentation, allowing reoxidation of NADH generated during glycolysis In Saccharomyces cerevisiae, fermentation predominates over respiration when glucose concentrations are high, even under aerobic conditions Depending on this characteristic, yeasts are classified as positive or Crabtree-negative Thus, in Crabtree-positive yeasts, such as

S cerevisiae, NADH is mainly oxidized in

glucose-Keywords

evolution; fermentation; petite mutants;

redox metabolism; respiration

Correspondence

C Compagno, Dipartimento di Scienze

Biomolecolari e Biotecnologie, Universita`

degli Studi di Milano, via Celoria,

26 20133 Milan, Italy

Fax: +39 02503 14912

E-mail: concetta.compagno@unimi.it

(Received 9 October 2006, revised 24

November 2006, accepted 11 December

2006)

doi:10.1111/j.1742-4658.2007.05645.x

The yeast Saccharomyces cerevisiae is characterized by its ability to: (a) degrade glucose or fructose to ethanol, even in the presence of oxygen (Crabtree effect); (b) grow in the absence of oxygen; and (c) generate respir-atory-deficient mitochondrial mutants, so-called petites How unique are these properties among yeasts in the Saccharomyces clade, and what is their origin? Recent progress in genome sequencing has elucidated the phylo-genetic relationships among yeasts in the Saccharomyces complex, providing

a framework for the understanding of the evolutionary history of several modern traits In this study, we analyzed over 40 yeasts that reflect over

150 million years of evolutionary history for their ability to ferment, grow

in the absence of oxygen, and generate petites A great majority of isolates exhibited good fermentation ability, suggesting that this trait could already

be an intrinsic property of the progenitor yeast We found that lineages that underwent the whole-genome duplication, in general, exhibit a fermentative lifestyle, the Crabtree effect, and the ability to grow without oxygen, and can generate stable petite mutants Some of the pre-genome duplication lin-eages also exhibit some of these traits, but a majority of the tested species are petite-negative, and show a reduced Crabtree effect and a reduced abil-ity to grow in the absence of oxygen It could be that the abilabil-ity to accumu-late ethanol in the presence of oxygen, a gradual independence from oxygen and⁄ or the ability to generate petites were developed later in several line-ages However, these traits have been combined and developed to perfection only in the lineage that underwent the whole-genome duplication and led to the modern Saccharomyces cerevisiae yeast

Abbreviation

EtBr, ethidium bromide.

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rich media by fermentation rather than by respiration,

even in the presence of oxygen This has been

attrib-uted to a limited capacity and⁄ or saturation of the

respiratory route of pyruvate dissimilation [1,2]

Glu-cose metabolism and oxygen can also be related by

the Pasteur effect, which has been defined as the

inhi-bition of fermentative metabolism by oxygen, but in

S cerevisiae this phenomenon is only observable at

low glycolytic fluxes [3] In the Kluyver effect, the

absence of oxygen impairs the utilization of particular

disaccharides, although one or both of the

monosac-charide components can be used anaerobically in

fer-mentation [4] This characteristic seems to be

determined mainly by the activity of sugar carriers

[5] The inhibition of fermentation of glucose as well

as other sugars in the absence of oxygen has been

described as the Custer effect, found in Brettanomyces

intermedius and in Candida utilis [6], and has been

proposed to be due to a redox imbalance The

regula-tory mechanisms behind these phenomena appear to

influence energy metabolism in different ways among

different yeast species

Apart from alcoholic fermentation, the ability to

grow under anaerobic conditions also determined by

other factors Some metabolic pathways require the

presence of molecular oxygen This is true to various

extents for the biosynthesis of sterols and fatty acids,

heme⁄ hemoproteins, NAD, and uracil [7,8] The

abil-ity to translocate ATP produced in the cytoplasm into

mitochondria, and the ability to adjust the redox

bal-ance, play a very important role in independence

from oxygen [9–14] In S cerevisiae, three genes

encode for ATP transporters, AAC1, AAC2 and

AAC3 Deletion of AAC2 and AAC3 is anaerobically

lethal [9–11] Under anaerobic conditions, yeast cells

can achieve redox balance by production of glycerol

[12–14] This means that the nutritional conditions

also have a strong influence on the ability to grow

anaerobically Comparison of species belonging to

several yeast genera for their ability to grow

anaerobi-cally in complex and synthetic minimal media

revealed a superiority of S cerevisiae for growth

under restrictive conditions in terms of strict

anaero-biosis and minimal presence of organic nutrients [15]

The use of cDNA arrays recently provided new

insights into gene networks and pointed out the

essen-tial role of the regulation of gene expression

underly-ing the physiologic response of S cerevisiae to oxygen

deprivation [16,17]

Saccharomyces cerevisiae constantly produces

mutants that are stable during vegetative reproduction

and are characterized by a reduced colony size on

solid media in which a fermentable carbon source is

the limiting factor [18] These mutants are called

‘petites’, and are a special class of respiratory-deficient mutants characterized by large deletions in their mtDNA or a complete lack of the mitochondrial gen-ome [19,20] Several Saccharomyces yeasts readily give rise to petites [21], but a majority of other yeasts fail

to yield stable petite mutants, and are therefore called

‘petite-negative’ yeasts [22] So far, the origin of and the biochemical and physiologic requirements for the occurrence of petites in yeast have been unclear It has previously been suggested that the petite-positive character might coincide with the ability to grow

in the absence of oxygen [22–24] However, Saccharo-myces kluyveri is an example of a yeast that can grow anaerobically, but cannot generate true petite mutants [25]

The origin of different responses to the pres-ence⁄ absence of oxygen has so far been poorly under-stood [26] Among the reasons are that few yeasts have been studied, and that the phylogenetic relation-ships among these yeasts were unclear at the time Recently, phylogenetic relationships among yeasts have been determined from a multigene sequence ana-lysis, which placed 75 species of the Saccharomyces complex into 14 well-supported clades [27] In many cases, these clades do not correspond to the circum-scribed genera: species of Kluyveromyces as well as of Zygosaccharomyces are found in different clades, indi-cating the polyphyly of these genera as presently defined According to this analysis, it was proposed

to reassign the species into five new genera [28] The

S cerevisiae lineage underwent a whole-genome dupli-cation about 100 million years ago [29–31], and the Saccharomyces clade can therefore be subdivided into pre- and post-genome duplication lineages Appar-ently, the duplication took place after the separation

of Saccharomyces, Kazachstania, Naumovia, Nakesimia and Tetrapisispora from the rest of Saccharomyces complex genera (Fig 1)

Another problem for comparative studies on the regulation of energy metabolism in aerobic and anaer-obic growth is caused by differences among the experi-mental conditions used, such as composition of media and adequate control of anaerobic conditions The purpose of the present work was to study the fermen-tative capacity, the ability to grow in anaerobic condi-tions and the occurrence of the petite phenotype in a large set of strains belonging to the ‘Saccharomyces complex’ Our study includes more than 40 strains, and provides a basis for speculation on how these metabolic traits evolved within the Saccharomyces clade, which originated approximately 150 million years ago

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Glucose metabolism and ethanol production

in aerobiosis (Crabtree effect)

In order to look for the presence of the Crabtree effect

in species belonging to the Saccharomyces complex, we

performed batch cultivations in a fermenter under

well-controlled aerobic conditions As a consequence of

respirofermentative glucose metabolism (Crabtree

effect), leading to the production of ethanol and other

byproducts (pyruvate, acetate, succinate, and glycerol),

S cerevisiaegrowing in batch on glucose under aerobic

conditions gave a low biomass yield (Table 1) Species

belonging to the genera Naumovia (Saccharomyces

castellii) and Nakaseomyces (Candida glabrata) showed

(Table 1) high specific ethanol production rates

(20.5 mmolÆg)1Æh)1 and 16.8 mmolÆg)1Æh, respectively)

as well as a low biomass yield (0.08 gÆg)1and 0.11 gÆg)1)

during the exponential phase of growth, with values very

similar to those reported for S cerevisiae [35] These

data indicate that these species behave as typical

Crab-tree-positive yeasts In the Torulaspora genus, we found

one species, T globosa, that showed a typical Crabtree

effect, with a high specific ethanol production rate

(18.6 mmolÆg)1Æh)1) and a low biomass yield

(0.08 gÆg)1) On the other hand, T delbrueckii showed a

less pronounced Crabtree effect, with a lower specific

ethanol production rate (6.13 molÆg)1Æh)1) and a higher

biomass yield (0.27 gÆg)1), as previously observed in

S kluyveri(Table 1) [36] A similar situation was

detec-ted in species belonging to the Hanseniaspora genus

Hanseniaspora vinaeand Hanseniaspora occidentalis did

in fact exhibit the ability to produce ethanol under

aero-bic conditions, but to a lower extent than S cerevisiae (Table 1) In the Zygosaccharomyces genus, Z bailii has been reported to show a reduced Crabtree effect [37] In our experiments, Z rouxii showed the lowest ethanol production rate (1.51 mmolÆg)1Æh)1) of all tested species Species belonging to the Kluyveromyces genus, such

as K wickerhamii, behaved like the Crabtree-negative yeast K lactis, being quite unable to produce ethanol under aerobic conditions (Table 1), in spite of high glucose consumption rates As a consequence of a purely respiratory metabolism, the two Kluyveromyces species showed the highest biomass yields (0.45 gÆg)1 and 0.4 gÆg)1, respectively) In conclusion, even though

a limited number of species was tested, our data indi-cate that the Crabtree effect is present in several spe-cies of the Saccharomyces complex, but is expressed at significantly different levels

Growth in aerobic conditions in the presence

of antimycin A

To further assess fermentative capacity, we tested for growth when respiration becomes gradually more impaired, by increasing the concentration of anti mycin A This drug is a well-known inhibitor of elec-tron transfer from quinone to cytocrome b [38] Yeast strains were cultivated in aerobic conditions on plates containing rich or synthetic minimal medium (Table 2) All but two of the species analyzed grew

on rich medium plus antimycin A, indicating that they are able to grow through fermentative metabo-lism, and most likely produce ethanol Most of the species, 29 out of 49, were able to grow on synthetic minimal medium at the highest antimycin A

concen-Table 1 Occurrence of respirofermentative metabolism in aerobic batch cultures: specific rates of growth (l),specific consumption rates of glucose (fructose) [qGlu (Frt)], specific production rates of ethanol (qEtOH) and the yields of biomass and ethanol relative to consumed glucose (fructose) for several yeasts of the Saccharomyces complex The data for S cerevisiae, Z bailii and S kluyveri are from the literature [35–37].

Strain

Carbon source

l (h)1)

qGlu (Frt) (mmolÆg)1Æh)1)

qEtOH (mmolÆg)1Æh)1)

Biomass yield (gÆg)1)

Ethanol yield (gÆg)1)

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Table 2 Analysis of growth under aerobic conditions in the presence of increasing concentrations of antimycin A The analysis refers to the Saccharomyces complex: the species are listed according to their phylogenetic relationship with S cerevisiae (the lowest species in the col-umn is the least related) as reported by Kurtzman & Robnett [27] –, no growth; +, growth within 7 days; NT, not tested Numbers indicate the maximal tolerated dose of antimycin A.

Antimycin A concentration (l M )

Rich medium:

5

Synthetic minimal medium:

0.5–25

Synthetic minimal medium plus lysine and glutamic acid:

0.5–25

Synthetic minimal medium plus acetoin: 0.5–25

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tration tested, whereas the rest could grow at lower

levels of the drug For some of these species, such as

Z bailii, T globosa, Zygosaccharomyces

microellipso-ides, K lactis, and H occidentalis, the addition of

acetoin, as well as the addition of lysine plus

glutam-ate, restored growth in the presence of high

concen-trations of antimycin A This suggests that for these

species the inability to grow in the presence of

anti-mycin A is mainly due to an impaired redox balance

This balance is substantially affected on synthetic

minimal medium because of the high level of NADH

generation, due to amino acid biosynthesis Much of

the generation of NADH during amino acid

biosyn-thesis takes place in the mitochondria Because of the

block in the respiratory chain caused by the addition

of antimycin A, NADH should then be reoxidized

through shuttle mechanisms with the cytoplasm [14]

Acetoin acts as a redox sink at the cytoplasmic level,

being reduced to 2,3-butanediol by the cytosolic

NAD+-linked 2,3-butanediol dehydrogenase [39] In

some species (Saccharomyces bayanus, Saccharomyces

servazii, Hanseniaspora valbyensis), we observed that

the inability to grow in the presence of high

concen-trations of antimycin A was actually due to an

impairment in the reoxidation of NADH at the

mit-ochondrial level, because in this case the addition of

acetoin did not help to restore the redox balance

(Table 2) This could indicate that, in these yeasts,

the mechanisms for shuttling NADH reducing

equiva-lents from mitochondria to cytosol are inefficient For

other species, such as S barnettii, Z rouxii, K

wick-erhamii, Eremothecium gossypii, and Kloeckera

lindner-i, the inability to grow on synthetic minimal medium

when respiration is at least partially impaired was not

alleviated by the addition of acetoin or of amino

acids In this case, the very low fermentative capacity

does not provide sufficient energy for growth when

respiration is limited

These data seem to indicate that most of the species belonging to the Saccharomyces complex possess a good fermentative capacity, being able to generate suf-ficient energy to grow when respiration is impaired Nevertheless, we observed that redox problems can, in some cases, limit the ability of the yeast to grow when the respiration chain is blocked

Growth under strict anerobic conditions All strains were cultivated on plates containing rich or synthetic minimal medium, and incubated under strict anerobic conditions Under these conditions, most of the species were able to grow after 7 days on both complex and synthetic minimal media (Fig 1) All an-alyzed species belonging to the Saccharomyces, Kaz-achstania, Naumovia, Nakaseomyces and Tetrapisispora genera were able to grow under the most stringent conditions, i.e on synthetic minimal medium under strict anaerobiosis (Fig 1, species in red)

Z microellipsoides (Torulaspora genus) and S kluyveri (Lachancea genus) were able to grow after 7 days only

on rich medium However, the addition of acetoin⁄ amino acids restored growth on synthetic minimal medium after 14 days of incubation (Fig 1, in blue) This suggests that the growth problems of these strains

on synthetic minimal medium are mainly caused by inefficient homeostasis of the redox cofactors under these conditions

Species belonging to the genera Zygosaccharomyces (Z bailii), Torulaspora (T globosa), Kluyveromyces (K lactis, K marxianus) and Hanseniaspora (H guiller-mondii and H occidentalis) showed growth on rich medium only after 14 days of incubation, but failed to grow on synthetic minimal medium, even in the pres-ence of acetoin (Fig 1, in green) This may reflect a strong redox problem that can completely impair growth in anaerobic conditions on synthetic minimal

Table 2 (Continued).

Antimycin A concentration (l M )

Rich medium:

5

Synthetic minimal medium:

0.5–25

Synthetic minimal medium plus lysine and glutamic acid:

0.5–25

Synthetic minimal medium plus acetoin: 0.5–25

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medium, where NADH production is high Z bailii is

known to produce more ethanol on fructose than on

glucose [37], and fructose is taken up by facilitated

transport [40] We then tested whether the presence of

fructose (instead of glucose) as carbon source could

allow for growth in anaerobic conditions However,

this was not the case

Other species belonging to the genera

Zygosaccha-romyces (Z rouxii, Z bisporus), Zygotorulaspora

(Z mrakii), Kluyveromyces (K aestuarii, K

nonfermen-tans, K wickerhamii), Eremothecium (E gossypii) and

Hanseniaspora (K lindneri) (Fig 1, in black) were

unable to grow on both rich and synthetic minimal

media in anaerobic conditions, even after addition of acetoin

The ability of some species to grow under anaerobic conditions on synthetic minimal medium was also tes-ted in batch cultures K lactis was used as a negative control, because it was previously found to be unable

to grow under these conditions [13] The species ana-lyzed, S castellii and C glabrata, showed the same behavior as observed in plate experiments, and were able to grow at high specific growth rates: 00.18 h)1 and 0.2 h)1, respectively (Fig 2)

In short, the upper five genera on the phylogenetic tree (post-genome duplication genera) showed a clear

Fig 1 Growth under strict anaerobic

condi-tions: yeast species in red grow both on rich

and on synthetic minimal medium within

7 days; species in blue grow on rich

med-ium within 7 days and on synthetic minimal

medium enriched with lysine and glutamic

acid or acetoin within 14 days; species in

green grow on rich medium within 14 days,

but fail to grow on the synthetic minimal

medium; species in black do not grow on

either rich or on synthetic minimal medium.

The phylogenetic tree is adapted from

Kurtzman & Robnett [27] The timing,

approximately 100 million years ago, of the

whole-genome duplication [29] is indicated

by an arrow.

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potential to grow under strictly anaerobic conditions.

On the other hand, the lower genera (pre-genome

duplication species) represent a mosaic of phenotypes;

some species being able and others being unable to

grow in the absence of oxygen

Petite generation

The ability to generate respiratory-deficient mutants

with grossly rearranged mtDNA molecules, sometimes

referred to as ‘the petite phenotype’, has often been

associated with the ability to grow anaerobically [25]

The following species, belonging to the Saccharomyces

clade, have previously been studied in detail for petite

generation ability and mtDNA structure: several

Sac-charomyces spp sensu stricto, Kazachstania genus

(S servazzii, S unisporus, S transvaalensis, S exiguus),

Naumovia genus (S castellii and S dairenensis), and

Nakeseomyces genus (C glabrata) They were found

to be petite-positive [21,41] On the other hand,

S kluyveri (belonging to the Lachancea genus) and

K lactis (belonging to the Kluyveromyces genus) do

not easily produce viable and stable petite clones [25]

Over 30 species⁄ strains, mainly belonging to the

groups that have so far not been tested for petite

generation, were analyzed in at least two independent

experiments (Fig 3) The aim of this experiment was

to determine whether a certain strain⁄ species can exist

as a petite mutant (which represents a special physio-logic state) and not to study the mechanisms behind the generation of petite mutants Kazachstania species (Arxiozyma telluris, S transvaalensis, K africanus,

S spencerorum, K lodderae, K piceae, S barnettii and

C humilis) could all generate spontaneous respiratory-deficient colonies, and also generated petites at a high frequency when exposed to ethidium bromide (EtBr)

In the Nakeseomyces genus, C glabrata and K bacilli-sporus generated spontaneous petites and EtBr-induced petites, but petites could not be detected in

K delphensis

In the Tetrapisispora genus, two species, T phaffii and T iriomotensis, were sensitive to EtBr and could therefore not be tested for petite induction, but

K blattae easily generated petites upon exposure to EtBr T phaffii and T iriomotensis did not generate spontaneous petites, or induced petites at lower EtBr concentrations The tested members of the genera Zygosaccharomyces (Z bisporus, Z rouxii), Zygotoru-laspora (Z mrakii), Torulaspora (T delbrueckii, T glo-bosa), Lachancea (Z fermentati, K thermotolerans and

S kluyveri) and Kluyveromyces (K aestuarii, K nonfer-mentans and K lactis) did not generate any sponta-neous or induced petites under the employed conditions, and are therefore considered to be petite-negative However, two species, Z florentinus and

K wickerhamii, generated petites upon prolonged exposure (10 days) to EtBr A few K wickerhamii petites were analyzed, and were found to contain grossly rearranged mtDNA with an elevated A + T content (data not shown) E gossypii was very sensi-tive to EtBr, and its ability to produce petites could therefore not be tested, but spontaneous petites could not be detected In the Hanseniospora genus, H occi-dentalis and H vinae did not generate petites spontane-ously or upon induction with EtBr, but H osmophila generated petites upon prolonged exposure to EtBr Again, post-genome duplication species, except for the Tetrapisispora group, showed an almost uniform phe-notype with regard to the ability to generate petite mutants On the other hand, a majority of the pre-gen-ome duplication species could not generate viable petites, except for three species belonging to three dif-ferent genera (Fig 3)

Discussion

The fundamental physiologic characteristics of the yeast S cerevisiae can be summarized as the ability to: (a) degrade glucose or fructose to ethanol, even in the presence of oxygen (Crabtree effect); (b) grow in the

A

B

Fig 2 Anaerobic batch cultures on glucose synthetic minimal

med-ium of (A) S castellii and (B) C glabrata: r, biomass measured as

D 600 ⁄ mL; j, glucose; m, ethanol; h, glycerol Both species show

behavior similar to that of S cerevisiae [25].

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absence of oxygen; and (c) generate

respiratory-deficient mitochondrial mutants, so-called petites [42]

However, how unique are these properties among

clo-sely related yeasts, and what is their origin? Recent

progress in genome sequencing has elucidated

phylo-genetic relationships among yeasts belonging to the

Saccharomyces clade, and thereby provides a

frame-work for an understanding of the evolutionary history

of several modern traits For example, the

whole-gen-ome duplication took place approximately 100 million

years ago in the S cerevisiae lineage [29–31], and we

can therefore talk about pre- and post-whole-genome

duplication yeasts within the Saccharomyces clade In

this study, we analyzed over 40 yeasts for their ability

to ferment, grow in the absence of oxygen, and

gener-ate stable petites, and we attempted to determine

whether these traits were expressed in the progenitor

yeasts, and whether they are related to the whole-genome duplication

A good fermentative capacity is the condi-tio sine qua non for the development of the ability to grow in strictly anaerobic conditions Under anaerobic conditions, the respiration-based biochemical pathways are shut down, and substrate-level phosphorylation is the only way for the cell to produce energy However, homeostasis of the redox cofactors is also important for continuation of metabolic activities Under anaer-obic conditions, yeast cells achieve such a redox bal-ance through the production of glycerol, mainly through the action of glycerol 3-phosphate dehydrogen-ase (Gpd2) [12], and through the production of succi-nate, by fumarate reductase [43] Under these conditions, the mitochondria do not play a role in energy metabolism, but they are still essential for some

Fig 3 Distribution of petite-positive and

petite-negative species in a phylogenetic

tree of the Saccharomyces complex,

adap-ted from Kurtzman & Robnett [27] The

examined species are indicated by different

colors: red, petite-positive species; green,

petite-negative species The timing,

approxi-mately 100 million years ago, of the

whole-genome duplication [29] is indicated by an

arrow.

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assimilatory reactions, as in amino acid biosynthesis,

and the generation of NADH [44] The ability to grow

in anaerobic conditions is therefore also strictly

dependent on the nutritional conditions

In our experiments, all but two of the analyzed

spe-cies belonging to the Saccharomyces complex could

grow on rich media when mitochondrial respiration

was partially impaired with antimycin A (Table 2)

Thus, the progenitor of the Saccharomyces complex

yeast probably had a well-developed fermentative

meta-bolism, which was sufficient to support growth in the

absence of oxygen When we made the conditions more

stringent, by increasing the concentration of

antimy-cin A and testing on the synthetic minimal medium

(Table 2), different yeast groups showed different

growth properties A high fermentative activity is, in

fact, essential in this case to cope with this situation If

the fermentative activity is too low, energy problems

can arise ATP is consumed by glucose uptake in the

case of yeasts having H+-symport mechanisms for

glu-cose transport, and in all cases ATP is used for

phos-phorylation of the hexose before ATP can be produced

in later metabolism Moreover, glycerol production

leads to reduced ATP production In these cases, the

presence of alternative respiration mechanisms, such as

cyanide-resistant salicyl hydroxamate-sensitive

respir-ation associated with the presence of complex I, can

operate and provide additional ATP when respiration

is blocked by antimycin A [45] Nevertheless, in some

cases we observed that the main problem for growth,

when respiration is impaired, seems to be insufficient

homeostasis of redox cofactors In these cases, the

addition of a redox sink, at the cytosolic as well as at

the mitochondrial level, efficiently promoted growth

This means that, in addition to high-level fermentative

metabolism, efficient mechanisms to maintain redox

balance are important for the ability to grow at low

levels of oxygen

Among the analyzed species belonging to the genera

Saccharomyces, Kazachstania, Naumovia,

Nakaseomy-ces and Tetrapisispora, those that showed high

resist-ance to antimycin A were also able to grow under the

most stringent conditions, i.e on the synthetic minimal

medium and under strict anaerobic conditions (Table 2

and Fig 1) Interestingly, some species, such as S

bay-anus, S servazii, and S barnettii, which showed

severely impaired growth in aerobic conditions in the

presence of antimycin A, were perfectly able to grow

under strict anaerobic conditions This seems to reflect

an inhibitory effect exerted by oxygen on fermentative

activity, the so-called Pasteur effect [3] Such an

inhibi-tory effect of oxygen could be a more recently

acquired trait, originating independently in several

yeast lineages In contrast, whereas the upper four post-genome duplication genera generated respiratory-deficient petite mutants, Tetrapisispora exhibited a transition petite phenotype This group deserves more study to determine the details of respiratory, fermenta-tive and mtDNA metabolism

In the other yeast groups (pre-genome duplication genera), the situation is more heterogeneous Among the analyzed species belonging to the genera Zygotoru-laspora, ToruZygotoru-laspora, Lachancea and Hanseniaspora, some of those that, in aerobic conditions, showed good resistance to antimycin A were able to grow under strict anaerobic conditions, like the above-mentioned genera (Table 2 and Fig 1) Some species belonging to the Zygosaccharomyces, Torulaspora, Kluyveromyces and Hanseniaspora groups were able to grow in anaer-obic conditions, but only on rich media, where the presence of amino acids can remedy the redox imbal-ance problems, and at low growth rates (detection requiring 14 days) Other species belonging to the gen-era Zygosaccharomyces, Zygotorulaspora, Kluyveromy-ces, Eremothecium and Hanseniaspora showed a much reduced level of resistance to antimycin A, and were quite unable to grow in anaerobic conditions, both on rich and on synthetic minimal media In these cases, the main growth problem appeared to be lack of energy, because an insufficient amount of ATP could

be generated by fermentation This interpretation is supported by the fact that S cerevisiae mutants in which glycolytic enzyme levels are low, such as gcr1 or gcr2, or in which hexose transport is inefficient, are sensitive to low concentrations of antimycin A and are unable to grow in anaerobic conditions [46,47]

The ability to grow in anaerobic conditions is a result of fine-tuning of several metabolic pathways This trait is not only dependent on the presence of genes encoding specific enzyme activities; these must also be a part of a well-regulated network The phylo-genetic tree (Fig 1) suggests that lineages that under-went whole-genome duplication exhibit a fermentative lifestyle, the presence of the Crabtree effect, the ability

to grow without oxygen, and the ability to generate petites (Table 1, Figs 1 and 3) Whereas a majority of pre-genome duplication species showed a reduced Crabtree effect, could not generate viable petite mutants, and needed some oxygen for their growth, some lineages exhibited similar traits as the post-gen-ome duplication lineage (Fig 4) However, it should

be noted that none of the pre-genome duplication spe-cies had all these traits expressed to the same quantita-tive level as the post-genome duplication species The presence of these traits in at least one species in each genus suggests that the Saccharomyces complex

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progenitor had the basic capacity to ferment, and this

was probably an adaptation to an environment with a

low oxygen concentration The mosaic distribution of

the studied phenotypes in the phylogenetic tree may,

then, reflect independent adaptations to changes in

environmental conditions that occurred many millions

of years ago The end of the Cretaceous period

provi-ded an excess of fruits, and thereby increased amounts

of sugars Different lineages of yeast, able to ferment,

entered into a fierce competition for these sugars with

different bacteria The independence from oxygen and

the ability to generate spontaneous petites, which can

only ferment and therefore produce ethanol, were

likely to strengthen the competitive advantages of

yeast Horizontal transfer of bacterial genes could also

have contributed to the increase in level of oxygen

independence [48] The ability to accumulate ethanol

in the presence of oxygen was exploited by several

yeasts as an additional weapon to inhibit the growth

of other microbes The appearance of an elevated

fre-quency of spontaneous petites helped to increase the

production of ethanol However, other evolutionary

strategies could also have contributed to the evolution

of these traits in yeasts [49,50]

Alternatively, it could be that the progenitor was

already Crabtree-positive, petite-positive and able to

grow without oxygen, but these properties were later

independently lost in several pre-genome duplication

lineages However, it is difficult to find a rationale for

this and imagine environmental conditions that would

promote this evolutionary scenario

Experimental procedures

Yeast strains The yeast species analyzed in this study belong to the Saccharomycescomplex described by Kurtzman & Robnett [27] Most of these strains were kindly provided by

C Kurtzman (Microbial Genomics and Bioprocessing Research Unit, US Department of Agriculture, Peoria, IL, USA) A majority of the studied species are represented

by their type strains: A telluris NRRL-YB-4302 (CBS 2685),

C glabrata Y-65 (CBS 138), C humilis NRRL-Y-17074 (CBS 5658), H guillermondii NRRL-Y-1625 (CBS 465), H occidentalis NRRL-Y-7946 (CBS 2592),

H osmophila NRRL-Y-1613 (CBS 313), H valbyensis NRRL-Y-1626 (CBS 479), H vineae NRRL-Y-17529 (CBS 2171), Klo lindneri NRRL-Y-17531 (CBS 285),

K aestuarii NRRL-YB-4510 (CBS 4438), K africanus NRRL-Y-8276 (CBS 2517), K bacillisporus NRRL-Y-17846 (CBS 7720), K blattae NRRL-Y-10934 (CBS 6284), K del-phensis 2379 (CBS 2170), K lodderae

NRRL-Y-8280 (CBS 2757), K marxianus NRRL-Y-8281 (CBS 712),

K nonfermentans NRRL-Y-27343 (JCM 10232), K piceae 17977 (CBS 7738), K thermotolerans

NRRL-Y-8284 (CBS 6340), K waltii NRRL-Y-8285 (CBS 6430),

K wickerhamii NRRL-Y-8286 (CBS 2745), S barnettii NRRL-Y-27223 (CBS 6946), S bayanus NRRL-Y-12624 (CBS 380), S castellii NRRL-Y-12630 (CBS 4309),

S dairensis NRRL-Y-12639 (CBS 421), S exiguus NRRL-Y-12640 (CBS 379), S kluyveri NRRL-Y-12651 (CBS 3082), S paradoxus NRRL-Y-17217 (CBS 432),

S pastorianus NRRL-Y-27171 (CBS 1538), S servazii

Fig 4 A simple phylogenetic relationship

between the yeasts analyzed in aerobic

batch cultures is shown, and the size of

their Crabtree effect is quantified as the

yields of biomass in relation to consumed

glucose (in brackets, gÆg)1) The S cerevisiae

and K lactis lineages separated more than

100 million years ago; the S cerevisiae and

S pombe lineages separated more than

200 million years ago The timing,

approxi-mately 100 million years ago, of the

whole-genome duplication [29] is indicated by an

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