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Tiêu đề EGF receptor in relation to tumor development: molecular basis of responsiveness of cancer cells to EGFR-targeting tyrosine kinase inhibitors
Tác giả Kenji Takeuchi, Fumiaki Ito
Trường học Setsunan University, Faculty of Pharmaceutical Sciences, Department of Biochemistry
Chuyên ngành Biochemistry
Thể loại Minireview
Năm xuất bản 2009
Thành phố Hirakata, Osaka
Định dạng
Số trang 11
Dung lượng 528,1 KB

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EGF receptor in relation to tumor development: molecular basis of responsiveness of cancer cells to EGFR-targeting tyrosine kinase inhibitors Kenji Takeuchi and Fumiaki Ito Department of

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EGF receptor in relation to tumor development: molecular basis of responsiveness of cancer cells to EGFR-targeting tyrosine kinase inhibitors

Kenji Takeuchi and Fumiaki Ito

Department of Biochemistry, Faculty of Pharmaceutical Sciences, Setsunan University, Osaka, Japan

Introduction

The epidermal growth factor receptor (EGFR) is

com-posed of an extracellular ligand-binding domain, a

transmembrane domain and an intracellular tyrosine

kinase domain The binding of a ligand to the

extracel-lular domain of the EGFR induces receptor

dimeriza-tion, activation of the intracellular kinase domain and

autophosphorylation of tyrosine residues within the cytoplasmic domain of the receptor The tyrosine-phosphorylated motifs of the EGFR recruit various adaptors or signaling molecules [1,2] The EGFR is able to activate a variety of signaling pathways through its association with these molecules

Extra-Keywords

cancer; epidermal growth factor receptor

(EGFR); gefitinib; non-small cell lung cancer

(NSCLC); tyrosine kinase inhibitor (TKI)

Correspondence

K Takeuchi, Department of Biochemistry,

Faculty of Pharmaceutical Sciences,

Setsunan University, Hirakata, Osaka

573-0101, Japan

Fax: +81 72 866 3117

Tel: +81 72 866 3118

E-mail: takeuchi@pharm.setsunan.ac.jp

(Received 17 July 2009, revised 17

September 2009, accepted 13 October

2009)

doi:10.1111/j.1742-4658.2009.07450.x

The function of the epidermal growth factor receptor (EGFR) is dysregu-lated in various types of malignancy as a result of gene amplification, mutations, or abnormally increased ligand production Therefore, the tyro-sine kinase activity of the EGFR is a promising therapeutic target EGFR tyrosine kinase inhibitors, such as gefitinib (Iressa), show evident anticancer effects in patients with non-small cell lung cancer The induction of apop-tosis has been considered to be the major mechanism for these gefitinib-mediated anticancer effects Lung cancer cells harboring mutant EGFRs become dependent on them for their survival and, consequently, undergo apoptosis following the inhibition of EGFR tyrosine kinase by gefitinib Gefitinib has been shown to inhibit cell survival and growth signaling path-ways such as the extracellular signal-regulated kinase 1⁄ 2 pathway and the Akt pathway, as a consequence of the inactivation of EGFR However, the precise downstream signaling molecules of extracellular signal-regulated kinase 1⁄ 2 and Akt have not yet been elucidated In this minireview we have highlighted the effect of tyrosine kinase inhibitors on members of the Bcl-2 family of proteins, which are downstream signaling molecules and serve as the determinants that control apoptosis We also discuss tyrosine kinase inhibitor-induced apoptosis via c-Jun NH2-terminal kinase and p38 mitogen-activated protein kinase

Abbreviations

BH, Bcl-2 homology domain; Bim, Bcl-2 interacting mediator of cell death; CDK, cyclin-dependent kinase; CRE, cAMP-response element; CREB, CRE-binding protein; EGFR, epidermal growth factor receptor; ERK, extracellular signal-regulated kinase; HNSCC, head and neck squamous cell carcinomas; IAP, inhibitor of apoptosis protein; JNK, c-Jun NH2-terminal kinase; KIP, kinase inhibitor proteins; MEK,

MAPK ⁄ ERK kinase; MKK, MAPK kinase; MKP-1, mitogen-activated protein kinase phosphatase-1; MOMP, mitochondrial outer membrane permeabilization; NSCLC, non-small cell lung cancer; Pak1, p21-activated kinase 1; PI3K, phosphatidylinositol 3-kinase; PUMA, p53

up-regulated modulator of apoptosis; RB, retinoblastoma; TKI, tyrosine kinase inhibitor.

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cellular signal-regulated kinase (ERK)1⁄ 2, which is one

of the three major groups of mitogen-activated protein

kinases (MAPKs) in mammals, is activated by the

EGFR tyrosine kinase and plays an essential role in

cell proliferation In contrast, EGFR signaling inhibits

the activation of the other two MAPKs, namely p38

MAPK and c-Jun NH2-terminal kinase (JNK)

Fur-thermore, the phosphatidylinositol 3-kinase (PI3K)⁄

Akt pathway, which is activated by the EGFR, has

been implicated in both cell proliferation and survival

Potential targets of these MAPK and PI3K⁄ Akt

sig-naling pathways include apoptosis-related molecules

(Bcl-2 family members and Fas) and cell-cycle

regula-tory molecules (e.g p27KIP1; Fig 1) The EGFR

there-fore plays an important role in both cell proliferation

and survival

EGFR function is dysregulated in various types of

malignancy [1,2] as a result of gene amplification,

mutations (resulting in a constitutively active EGFR)

or abnormally increased ligand production (reviewed

in [3]) Moreover, enforced expression of mutant

EG-FRs in transgenic mice promotes the development of

lung carcinomas [4,5] Therefore, EGFR-tyrosine

kinase is a promising therapeutic target Small

mole-cules that are active orally against the EGFR [e.g

gefitinib (Iressa) and erlotinib (Tarceva)] show evident

anticancer effects in patients with non-small cell lung

cancer (NSCLC) [6–8] Beneficial responsiveness to

these EGFR-targeting tyrosine kinase inhibitors

(TKIs) in patients with NSCLC is closely associated

with EGFR mutations such as del746-750 and L858R

in the kinase domain [9–11] Lung cancer cells

harboring mutant EGFRs become dependent on them

for their survival and, consequently, undergo

apopto-sis following inhibition of EGFR tyrosine kinase by gefitinib Gefitinib has been shown to inhibit cell growth and survival signaling pathways, such as the ERK1⁄ 2 pathway and the Akt pathway, as a conse-quence of inactivation of the EGFR [12] With refer-ence to Fig 1, which presents an overview of the intracellular signaling pathways activated by the EGFR tyrosine kinase, we will describe some of the diverse actions of TKIs on cell growth, cell survival and cell motility

target pathways for TKIs

Akt induces the phosphorylation of pro-caspase-9, thereby inhibiting its protease activity [13] Further-more, hepatocyte growth factor significantly inhibits adriamycin-induced apoptosis in the human gastric adenocarcinoma cell line MKN74 through phosphory-lation of pro-caspase-9 via the Akt signaling pathway [14] Akt also phosphorylates Bad [15], a pro-apoptotic member of the Bcl-2 family, and the forkhead tran-scription factor FKHR [16], a pro-apoptotic transcrip-tion factor Therefore, the Akt signaling pathway has emerged as the major mechanism by which growth factors promote cell survival (reviewed in [17])

A link between the Akt pathway and gefitinib-responsiveness was reported by Engelman et al [18]: the Akt pathway is down-regulated in response to gefi-tinib only in NSCLC cell lines that are growth-inhib-ited by gefitinib Thus, activated Akt has been indicated as a molecular determinant of a response to EGFR-targeting drugs However, the NSCLC cell line H3255, harboring the L858R mutation in EGFR exon

Fig 1 Major signaling pathways

downstream of the activated EGFR

Activation of several signaling cascades

triggered predominately by the ERK1⁄ 2

and the PI3K⁄ Akt pathways results, in turn,

in the inactivation of pro-apoptotic Bcl-2

proteins (e.g PUMA, Bax, Bim and Bad),

Fas, and CDK inhibitors (e.g p27 KIP1 ,

p21 WAF1 and p15 INK4b ), and also in the

activation of Pak1.

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21, and PC-9, harboring a deletion (del746-750) in

EGFR exon 19, are highly sensitive to gefitinib; and

this sensitivity to gefitinib is associated with

depen-dence on both Akt and ERK1⁄ 2 pathways [10,19]

Apoptosis

The induction of apoptosis has been considered as the

major mechanism for gefitinib-mediated anticancer

effects Mammals have two distinct, but ultimately

converging, apoptosis signaling pathways: the extrinsic

(also called ‘death receptor’) pathway, which is

acti-vated by death receptors; and the intrinsic (also called

‘mitochondrial’ or ‘Bcl-2-regulated’) pathway [20] The

intrinsic pathway is characterized by the

permeabili-zation of the outer mitochondrial membrane and the

release of several pro-apoptotic factors into the

cytoplasm For mitochondrial outer membrane

per-meabilization (MOMP), a coordinated effort between

numerous Bcl-2 proteins must be engaged (reviewed in

[21]) The Bcl-2 proteins can be divided into three

groups according to their function (Fig 2) Members

of the Bcl-2 protein family are distinguished by the

presence of up to four different Bcl-2 homology

domains (designated BH1–4) The multidomain

pro-apoptotic Bcl-2 proteins, Bax and Bak, contain BH1–3

domains and only induce MOMP following apoptotic

stimuli, resulting in the release of cytochrome c,

activa-tion of the caspase cascade and cellular destrucactiva-tion

[22] To prevent cell death, Bax and Bak are bound

and inhibited by the anti-apoptotic members of the

Bcl-2 protein family (Bcl-2, Bcl-xL, Bcl-w, Mcl-1 and

A1), which contain four BH domains [22] The third

subgroup, the BH3-only proteins, are structurally

diverse and contain only one conserved domain (BH3)

Often, the BH3-only proteins are subdivided into

direct activators [Bid and Bcl-2 interacting mediator of

cell death (Bim)] and de-repressors [Bad, Bik, Bmf,

NOXA, and p53 up-regulated modulator of apoptosis (PUMA)] These de-repressors initiate apoptosis signal-ing by bindsignal-ing and antagonizsignal-ing the anti-apoptotic Bcl-2 family members, thereby causing activation of Bax and Bak [23] Regulation of Bcl-2 family members can occur by a number of mechanisms, including up-regulation of synthesis, enhancement of degrad-ation and phosphoryldegrad-ation In the event that cancer cells undergo apoptosis in response to gefitinib, inhibi-tion of Akt- and ERK1⁄ 2-dependent pathways eventu-ally change the expression level of one or more of these Bcl-2 family members

Bad Bad is one of the ‘death-promoting’ members of the Bcl-2 family, and its pro-apoptotic activity is regulated primarily by phosphorylation at several sites [24] Acti-vated Akt [13,25] and ERK1⁄ 2-p90 ribosomal S6 kinase-1 (p90Rsk-1) [26,27] pathways have been shown

to promote survival signaling by phosphorylating Bad

at Ser136 and Ser112, respectively These phosphory-lated residues provide binding sites for 14-3-3 proteins, which subsequently sequester Bad

Phosphorylation of Bad-Ser112 via ERK1⁄ 2 path-way ( in Fig 2) is inhibited by either gefitinib or the MAPK⁄ ERK kinase (MEK) inhibitor PD98059 in mammary epithelial cells and primary cultures of malignant breast carcinoma [28] Gefitinib has no effect on EGF-mediated Bad-Ser112 phosphorylation

in the cells transfected with vectors encoding constitu-tively active p90Rsk-1 Thus, the EGF induces Bad phosphorylation through an ERK1⁄ 2 pathway involv-ing p90Rsk-1 It has also been reported that primary cultures of Bad) ⁄ )mammary cancer cells are no longer sensitive to gefitinib-induced apoptosis, suggesting that Bad might be an important pro-apoptotic effector molecule downstream of the EGFR

Fig 2 Bcl-2 family proteins as targets of TKIs.

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PUMA was initially identified as a critical mediator of

apoptosis induced by the tumor suppressor p53 [29,30]

and it can be directly activated by p53 through

p53-responsive elements in its promoter region PUMA can

also induce p53-independent apoptosis in response to a

wide variety of stimuli [31] Therefore, PUMA is a

crit-ical mediator of both p53-dependent and

p53-indepen-dent apoptosis and mediates apoptosis through the

Bcl-2 family proteins Bax⁄ Bak [32] PUMA is induced

by gefitinib, independently of p53, in head and neck

squamous cell carcinomas (HNSCC) [33] This

BH3-only protein functions as a critical mediator of

gefiti-nib-induced apoptosis, and in the Akt pathway and

p73, p53 family proteins serve as key regulators of

PUMA induction after EGFR inhibition (pathway

in Fig 2) Overexpression of EGFR is found in more

than 80% of HNSCC Thus, TKIs have emerged as

promising treatments, not only for NSCLC but also

for HNSCC

Bim

Bim is a member of the BH3-only proteins [34]

Under conditions that promote cell growth, Bim is

bound to dynein light chain (LC8) of the

microtubu-lar motor complex and is sequestered away from

other Bcl-2 family members [35] Following a

pro-apoptotic stimulus, however, Bim is localized to the

mitochondria, where it initiates the mitochondrial cell

death pathway by directly activating Bax⁄ Bak [36]

Bim expression is regulated by both transcriptional

and post-transcriptional levels (pathway in Fig 2)

Phosphorylation of Bim by ERK1⁄ 2 targets Bim for

degradation by the ubiquitin-proteasome system [37]

Bim has recently been reported to mediate

gefitinib-induced apoptosis [38–40] Bim knockdown by RNA

interference protects the NSCLC cell line, H3255,

potently against gefitinib, and the level of protection

correlates with the extent of Bim reduction, indicating

that Bim is essential for gefitinib-induced apoptosis of

NSCLC cells The induction of Bim after treatment

with gefitinib is a consequence of both transcriptional

induction and dephosphorylation Thus, shutdown of

the EGFR-MEK-ERK signaling cascade by gefitinib

elicits Bim accumulation and causes apoptosis The

T790M mutation of the EGFR, which renders

gefiti-nib and erlotigefiti-nib ineffective inhibitors of EGFR

kinase activity, blocks gefitinb-induced up-regulation

of Bim and apoptosis [38] These experiments point

to an important role for the induction of Bim in

gefitinib-triggered apoptosis of NSCLC cells

Bax Bax is a 21-kDa multi-BH domain apoptotic pro-tein and acts downstream of BH3-only propro-teins The induction of Bax expression can be sufficient to induce apoptosis and requires no additional death stimulus [41] Furthermore, Bax expression is associated with tumor development [42] The protein is normally found

in the cytoplasm, where it is heterodimerized to anti-apoptotic Bcl-2 family members such as Mcl-1 and Bcl-xL; however, once the cell is exposed to an apop-totic stimulus, Bax is translocated to the mitochondria [43] and induces mitochondrial dysfunction, character-ized by the formation of large pores in the mito-chondrial membrane [44]

Stimulation of the Akt pathway inhibits Bax translo-cation from the cytoplasm to the mitochondria and promotes survival [45] Anti-apoptotic stimuli lead to the activation of Akt and to Ser184 phosphorylation

of Bax [46] This phosphorylation promotes the seques-tration of Bax in the cytoplasm and increases the abil-ity of Bax to heterodimerize with the anti-apoptotic Bcl-2 family members Mcl-1 and Bcl-xL, thereby inhibiting activation of apoptosis signals Gefitinib is known to induce apoptosis through shutdown of Akt signaling However, it has not been demonstrated whether this shutdown transmits the apoptotic signal via inhibition of Bax phosphorylation

Regulation of Bax also occurs by mechanisms other than phosphorylation Gefitinib inhibits growth of human gallbladder adenocarcinoma cells (HAG-1) by arresting the cells in the G0⁄ G1 phase [47] This arrest

is accompanied by depression of cyclin D1 mRNA as well as by the accumulation of p27 protein However, when HAG-1 cells are treated with gefitinib for more than 72 h, the apoptotic population increases Corre-spondingly, gefitinib up-regulates expression of total Bax, with a subsequent increase in p18 Bax that has been shown to be generated through the cleavage of full-length Bax during apoptosis (pathway in Fig 2) Cleavage of Bax into p18 Bax occurs in response to various stimuli, such as interferon-a [48] and chemo-therapeutic agents [49] p18 Bax fragment is as efficient

as full-length Bax in promoting cytochrome c release [49,50] and more potent than full-length Bax in induc-ing apoptotic cell death [51] It is also suggested that

an increase in gefitinib-induced expression of total Bax

is caused by the decreased degradation of Bax As ERK1⁄ 2 and Akt are significantly inhibited in gefiti-nib-treated HAG-1 cells, simultaneous inhibition of these pathways by gefitinib may lead to the accumula-tion of Bax and subsequent apoptosis As described below, gefitinib initiates the intrinsic pathway of

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apop-tosis through p38a-dependent Bax activation in

intesti-nal epithelial cells (pathway in Fig 2) Accordingly,

inhibition of Akt-dependent Bax phosphorylation at

Ser184, generation of the p18 Bax fragment and

p38a-dependent Bax activation are proposed for Bax

activation Further studies are needed to understand

the precise mechanism by which gefitinib induces

apoptosis in a Bax-dependent manner

Inhibitor of apoptosis protein family

Induction of MOMP following apoptotic stimuli

results in the release of cytochrome c and subsequent

activation of caspase-9 and caspase-3, which are

cystein proteases that cleave vital cellular targets and

cause apoptosis Caspases can be inhibited by members

of the inhibitor of apoptosis protein (IAP) family such

as cIAP-1, cIAP-2, X-linked IAP and survivin Recent

studies have suggested that activation of the PI3K⁄ Akt

pathway by EGFR signaling causes up-regulation of

survivin expression [52] The levels of cIAP-2 are

down-regulated by gefitinib or erlotinib in intestinal

epithelial cells [53] Furthermore, the expression of

cIAP-1 and of X-linked IAP is reduced by AG1478 in

squamous cell carcinoma cell lines NA and Ca9-22

[54] As small interfering RNA (siRNA)-based

deple-tion of IAP increases apoptosis in response to gefitinib,

IAPs might be a molecular target for the induction of

apoptosis by TKIs

Inhibition of cell proliferation

EGFR signaling activates a variety of pathways such

as those for cell survival, cell proliferation, cell

motil-ity, angiogenesis and expression of extracellular matrix

proteins [55] Accordingly, TKIs against EGFR exert

not only apoptosis-inducing action but also other

divergent actions For instance, EGFR inhibition leads

to the induction of cell-cycle arrest at the G1-S bound-ary [56] Cell-cycle regulation is important in growth control, and therefore deregulation of the cell-cycle machinery has been implicated in carcinogenesis [57] Cyclins and cyclin-dependent kinases (CDKs), in asso-ciation with each other, play key roles in promoting the G1-to-S phase transition of the cell-cycle by phos-phorylating the retinoblastoma (RB) protein Activa-tion of cyclin–CDK complexes is counterbalanced by CDK inhibitors, including those of the kinase inhibitor proteins (KIP) family and the INK4 family (Fig 3) The KIP family consists of p27KIP1, p21WAF1⁄ CIP1and p57KIP2; and the INK4 family consists of p15INK4b, p16INK4a, p18INK4cand p19INK4d

AG1478, which, like gefitinib and erlotinib, acts as a specific inhibitor of the EGFR tyrosine kinase, has been shown to result in a dose-dependent up-regula-tion of p27KIP1and in hypophosphorylation of the RB protein in human epidermoid carcinoma cell line A431 cells [56] These changes are temporally associated with recruitment of tumor cells in the G1 phase and a marked reduction in the proportion of cells in the S phase The G1 arrest and up-regulation of p27KIP1 resulting from EGFR blockade are caused by the interruption of PI3K signals In addition to p27KIP1, p21WAF1⁄ CIP1 is involved in gefitinib-induced growth inhibition in HNSCC [58] Another group of cell-cycle regulatory molecules – those of the INK4 family – has also been implicated in gefitinib-induced inhibition of cell growth Gefitinib up-regulates p15INK4b in human immortalized keratinocyte HaCaT cells and results in

RB hypophosphorylation and G1 arrest [59] More-over, mouse embryo fibroblasts lacking p15INK4b are resistant to the growth-inhibitory effects of gefitinib

As the level of p15INK4b is increased by MEK inhibi-tors, but not by Akt inhibiinhibi-tors, the induction of

Fig 3 The cell-cycle is arrested at the G 1

phase by TKI-induced CDK inhibitors EGFR-TKIs result in the up-regulation of CDK inhib-itors, including KIP family members and INK4 family members Members of the KIP family can inhibit the catalytic activity of CDK2, 4 and 6 Members of the INK4 family are specific inhibitors of the cyclin D–CDK4 ⁄ 6 complex It is not yet known

if EGFR-TKIs can stop G2transition and G 2 ⁄ M cell-cycle progression by up-regulation of KIP family members.

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p15INK4b by inhibition of the ERK1⁄ 2 pathway is

associated with the antiproliferative effects of gefitinib

Inhibition of cell motility

The EGFR can transmit signals for re-organization of

the cytoskeleton, the formation of lamellipodia,

mem-brane ruffling and changes in cell morphology

Accordingly, dysregulation of the EGFR contributes

to the progression, invasion and maintenance of the

malignant phenotype In keratinocyte and cutaneous

squamous cancer cells, gefitinib blocks EGF-induced

cytoskeleton remodeling and in vitro invasiveness, as

well as cell growth [60] Gefitinib also effectively

inhib-its ERK1⁄ 2 activation and p21-activated kinase 1

(Pak1) activity (see Fig 1) Pak1 is a serine⁄ threonine

kinase and is a critical component of many growth

fac-tor recepfac-tor-mediated signal transduction pathways,

leading to directional cell motility and cell invasiveness

[61] Because deregulation of EGFR signaling is

com-monly associated with stimulation of ERK1⁄ 2 and

Pak1 pathways, gefitinib might lead to inhibition of

invasiveness of human cancer cells through the

inhibi-tion of ERK1⁄ 2 and Pak1 The use of gefitinib in cells

with activated ERK1⁄ 2 or Pak1 pathways might

potentially lead to beneficial anti-cancer activity

through the inhibition of not only cell survival but also

cell invasiveness

p38, JNK and Fas as target molecules

of gefitinib

p38

As described above, the treatment of intestinal

epithe-lial cells with gefitinib results in a dramatic increase in

apoptosis and activation of the intrinsic apoptotic

pathway via trafficking of activated Bax to the

mito-chondria [62] Akt is known to phosphorylate Bax and

to prohibit its mitochondrial translocation However,

the Akt pathway plays a minor role in the induction

of apoptosis in intestinal epithelial cells Instead, p38

MAPK phosphorylation is associated with

mitochon-drial translocation of Bax and subsequent induction of

apoptosis following EGFR inhibition (pathway in

Fig 2) Furthermore, p38a, one of the four p38

iso-forms, is required for Bax activation and apoptosis

Because activation of p38 by UVB irradiation in

human keratinocytes results in induction of a

confor-mational change in Bax and its translocation to

mito-chondria [63], p38 may be an important upstream

molecule of Bax activation in response to a variety of

apoptosis-inducing stimuli

JNK and mitogen-activated protein kinase phosphatase-1

The activity of JNK, one of the MAPKs, is tightly controlled by both protein kinases, such as MAPK kinase 4 (MKK4) or MAPK kinase 7 (MKK7) and protein phosphatases such as MAPK phosphatase (MKP) Mitogen-activated protein kinase

phosphatase-1 (MKP-phosphatase-1) is a dual-specificity protein phosphatase, which can dephosphorylate both phosphothreonine and phosphotyrosine residues and subsequently block the activities of MAPKs [64] Although MKP-1 was initially characterized as an ERK-specific phosphatase [65], subsequent studies have determined that MKP-1 preferentially acts on JNK and p38 MAPK in response

to various stresses [66]

MKP-1 has been correlated with tumorigenesis Several observations have indicated that MKP-1 is overexpressed in human tumors Constitutive expression levels of MKP-1 in NSCLC cell lines are higher than those found in normal cells under basal growth condi-tions [67] Overexpression of MKP-1 has been reported

to protect cells against apoptosis induced by UV irradia-tion, Fas ligand, cisplatin, paclitaxel, proteasome inhibi-tors or radiation therapy [68] These observations have established that MKP-1 plays an important role in resistance against many types of stresses, including anti-cancer drugs, in various cell lines MKP-1 may be a rational target to enhance anticancer drug activity Our recent results have shown that the activation of JNK induced by EGFR-TKI AG1478 is critical for the apoptotic action of AG1478 against the NSCLC cell line PC-9 [69] Various types of stimuli activate JNK through phosphorylation by the dual-specificity JNK kinases; but JNK kinases MKK4 and MKK7 are not activated by AG1478 treatment In contrast, JNK phosphatase (i.e MKP-1) is constitutively expressed in PC-9 cells and its expression level is reduced by AG1478 Furthermore, the inhibition of JNK activation by ectopic expression of MKP-1 or a domi-nant-negative form of JNK strongly suppresses AG1478-induced apoptosis Thus, JNK, which is acti-vated through the decrease in the MKP-1 level, is criti-cal for the apoptotic action of AG1478 against PC-9 cells Interestingly, AG1478 has no inhibitory activity towards MKP-1 expression in some resistant cell lines isolated from gefitinib-sensitive PC-9 cells (unpublished data of T Shin-ya, K Takeuchi and F Ito)

Although MKP-1 expression has been implicated in cancer and in TKI sensitivity, the mechanism by which EGFR activation controls the MKP-1 expression level

is unclear MKP-1 is encoded by an early response gene, which is transiently induced by mitogens and

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stress signals such as serum, growth factors, cytokines,

UV irradiation, heat shock, hypoxia and anticancer

drugs [68] through both transcriptional [70,71] and

post-translational [72,73] mechanisms As depicted in

Fig 3, the human mkp-1 gene contains four exons and

three introns coding for an inducible mRNA that is

approximately 2.4 kb long [74] The

pro-moter⁄ enhancer region of the mkp-1 gene contains

multiple activator protein 2 (AP2), trans-acting

tran-scription factor 1 (SP1) and cAMP-response element

(CRE) sites, but only one site for each of activator

protein 1 (AP1), neurofibromin 1 (NF1) and TATA

box [74] ERK1⁄ 2 can phosphorylate Ser133 of the

CRE-binding protein (CREB) through p90Rsk-2, and

Ser133 phosphorylation is required for

CREB-medi-ated transcription [75] These results suggest that

EGFR signaling can induce the transcription of mkp-1

via phosphorylation of CREB However, induction of

MKP-1 in mouse embryo fibroblasts following

treat-ment with arsenite and irradiation with UVC is

pre-dominantly mediated by the p38 MAPK pathway

Both p38 MAPK and ERK have been implicated in

the transcriptional induction of MKP-1, and each may

use a different set of transcription factors to enhance

MKP-1 expression

Several lines of evidence suggest that

phosphoryla-tion of MKP-1 protein plays an important role in the

stabilization of MKP-1 (Fig 4) ERK1⁄ 2 reduces

MKP-1 degradation by phosphorylating the Ser359

and Ser364 residues of MKP-1 [72] ERK1⁄ 2 is also

responsible for the degradation of MKP-1 via the

phosphorylation of Ser296 and Ser323 residues [76]

Once phosphorylated, Skp2 (also called SCFSkp2 of

Skp1⁄ Cul1 ⁄ F-box protein Skp2; ubiquitin-protein

iso-peptide ligase E3) targets MKP-1 for degradation via

the ubiquitin proteasomal pathway [73] In addition to the transcriptional and post-translational control described here, it is suggested that transcription of the mkp-1 gene is also controlled at the level of transcrip-tional elongation [71] The mechanism responsible for the regulation of MKP-1 expression is complex, and both transcriptional down-regulation and degradation

of MKP-1 may be effects observed in cells having an apoptotic response to EGFR-TKI AG1478

Fas Exposure of the human NSCLC cell line, A549, to gef-itinib causes a marked increase in the expression of Fas protein and in the activation of caspases 2, 3 and

8 [77] Co-treatment of cells with Fas antagonist anti-body significantly blocks gefitinib-induced apoptosis Furthermore, caspase-8 and caspase-3 inhibitors, but not a caspase-9 inhibitor, are capable of restoring cell viability Thus, Fas appears to play a major role in the initiation of gefitinib-induced apoptosis through activa-tion of the caspase-8⁄ caspase-3 cascade Treatment of A549 cells with gefitinib results in the translocation of p53 from the cytosol to the nucleus Moreover, inhibi-tion of p53 using antisense oligonucleotide causes down-regulation of Fas and a significant decrease in gefitinib-induced apoptosis p53 may thus play a role

in determining gefitinib sensitivity by regulating Fas expression in NSCLC

Conclusions

Important regulators of cell survival and apoptosis are the Bcl-2 family of proteins Members of this family, such as Bcl-2 and Bcl-xL, can inhibit apoptosis,

Fig 4 Regulation of MKP-1 expression by EGFR signaling MKP-1 expression is controlled through both transcription and post-translation steps ERK1 ⁄ 2, JNK and p38 MAPK can activate transcription of the mkp-1 gene The promoter ⁄ enhancer region

of the mkp-1 gene has the potential to bind many transcription factors AP1, activator protein 1; CAD, phosphatase catalytic domain; CRE, cAMP-responsive element; NF1, neurofibromin 1; SP1, trans-acting transcription factor 1.

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whereas others promote apoptosis The balance

between these pro-apoptotic and anti-apoptotic Bcl-2

family members determines the cellular fate (i.e

survival or apoptosis) In cancer cells that undergo

apoptosis in response to TKIs, shutdown of ERK1⁄ 2

and PI3K⁄ Akt signaling pathways following the

inhi-bition of EGFR activation ultimately results in the

disruption of the balance between pro-apoptotic and

anti-apoptotic Bcl-2 proteins and subsequent

apopto-sis Bcl-2 family proteins are key molecules for

regulat-ing the permeabilization of the outer mitochondrial

membrane and thus represent pivotal components in

TKI-dependent apoptosis signaling TKIs change the

transcription level of Bcl-2 family genes and the

phos-phorylation state of their proteins, thereby changing

the amount and localization of Bcl-2 family members

However, each type of cancer has its own way of

disrupting the balance of the networks of signaling

cascades following TKI treatment Therefore,

under-standing how Bcl-2 family members are regulated in

each type of cancer is critical for understanding how

TKIs cause apoptosis in each of them

It is now clear that TKIs are unlikely to provide

cures for the majority of patients with NSCLC

Despite the initial dramatic efficacy of gefitinib and

erlotinib in NSCLC patients with EGFR mutations,

all patients ultimately develop resistance to TKIs A

secondary mutation in the EGFR (T790M) and the

amplification of hepatocyte growth factor receptors

have been identified as major mechanisms of acquired

resistance to TKIs [78] However, it is still important

to identify additional mechanisms of resistance and to

overcome acquired resistance to TKIs Research on

the signaling routes from the EGFR to Bcl-2 family

members will provide critical information to augment

the efficacy of TKIs and to identify patients who will

have a positive response to TKIs

Acknowledgements

This work was supported, in part, by a grant-in-aid

for scientific research from the Ministry of Education,

Culture, Sports, Science, and Technology of Japan,

and by funding from the Fugaku Trust for Medical

Research

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